Chapter 22: Problem 89
Write the sequence of all possible tetrapeptides composed of the following amino acids. a. two phenylalanines and two glycines b. two phenylalanines, glycine, and alanine
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Chapter 22: Problem 89
Write the sequence of all possible tetrapeptides composed of the following amino acids. a. two phenylalanines and two glycines b. two phenylalanines, glycine, and alanine
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How many different pentapeptides can be formed using five different amino acids?
Polychlorinated dibenzo- \(p\) -dioxins (PCDDs) are highly toxic substances that are present in trace amounts as by-products of some chemical manufacturing processes. They have been implicated in a number of environmental incidents- for example, the chemical contamination at Love Canal and the herbicide spraying The most toxic \(\mathrm{PCDD}\) is \(2,3,7,8\) -tetrachloro-dibenzo- \(p\) -dioxin. Draw the structure of this compound. Also draw the structures of two other isomers containing four chlorine atoms.
Alcohols are very useful starting materials for the production of many different compounds. The following conversions, starting with 1-butanol, can be carried out in two or more steps. Show the steps (reactants/catalysts) you would follow to carry out the conversions, drawing the formula for the organic product in each step. For each step, a major product must be produced. See Exercise 62. (Hint: In the presence of \(\mathrm{H}^{+}\), an alcohol is converted into an alkene and water. This is the exact reverse of the reaction of adding water to an alkene to form an alcohol.) a. 1 -butanol \(\longrightarrow\) butane b. 1-butanol \(\longrightarrow 2\) -butanone
Why is glycine not optically active?
Ethylene oxide, is an important industrial chemical. Although most ethers are unreactive, ethylene oxide is quite reactive. It resembles \(\mathrm{C}_{2} \mathrm{H}_{4}\) in its reactions in that addition reactions occur across the \(\mathrm{C}-\mathrm{O}\) bond in ethylene oxide. a. Why is ethylene oxide so reactive? (Hint: Consider the bond angles in ethylene oxide as compared with those predicted by the VSEPR model.) b. Ethylene oxide undergoes addition polymerization, forming a polymer used in many applications requiring a nonionic surfactant. Draw the structure of this polymer.
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