Chapter 10: Problem 26
Compare and contrast the structures of the following solids. a. diamond versus graphite b. silica versus silicates versus glass
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Chapter 10: Problem 26
Compare and contrast the structures of the following solids. a. diamond versus graphite b. silica versus silicates versus glass
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Rationalize the differences in physical properties in terms of intermolecular forces for the following organic compounds. Compare the first three substances with each other, compare the last three with each other, and then compare all six. Can you account for any anomalies? $$ \begin{array}{|lccc|} \hline & \text { bp }\left({ }^{\circ} \mathrm{C}\right) & \operatorname{mp}\left({ }^{\circ} \mathrm{C}\right) & \Delta H_{\text {vap }}(\mathbf{k J} / \text { mol }) \\ \hline \text { Benzene, } \mathrm{C}_{6} \mathrm{H}_{6} & 80 & 6 & 33.9 \\ \text { Naphthalene, } & & & \\ \mathrm{C}_{10} \mathrm{H}_{8} & 218 & 80 & 51.5 \\ \text { Carbon tetra- } & & & \\ \text { chloride } & 76 & -23 & 31.8 \\ \text { Acetone, } & & & \\ \mathrm{CH}_{3} \mathrm{COCH}_{3} & 56 & -95 & 31.8 \\ \text { Acetic acid, } & & & \\ \mathrm{CH}_{3} \mathrm{CO}_{2} \mathrm{H} & 118 & 17 & 39.7 \\ \text { Benzoic acid, } & & & \\ \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{CO}_{2} \mathrm{H} & 249 & 122 & 68.2 \\\ \hline \end{array} $$
Explain how the evaporation of water acts as a coolant for the earth.
Hydrogen bonding is a special case of very strong dipole-dipole interactions possible among only certain atoms. What atoms in addition to hydrogen are necessary for hydrogen bonding? How does the small size of the hydrogen atom contribute to the unusual strength of the dipole-dipole forces involved in hydrogen bonding?
Identify the most important types of interparticle forces present in the solids of each of the following substances. a. Ar e. \(\mathrm{CH}_{4}\) b. \(\mathrm{HCl}\) f. \(\mathrm{CO}\) c. HF g. \(\mathrm{NaNO}_{3}\) d. \(\mathrm{CaCl}_{2}\)
Rationalize why chalk (calcium carbonate) has a higher melting point than motor oil (large compound made from carbon and hydrogen), which has a higher melting point than water and engages in relatively strong hydrogen bonding interactions.
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