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What are the possible values for the quantum numbers \(n, \ell\), and \(m_{\ell} ?\)

Short Answer

Expert verified
Possible values for the quantum numbers are: - Principal quantum number (n): \(n = 1, 2, 3, ...\) - Azimuthal quantum number (â„“): \(â„“ = 0, 1, ..., n-1\) - Magnetic quantum number (m_â„“): \(m_{â„“} = -â„“, -â„“+1, ... , 0, ... , â„“-1, â„“\)

Step by step solution

01

Understand quantum numbers

Quantum numbers are numbers that describe the unique state of an electron in an atom. There are three main quantum numbers: 1. Principal quantum number (n): Determines the energy level of an electron in an atom and the size of its orbital. It can have any positive integer value starting from 1 (n=1, 2, 3, ...). 2. Azimuthal quantum number (â„“): Determines the shape of the orbital and is related to the angular momentum of an electron. It depends on the value of n and can have integer values ranging from 0 to n-1 (â„“=0, 1, ..., n-1). 3. Magnetic quantum number (m_â„“): Determines the orientation of the orbital in space and is related to the projection of the angular momentum along with a specified axis. It depends on the value of â„“ and can have integer values ranging from -â„“ to +â„“ (m_â„“=-â„“, -â„“+1, ... , 0, ... , â„“-1, â„“).
02

Finding the possible values of n

The principal quantum number can have any positive integer value. So the possible values of n can be expressed as: \(n = 1, 2, 3, ...\)
03

Finding the possible values of â„“

The azimuthal quantum number (â„“) is related to the value of n and ranges from 0 to n-1. For each value of n, possible values of â„“ can be expressed as: \(â„“ = 0, 1, ..., n-1\)
04

Finding the possible values of m_â„“

The magnetic quantum number (m_â„“) is related to the value of â„“ and ranges from -â„“ to +â„“. For each value of â„“, possible values of m_â„“ can be expressed as: \(m_{â„“} = -â„“, -â„“+1, ... , 0, ... , â„“-1, â„“\)
05

Listing the possible quantum number values

The possible values for the quantum numbers n, â„“, and m_â„“ can be summarized as: - Principal quantum number (n): \(n = 1, 2, 3, ...\) - Azimuthal quantum number (â„“): \(â„“ = 0, 1, ..., n-1\) - Magnetic quantum number (m_â„“): \(m_{â„“} = -â„“, -â„“+1, ... , 0, ... , â„“-1, â„“\)

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Principal Quantum Number Explained
Imagine being in a vast library, the shelves labeled with numbers that help you find books at different heights. In the world of atoms, electrons are a bit like books and the shelves are energy levels determined by the principal quantum number, often denoted by the symbol \(n\). The higher the number, the higher the energy level and the larger the orbital where an electron can be found.

With each step up, starting from 1, the electron resides further from the nucleus — meandering in shells that can hold more energy and more electrons. Think of \(n=1\) as the ground floor, \(n=2\) a little higher, and so on, with no upper limit in theory. However, due to the limitations in energy that an electron can possess, we do not see electrons with an arbitrarily high \(n\) value.

So, the principal quantum number sets the stage, sketching out the size of the electron's 'room' — it chalks the boundaries for an electron's personal space within an atom.
Azimuthal Quantum Number Demystified
Now, within each energy level, or 'floor', defined by the principal quantum number, there are various types of 'rooms' with different shapes — enter the azimuthal quantum number (\(\ell\)). It's akin to the various room shapes in a hotel, ranging from a cozy circular room to an elongated suite.

These 'rooms' are in fact subshells, represented by s, p, d, and f, corresponding to the values of \(\ell = 0, 1, 2, 3\), respectively. The value of \(\ell\) is contingent on \(n\); for instance, if \(n=2\), \(\ell\) could be 0 or 1 (s or p subshell). But it could never exceed \(n-1\), ensuring that every room fits neatly within its floor.

It's crucial to understand that the azimuthal quantum number is not just about shapes; it relates to the intricate dance of electrons — their angular momentum. Each increase in \(\ell\) adds more loops and swirls to the electron's pathway, effectively changing its motion style.
Magnetic Quantum Number: The Orientation Guide
When it comes to the magnetic quantum number, represented by \(m_{\ell}\), one moves from the realm of size and shape to orientation — it's as if each room on our hotel floor could be rotated to face different directions. Each \(m_{\ell}\) value describes an electron's orbital orientation within a subshell relative to an external magnetic field.

For a given \(\ell\), \(m_{\ell}\) spans from \(\ell\) to \( -\ell\). If our subshell (room shape) is p-type (\(\ell=1\)), \(m_{\ell}\) could be -1, 0, or 1. This range of values accounts for the fact that you could rotate your hotel room left, right, or keep it as is. In quantum terms, each \(m_{\ell}\) value corresponds to a specific orbital that can house up to two electrons, who each get their unique spin direction, further distinguishing them.

Thus, the magnetic quantum number does not influence energy or shape but directs how different orbitals are positioned around the nucleus, providing a unique address for each electron's residence in atomic real estate.

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Most popular questions from this chapter

Calculate the wavelength of light emitted when each of the following transitions occur in the hydrogen atom. What type of electromagnetic radiation is emitted in each transition? a. \(n=3 \rightarrow n=2\) b. \(n=4 \rightarrow n=2\) c. \(n=2 \rightarrow n=1\)

The Heisenberg uncertainty principle can be expressed in the form $$ \Delta E \cdot \Delta t \geq \frac{h}{4 \pi} $$ where \(E\) represents energy and \(t\) represents time. Show that the units for this form are the same as the units for the form used in this chapter: $$ \Delta x \cdot \Delta(m v) \geq \frac{h}{4 \pi} $$

An ion having a \(4+\) charge and a mass of \(49.9\) amu has 2 electrons with principal quantum number \(n=1,8\) electrons with \(n=2\), and 10 electrons with \(n=3 .\) Supply as many of the properties for the ion as possible from the information given. (Hint: In forming ions for this species, the \(4 s\) electrons are lost before the \(3 d\) electrons.) a. the atomic number b. total number of \(s\) electrons c. total number of \(p\) electrons d. total number of \(d\) electrons e. the number of neutrons in the nucleus f. the ground-state electron configuration of the neutral atom

Defend and criticize Bohr's model. Why was it reasonable that such a model was proposed, and what evidence was there that it "works"? Why do we no longer "believe" in it?

The work function is the energy required to remove an electron from an atom on the surface of a metal. How does this definition differ from that for ionization energy?

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