Chapter 5: Problem 25
Which noble gas has the smallest density at STP? Explain.
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Chapter 5: Problem 25
Which noble gas has the smallest density at STP? Explain.
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Silane, \(\mathrm{SiH}_{4}\), is the silicon analogue of methane, \(\mathrm{CH}_{4}\). It is prepared industrially according to the following equations: $$ \begin{aligned} \mathrm{Si}(s)+3 \mathrm{HCl}(g) & \longrightarrow \mathrm{HSiCl}_{3}(l)+\mathrm{H}_{2}(g) \\ 4 \mathrm{HSiCl}_{3}(l) & \longrightarrow \mathrm{SiH}_{4}(g)+3 \mathrm{SiCl}_{4}(l) \end{aligned} $$ a. If \(156 \mathrm{~mL} \mathrm{HSiCl}_{3}(d=1.34 \mathrm{~g} / \mathrm{mL})\) is isolated when \(15.0 \mathrm{~L}\) \(\mathrm{HCl}\) at \(10.0 \mathrm{~atm}\) and \(35^{\circ} \mathrm{C}\) is used, what is the percent yield of \(\mathrm{HSiCl}_{3} ?\) b. When \(156 \mathrm{~mL} \mathrm{HSiCl}_{3}\) is heated, what volume of \(\mathrm{SiH}_{4}\) at \(10.0\) atm and \(35^{\circ} \mathrm{C}\) will be obtained if the percent yield of the reaction is \(93.1 \%\) ?
We-state that the ideal gas law tends to hold best at low pressures and high temperatures. Show how the van der Waals equation simplifies to the ideal gas law under these conditions.
A gauge on a compressed gas cylinder reads 2200 psi (pounds per square inch; 1 atm \(=14.7\) psi). Express this pressure in each of the following units. a. standard atmospheres b. megapascals (MPa) c. torr
In the "Méthode Champenoise," grape juice is fermented in a wine bottle to produce sparkling wine. The reaction is $$ \mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}(a q) \longrightarrow 2 \mathrm{C}_{2} \mathrm{H}_{3} \mathrm{OH}(a q)+2 \mathrm{CO}_{2}(g) $$ Fermentation of \(750 . \mathrm{mL}\) grape juice (density \(=1.0 \mathrm{~g} / \mathrm{cm}^{3}\) ) is allowed to take place in a bottle with a total volume of \(825 \mathrm{~mL}\) until \(12 \%\) by volume is ethanol \(\left(\mathrm{C}_{2} \mathrm{H}_{3} \mathrm{OH}\right)\). Assuming that the \(\mathrm{CO}_{2}\) is insoluble in \(\mathrm{H}_{2} \mathrm{O}\) (actually, a wrong assumption), what would be the pressure of \(\mathrm{CO}_{2}\) inside the wine bottle at \(25^{\circ} \mathrm{C}\) ? (The density of ethanol is \(0.79 \mathrm{~g} / \mathrm{cm}^{3}\).)
A piece of solid carbon dioxide, with a mass of \(7.8 \mathrm{~g}\), is placed in a 4.0-L otherwise empty container at \(27^{\circ} \mathrm{C}\). What is the pressure in the container after all the carbon dioxide vaporizes? If \(7.8 \mathrm{~g}\) solid carbon dioxide were placed in the same container but it already contained air at 740 torr, what would be the partial pressure of carbon dioxide and the total pressure in the container after the carbon dioxide vaporizes?
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