Chapter 5: Problem 16
At the same conditions of pressure and temperature, ammonia gas is less dense than air. Why is this true?
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Chapter 5: Problem 16
At the same conditions of pressure and temperature, ammonia gas is less dense than air. Why is this true?
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Which noble gas has the smallest density at STP? Explain.
In 1897 the Swedish explorer Andreé tried to reach the North Pole in a balloon. The balloon was filled with hydrogen gas. The hydrogen gas was prepared from iron splints and diluted sulfuric acid. The reaction is $$ \mathrm{Fe}(s)+\mathrm{H}_{2} \mathrm{SO}_{4}(a q) \longrightarrow \mathrm{FeSO}_{4}(a q)+\mathrm{H}_{2}(g) $$ The volume of the balloon was \(4800 \mathrm{~m}^{3}\) and the loss of hydrogen gas during filling was estimated at \(20 . \%\). What mass of iron splints and \(98 \%\) (by mass) \(\mathrm{H}_{2} \mathrm{SO}_{4}\) were needed to ensure the complete filling of the balloon? Assume a temperature of \(0^{\circ} \mathrm{C}, \mathrm{a}\) pressure of \(1.0\) atm during filling, and \(100 \%\) yield.
A gas sample containing \(1.50 \mathrm{~mol}\) at \(25^{\circ} \mathrm{C}\) exerts a pressure of 400 . torr. Some gas is added to the same container and the temperature is increased to \(50 .{ }^{\circ} \mathrm{C}\). If the pressure increases to 800 . torr, how many moles of gas were added to the container? Assume a constant-volume container.
As \(\mathrm{NH}_{3}(g)\) is decomposed into nitrogen gas and hydrogen gas at constant pressure and temperature, the volume of the product gases collected is twice the volume of \(\mathrm{NH}_{3}\) reacted. Explain. As \(\mathrm{NH}_{3}(g)\) is decomposed into nitrogen gas and hydrogen gas at constant volume and temperature, the total pressure increases by some factor. Why the increase in pressure and by what factor does the total pressure increase when reactants are completely converted into products? How do the partial pressures of the product gases compare to each other and to the initial pressure of \(\mathrm{NH}_{3}\) ?
Consider three identical flasks filled with different gases. Flask A: \(\mathrm{CO}\) at 760 torr and \(0^{\circ} \mathrm{C}\) Flask B: \(\mathrm{N}_{2}\) at 250 torr and \(0^{\circ} \mathrm{C}\) Flask C: \(\mathrm{H}_{2}\) at 100 torr and \(0^{\circ} \mathrm{C}\) a. In which flask will the molecules have the greatest average kinetic energy? b. In which flask will the molecules have the greatest average velocity?
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