Chapter 20: Problem 56
Trisodium phosphate (TSP) is an effective grease remover. Like many cleaners, TSP acts as a base in water. Write a balanced equation to account for this basic behavior.
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Chapter 20: Problem 56
Trisodium phosphate (TSP) is an effective grease remover. Like many cleaners, TSP acts as a base in water. Write a balanced equation to account for this basic behavior.
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a. Many biochemical reactions that occur in cells require relatively high concentrations of potassium ion \(\left(\mathrm{K}^{+}\right) .\) The concentration of \(\mathrm{K}^{+}\) in muscle cells is about \(0.15 \mathrm{M}\). The concentration of \(\mathrm{K}^{+}\) in blood plasma is about \(0.0050 M\). The high internal concentration in cells is maintained by pumping \(\mathrm{K}^{+}\) from the plasma. How much work must be done to transport \(1.0 \mathrm{~mol} \mathrm{~K}^{+}\) from the blood to the inside of a muscle cell at \(37^{\circ} \mathrm{C}\) (normal body temperature)? b. When \(1.0 \mathrm{~mol} \mathrm{~K}^{+}\) is transferred from blood to the cells, do any other ions have to be transported? Why or why not? c. Cells use the hydrolysis of adenosine triphosphate, abbreviated ATP, as a source of energy. Symbolically, this reaction can be represented as $$\operatorname{ATP}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{ADP}(a q)+\mathrm{H}_{2} \mathrm{PO}_{4}^{-}(a q)$$ where ADP represents adenosine diphosphate. For this reaction at \(37^{\circ} \mathrm{C}, K=1.7 \times 10^{5}\). How many moles of ATP must be hydrolyzed to provide the energy for the transport of \(1.0 \mathrm{~mol}\) \(\mathrm{K}^{+}\) ? Assume standard conditions for the ATP hydrolysis reaction.
The space shuttle orbiter utilizes the oxidation of methylhydrazine by dinitrogen tetroxide for propulsion: \(4 \mathrm{~N}_{2} \mathrm{H}_{3} \mathrm{CH}_{3}(l)+5 \mathrm{~N}_{2} \mathrm{O}_{4}(l) \longrightarrow 12 \mathrm{H}_{2} \mathrm{O}(g)+9 \mathrm{~N}_{2}(g)+4 \mathrm{CO}_{2}(g)\) Calculate \(\Delta H^{\circ}\) for this reaction using data in Appendix \(4 .\)
Diagonal relationships in the periodic table exist as well as the vertical relationships. For example, Be and Al are similar in some of their properties as are \(\mathrm{B}\) and \(\mathrm{Si}\). Rationalize why these diagonal relationships hold for properties such as size, ionization energy, and electron affinity.
Arsenic reacts with oxygen to form oxides that react with water in a manner analogous to that of the phosphorus oxides. Write balanced chemical equations describing the reaction of arsenic with oxygen and the reaction of the resulting oxide with water.
Sulfur forms a wide variety of compounds in which it has \(+6\), \(+4,+2,0\), and \(-2\) oxidation states. Give examples of sulfur compounds having each of these oxidation states.
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