Chapter 20: Problem 1
Although the earth was formed from the same interstellar material as the sun, there is little elemental hydrogen \(\left(\mathrm{H}_{2}\right)\) in the earth's atmosphere. Explain.
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Chapter 20: Problem 1
Although the earth was formed from the same interstellar material as the sun, there is little elemental hydrogen \(\left(\mathrm{H}_{2}\right)\) in the earth's atmosphere. Explain.
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Lead forms compounds in the \(+2\) and \(+4\) oxidation states. All lead(II) halides are known (and are known to be ionic). Only \(\mathrm{PbF}_{4}\) and \(\mathrm{PbCl}_{4}\) are known among the possible lead(IV) halides. Presumably lead(IV) oxidizes bromide and iodide ions, producing the lead(II) halide and the free halogen: Suppose \(25.00 \mathrm{~g}\) of a lead(IV) halide reacts to form \(16.12 \mathrm{~g}\) of a lead(II) halide and the free halogen. Identify the halogen.
Draw Lewis structures for the \(\mathrm{AsCl}_{4}^{+}\) and \(\mathrm{AsCl}_{6}^{-}\) ions. What type of reaction (acid-base, oxidation- reduction, or the like) is the following? $$2 \mathrm{AsCl}_{5}(g) \longrightarrow \mathrm{AsCl}_{4} \mathrm{AsCl}_{6}(s)$$
One harmful effect of acid rain is the deterioration of structures and statues made of marble or limestone, both of which are essentially calcium carbonate. The reaction of calcium carbonate with sulfuric acid yields carbon dioxide, water, and calcium sulfate. Because calcium sulfate is marginally soluble in water, part of the object is washed away by the rain. Write a balanced chemical equation for the reaction of sulfuric acid with calcium carbonate.
Ammonia is produced by the Haber process, in which nitrogen and hydrogen are reacted directly using an iron mesh impregnated with oxides as a catalyst. For the reaction $$\mathrm{N}_{2}(g)+3 \mathrm{H}_{2}(g) \rightleftharpoons 2 \mathrm{NH}_{3}(g)$$ equilibrium constants \(\left(K_{\mathrm{p}}\right.\) values) as a function of temperature are \(300^{\circ} \mathrm{C}, \quad 4.34 \times 10^{-3}\) \(500^{\circ} \mathrm{C}, \quad 1.45 \times 10^{-5}\) \(600^{\circ} \mathrm{C}, \quad 2.25 \times 10^{-6}\) Is the reaction exothermic or endothermic?
How do the acidities of the aqueous solutions of the alkaline earth metal ions \(\left(\mathrm{M}^{2+}\right)\) change in going down the group?
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