Chapter 21: Problem 49
The \(\mathrm{CrF}_{6}^{4-}\) ion is known to have four unpaired electrons. Does the \(\mathrm{F}^{-}\) ligand produce a strong or weak field?
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Chapter 21: Problem 49
The \(\mathrm{CrF}_{6}^{4-}\) ion is known to have four unpaired electrons. Does the \(\mathrm{F}^{-}\) ligand produce a strong or weak field?
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Sketch and explain the most likely pattem for the crystal field diagram for the complex ion trans-diamminetetracyanonickelate(II), where \(\mathrm{CN}^{-}\) produces a much stronger crystal field than \(\mathrm{NH}_{3}\). Explain completely and label the \(d\) orbitals in your diagram. Assume the \(\mathrm{NH}_{3}\) ligands lie on the \(z\) axis.
Acetylacetone (see Exercise 69, part a), abbreviated acacH, is a bidentate ligand. It loses a proton and coordinates as acac \(^{-}\), as shown below: Acetylacetone reacts with an ethanol solution containing a salt of europium to give a compound that is \(40.1 \% \mathrm{C}\) and \(4.71 \% \mathrm{H}\) by mass. Combustion of \(0.286 \mathrm{~g}\) of the compound gives \(0.112 \mathrm{~g}\) \(\mathrm{Eu}_{2} \mathrm{O}_{3}\). Assuming the compound contains only \(\mathrm{C}, \mathrm{H}, \mathrm{O}\), and \(\mathrm{Eu}\), determine the formula of the compound formed from the reaction of acetylacetone and the europium salt. (Assume that the compound contains one europium ion.)
Give formulas for the following complex ions. a. tetrachloroferrate(III) ion b. pentaammineaquaruthenium(III) ion c. tetracarbonyldihydroxochromium(III) ion d. amminetrichloroplatinate(II) ion
. Which is more likely to be paramagnetic, \(\mathrm{Fe}(\mathrm{CN})_{6}^{4-}\) or \(\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}^{2+}\) ? Explain.
A coordination compound of cobalt(III) contains four ammonia molecules, one sulfate ion, and one chloride ion. Addition of aqueous \(\mathrm{BaCl}_{2}\) solution to an aqueous solution of the compound gives no precipitate. Addition of aqueous \(\mathrm{AgNO}_{3}\) to an aqueous solution of the compound produces a white precipitate. Propose a structure for this coordination compound.
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