Chapter 11: Problem 27
Explain the terms isotonic solution, crenation, and hemolysis.
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Chapter 11: Problem 27
Explain the terms isotonic solution, crenation, and hemolysis.
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Is molality or molarity dependent on temperature? Explain your answer. Why is molality, and not molarity, used in the equations describing freezing-point depression and boiling-point elevation?
Rubbing alcohol contains 585 g isopropanol \(\left(\mathrm{C}_{3} \mathrm{H}_{7} \mathrm{OH}\right)\) per liter (aqueous solution). Calculate the molarity.
In flushing and cleaning columns used in liquid chromatography to remove adsorbed contaminants, a series of solvents is used. Hexane \(\left(\mathrm{C}_{6} \mathrm{H}_{14}\right)\), chloroform \(\left(\mathrm{CHCl}_{3}\right)\), methanol \(\left(\mathrm{CH}_{3} \mathrm{OH}\right)\), and water are passed through the column in that order. Rationalize the order in terms of intermolecular forces and the mutual solu- bility (miscibility) of the solvents.
In a coffee-cup calorimeter, \(1.60 \mathrm{~g} \mathrm{NH}_{4} \mathrm{NO}_{3}\) was mixed with \(75.0 \mathrm{~g}\) water at an initial temperature \(25.00^{\circ} \mathrm{C}\). After dissolution the salt, the final temperature of the calorimeter contents was \(23.34^{\circ} \mathrm{C}\). a. Assuming the solution has a heat capacity of \(4.18 \mathrm{~J} / \mathrm{g} \cdot{ }^{\circ} \mathrm{C}\), and assuming no heat loss to the calorimeter, calculate the enthalpy of solution \(\left(\Delta H_{\text {soln }}\right)\) for the dissolution of \(\mathrm{NH}_{4} \mathrm{NO}_{3}\) in units of \(\mathrm{kJ} / \mathrm{mol}\). b. If the enthalpy of hydration for \(\mathrm{NH}_{4} \mathrm{NO}_{3}\) is \(-630 . \mathrm{kJ} / \mathrm{mol}\), calculate the lattice energy of \(\mathrm{NH}_{4} \mathrm{NO}_{3}\).
Consider a beaker of salt water sitting open in a room. Over time, does the vapor pressure increase, decrease, or stay the same? Explain.
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