Chapter 20: Problem 90
In large doses, selenium is toxic. However, in moderate intake, selenium is a physiologically important element. How is selenium physiologically important?
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Chapter 20: Problem 90
In large doses, selenium is toxic. However, in moderate intake, selenium is a physiologically important element. How is selenium physiologically important?
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Trisodium phosphate (TSP) is an effective grease remover. Like many cleaners, TSP acts as a base in water. Write a balanced equation to account for this basic behavior.
The oxyanion of nitrogen in which it has the highest oxidation state is the nitrate ion \(\left(\mathrm{NO}_{3}^{-}\right)\). The corresponding oxyanion of phosphorus is \(\mathrm{PO}_{4}^{3-}\). The \(\mathrm{NO}_{4}{ }^{3-}\) ion is known but not very stable. The \(\mathrm{PO}_{3}^{-}\) ion is not known. Account for these differences in terms of the bonding in the four anions.
Use bond energies (Table 8.4) to show that the preferred products for the decomposition of \(\mathrm{N}_{2} \mathrm{O}_{3}\) are \(\mathrm{NO}_{2}\) and \(\mathrm{NO}\) rather than \(\mathrm{O}_{2}\) and \(\mathrm{N}_{2} \mathrm{O}\). (The \(\mathrm{N}-\mathrm{O}\) single bond energy is \(201 \mathrm{~kJ} / \mathrm{mol} .\) ) Hint: Consider the reaction kinetics.
The xenon halides and oxides are isoelectronic with many other compounds and ions containing halogens. Give a molecule or ion in which iodine is the central atom that is isoelectronic with each of the following. a. xenon tetroxide d. xenon tetrafluoride b. xenon trioxide e. xenon hexafluoride c. xenon difluoride
Lewis structures can be used to understand why some molecules react in certain ways. Write the Lewis structure for the reactants and products in the reactions described below. a. Nitrogen dioxide dimerizes to produce dinitrogen tetroxide. b. Boron trihydride accepts a pair of electrons from ammonia, forming \(\mathrm{BH}_{3} \mathrm{NH}_{3}\). Give a possible explanation for why these two reactions occur.
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