Chapter 20: Problem 2
List two major industrial uses of hydrogen.
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Chapter 20: Problem 2
List two major industrial uses of hydrogen.
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The \(\mathrm{N}_{2} \mathrm{O}\) molecule is linear and polar. a. On the basis of this experimental evidence, which arrangement, NNO or NON, is correct? Explain your answer. b. On the basis of your answer to part a, write the Lewis structure of \(\mathrm{N}_{2} \mathrm{O}\) (including resonance forms). Give the formal charge on each atom and the hybridization of the central atom. c. How would the multiple bonding in $$: \mathrm{N} \equiv \mathrm{N}-\mathrm{O}$$ be described in terms of orbitals?
Nitric acid is produced commercially by the Ostwald process, represented by the following equations: $$\begin{aligned}4 \mathrm{NH}_{3}(\mathrm{~g})+5 \mathrm{O}_{2}(g) & \longrightarrow 4 \mathrm{NO}(g)+6 \mathrm{H}_{2} \mathrm{O}(g) \\ 2 \mathrm{NO}(g)+\mathrm{O}_{2}(g) & \longrightarrow 2 \mathrm{NO}_{2}(g) \\ 3 \mathrm{NO}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(l) & \longrightarrow 2 \mathrm{HNO}_{3}(a q)+\mathrm{NO}(g)\end{aligned}$$ What mass of \(\mathrm{NH}_{3}\) must be used to produce \(1.0 \times 10^{6} \mathrm{~kg} \mathrm{HNO}_{3}\) by the Ostwald process? Assume \(100 \%\) yield in each reaction and assume that the NO produced in the third step is not recycled.
How do the acidities of the aqueous solutions of the alkaline earth metal ions \(\left(\mathrm{M}^{2+}\right)\) change in going down the group?
Slaked lime, \(\mathrm{Ca}(\mathrm{OH})_{2}\), is used to soften hard water by removing calcium ions from hard water through the reaction \(\mathrm{Ca}(\mathrm{OH})_{2}(a q)+\mathrm{Ca}^{2+}(a q)+2 \mathrm{HCO}_{3}^{-}(a q) \rightarrow\) Although \(\mathrm{CaCO}_{3}(s)\) is considered insoluble, some of it does dissolve in aqueous solutions. Calculate the molar solubility of \(\mathrm{CaCO}_{3}\) in water \(\left(K_{\mathrm{sp}}=8.7 \times 10^{-9}\right)\)
Which do you think would be the greater health hazard, the release of a radioactive nuclide of Sr or a radioactive nuclide of Xe into the environment? Assume the amount of radioactivity is the same in each case. Explain your answer on the basis of the chemical properties of Sr and Xe. Why are the chemical properties of a radioactive substance important in assessing its potential health hazards?
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