Chapter 21: Problem 48
Draw the \(d\) -orbital splitting diagrams for the octahedral complex ions of each of the following. a. \(\mathrm{Zn}^{2+}\) b. \(\mathrm{Co}^{2+}\) (high and low spin) c. \(\mathrm{Ti}^{3+}\)
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Chapter 21: Problem 48
Draw the \(d\) -orbital splitting diagrams for the octahedral complex ions of each of the following. a. \(\mathrm{Zn}^{2+}\) b. \(\mathrm{Co}^{2+}\) (high and low spin) c. \(\mathrm{Ti}^{3+}\)
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The carbonate ion \(\left(\mathrm{CO}_{3}^{2-}\right)\) can act as either a monodentate or a bidentate ligand. Draw a picture of \(\mathrm{CO}_{3}^{2-}\) coordinating to a metal ion as a monodentate and as a bidentate ligand. The carbonate ion can also act as a bridge between two metal ions. Draw a picture of a \(\mathrm{CO}_{3}^{2-}\) ion bridging between two metal ions.
Hemoglobin (abbreviated \(\mathrm{Hb}\) ) is a protein that is responsible for the transport of oxygen in the blood of mammals. Each hemoglobin molecule contains four iron atoms that serve as the binding sites for \(\mathrm{O}_{2}\) molecules. The oxygen binding is \(\mathrm{pH}\) dependent. The relevant equilibrium reaction is $$\mathrm{HbH}_{4}{ }^{4+}(a q)+4 \mathrm{O}_{2}(g) \rightleftharpoons \mathrm{Hb}\left(\mathrm{O}_{2}\right)_{4}(a q)+4 \mathrm{H}^{+}(a q)$$ Use Le Ch芒telier's principle to answer the following. a. What form of hemoglobin, \(\mathrm{HbH}_{4}^{4+}\) or \(\mathrm{Hb}\left(\mathrm{O}_{2}\right)_{4}\), is favored in the lungs? What form is favored in the cells? b. When a person hyperventilates, the concentration of \(\mathrm{CO}_{2}\) in the blood decreases. How does this affect the oxygenbinding equilibrium? How does breathing into a paper bag help to counteract this effect? (Hint: \(\mathrm{CO}_{2}\) reacts with water to produce carbonic acid.) c. When a person has suffered a cardiac arrest, an injection of a sodium bicarbonate solution is given. Why is this step necessary?
A certain first-row transition metal ion forms many different colored solutions. When four coordination compounds of this metal, each having the same coordination number, are dissolved in wa ter, the colors of the solutions are red, yellow, green, and blue Further experiments reveal that two of the complex ions are para magnetic with four unpaired electrons and the other two are dia magnetic. What can be deduced from this information about th four coordination compounds?
A metal ion in a high-spin octahedral complex has two more unpaired electrons than the same ion does in a low-spin octahedral complex. Name some possible metal ions for which this would be true.
a. Calculate the molar solubility of AgBr in pure water. \(K_{\text {sp }}\) for AgBr is \(5.0 \times 10^{-13}\) b. Calculate the molar solubility of AgBr in \(3.0 M \mathrm{NH}_{3}\). The overall formation constant for \(\mathrm{Ag}\left(\mathrm{NH}_{3}\right)_{2}^{+}\) is \(1.7 \times 10^{7}\), that is, \(\mathrm{Ag}^{+}(a q)+2 \mathrm{NH}_{3}(a q) \longrightarrow \mathrm{Ag}\left(\mathrm{NH}_{3}\right)_{2}^{+}(a q) \quad K=1.7 \times 10^{7}\) c. Compare the calculated solubilities from parts a and b. Explain any differences. d. What mass of \(\mathrm{AgBr}\) will dissolve in \(250.0 \mathrm{~mL}\) of \(3.0 \mathrm{M} \mathrm{NH}_{3}\) ? e. What effect does adding \(\mathrm{HNO}_{3}\) have on the solubilities calculated in parts a and \(\mathrm{b}\) ?
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