/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 10 Which are stronger, intermolecul... [FREE SOLUTION] | 91影视

91影视

Log out

Learning Materials

Features

Discover

Chapter 10: Problem 10

Which are stronger, intermolecular or intramolecular forces for a given molecule? What observation(s) have you made that support this? Explain.

Short Answer

Expert verified
Intramolecular forces, such as covalent, ionic, and metallic bonds, are generally stronger than intermolecular forces, like hydrogen bonding, dipole-dipole interactions, and London dispersion forces. Observations supporting this claim include the differences in boiling and melting points of substances with varying bond types and the fact that chemical reactions involve the breaking and rearrangement of intramolecular bonds, not intermolecular forces.

Step by step solution

01

Intermolecular vs Intramolecular forces

Intermolecular forces occur between molecules, while intramolecular forces occur within a molecule. Intermolecular forces include hydrogen bonding, dipole-dipole interactions, and London dispersion forces. Intramolecular forces, on the other hand, involve chemical bonds, such as covalent, ionic, and metallic bonds.
02

Comparing the strength of Intermolecular and Intramolecular forces

Generally, intramolecular forces (chemical bonds) are stronger than intermolecular forces. This is because intramolecular forces involve the sharing or transfer of electrons between atoms within a molecule, leading to the formation of stable chemical bonds. Intermolecular forces, however, are weaker interactions that result from fluctuations in electron distribution around molecules and affect properties such as boiling and melting points, solubility, and viscosity.
03

Observation: Boiling and Melting points

One observation that supports this claim is the difference in boiling and melting points of substances with different types of intramolecular forces. For example, substances with strong covalent bonds, such as diamonds, have very high melting points compared to substances with weaker intermolecular forces, such as water. This indicates that the strength of intramolecular forces plays a significant role in determining the boiling and melting points of substances.
04

Observation: Chemical reactions

Another observation is during chemical reactions; only the intramolecular bonds are broken and rearranged to form new products. Intermolecular forces are not strong enough to cause such changes in the molecular structure. This observation also highlights that intramolecular forces are stronger than intermolecular forces. In conclusion, intramolecular forces are generally stronger than intermolecular forces. Observations such as differences in boiling and melting points, as well as the breaking and forming of chemical bonds during reactions, support this claim.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91影视!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Iodine, like most substances, exhibits only three phases: solid, liquid, and vapor. The triple point of iodine is at 90 torr and \(115^{\circ} \mathrm{C}\). Which of the following statements concerning liquid \(\mathrm{I}_{2}\) must be true? Explain your answer. a. \(\mathrm{I}_{2}(l)\) is more dense than \(\mathrm{I}_{2}(g)\). b. \(\mathrm{I}_{2}(l)\) cannot exist above \(115^{\circ} \mathrm{C}\). c. \(\mathrm{I}_{2}(l)\) cannot exist at 1 atmosphere pressure. d. \(\mathrm{I}_{2}(l)\) cannot have a vapor pressure greater than 90 torr. e. \(\mathrm{I}_{2}(l)\) cannot exist at a pressure of 10 torr.

A metallic solid with atoms in a face-centered cubic unit cell with an edge length of \(392 \mathrm{pm}\) has a density of \(21.45 \mathrm{~g} / \mathrm{cm}^{3}\). Calculate the atomic mass and the atomic radius of the metal. Identify the metal.

When 1 mol benzene is vaporized at a constant pressure of \(1.00\) atm and at its boiling point of \(353.0 \mathrm{~K}, 30.79 \mathrm{~kJ}\) of energy (heat) is absorbed and the volume change is \(+28.90 \mathrm{~L}\). What are \(\Delta E\) and \(\Delta H\) for this process?

Consider the following data for xenon: Triple point: \(-121^{\circ} \mathrm{C}, 280\) torr Normal melting point: \(\quad-112^{\circ} \mathrm{C}\) Normal boiling point: \(-107^{\circ} \mathrm{C}\) Which is more dense, \(\operatorname{Xe}(s)\) or \(\operatorname{Xe}(I) ?\) How do the melting point and boiling point of xenon depend on pressure?

Why do liquids have a vapor pressure? Do all liquids have vapor pressures? Explain. Do solids exhibit vapor pressure? Explain. How does vapor pressure change with changing temperature? Explain.
See all solutions

Recommended explanations on Chemistry Textbooks

Chemical Reactions

Read Explanation

Chemistry Branches

Read Explanation

The Earths Atmosphere

Read Explanation

Chemical Analysis

Read Explanation

Organic Chemistry

Read Explanation

Physical Chemistry

Read Explanation
View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.