Chapter 4: Problem 30
Identify each of the following species as a Br酶nsted acid, base, or both: (a) HI, (b) \(\mathrm{C}_{2} \mathrm{H}_{3} \mathrm{O}_{2}^{-},\) (c) \(\mathrm{H}_{2} \mathrm{PO}_{4}^{-}\), (d) \(\mathrm{HSO}_{4}^{-}\).
Short Answer
Expert verified
(a) Acid; (b) Base; (c) Both; (d) Both.
Step by step solution
01
Understanding Br酶nsted Acids and Bases
A Br酶nsted acid is a substance that can donate a proton (H鈦), while a Br酶nsted base is a substance that can accept a proton. Some substances can act as both, donating or accepting a proton depending on the context.
02
Analyzing HI
HI, or hydrogen iodide, can donate a proton to form I鈦. Since it donates a proton, HI is classified as a Br酶nsted acid.
03
Analyzing C鈧侶鈧僌鈧傗伝
C鈧侶鈧僌鈧傗伝, acetate ion, can accept a proton to form acetic acid (CH鈧僀OOH). Because it can accept a proton, it functions as a Br酶nsted base.
04
Analyzing H鈧侾O鈧勨伝
H鈧侾O鈧勨伝 (dihydrogen phosphate) can donate a proton to become HPO鈧劼测伝 or accept a proton to form H鈧働O鈧. Thus, it can act as both a Br酶nsted acid (donating) and a base (accepting).
05
Analyzing HSO鈧勨伝
HSO鈧勨伝 (hydrogen sulfate) can donate a proton to become SO鈧劼测伝 or accept a proton to return to H鈧係O鈧. Therefore, it acts as both a Br酶nsted acid and base.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Proton Donor
In the realm of chemistry, a proton donor is another name for a Br酶nsted acid. These substances have the ability to donate a proton, specifically a hydrogen ion (
H^+
), during chemical reactions. The process of donating a proton transforms the original molecule, creating a new product.
For instance, in the case of hydrogen iodide (HI), the substance donates its proton to become iodide ( I^- ). This transformation is a key characteristic of Br酶nsted acids. Essentially, when you think of proton donors, think of substances eager to give away their extra hydrogen ions to partake in and drive chemical reactions.
Understanding which species can donate protons helps in identifying them as Br酶nsted acids and predicting their behavior in reactions.
For instance, in the case of hydrogen iodide (HI), the substance donates its proton to become iodide ( I^- ). This transformation is a key characteristic of Br酶nsted acids. Essentially, when you think of proton donors, think of substances eager to give away their extra hydrogen ions to partake in and drive chemical reactions.
Understanding which species can donate protons helps in identifying them as Br酶nsted acids and predicting their behavior in reactions.
Proton Acceptor
A proton acceptor is a term used to describe a Br酶nsted base. These entities have the ability to accept a proton from their surroundings, which leads to the formation of a new molecule.
When a substance acts as a proton acceptor, it typically starts with a negative charge or a lone pair of electrons that can easily accommodate an incoming proton.
For example, the acetate ion ( C_2H_3O_2^- ) acts as a proton acceptor by bonding with a proton to form acetic acid ( CH_3COOH ). By accepting this proton, the substance is stabilized and transformed, showcasing typical behavior of Br酶nsted bases.
Recognizing proton acceptors is crucial for understanding how certain reactions progress, as they guide the transfer and transformation of protons throughout the process.
When a substance acts as a proton acceptor, it typically starts with a negative charge or a lone pair of electrons that can easily accommodate an incoming proton.
For example, the acetate ion ( C_2H_3O_2^- ) acts as a proton acceptor by bonding with a proton to form acetic acid ( CH_3COOH ). By accepting this proton, the substance is stabilized and transformed, showcasing typical behavior of Br酶nsted bases.
Recognizing proton acceptors is crucial for understanding how certain reactions progress, as they guide the transfer and transformation of protons throughout the process.
HI Classification
Hydrogen iodide, written chemically as HI, is a classic example of a Br酶nsted acid. This classification stems from its capacity to donate a proton, a fundamental requirement for any Br酶nsted acid.
When HI gives away its proton, it leaves behind an iodide anion ( I^- ). This reaction forms new compounds and is indicative of HI's behavior as a Br酶nsted acid.
Overall, knowing specific molecules like HI helps further understand the broader concept of acids and their roles in chemical reactions. Knowing it donates protons is essential to classifying it correctly in reactions with other substances.
When HI gives away its proton, it leaves behind an iodide anion ( I^- ). This reaction forms new compounds and is indicative of HI's behavior as a Br酶nsted acid.
Overall, knowing specific molecules like HI helps further understand the broader concept of acids and their roles in chemical reactions. Knowing it donates protons is essential to classifying it correctly in reactions with other substances.
H鈧侾O鈧勨伝 Amphoteric Behavior
The concept of amphoteric behavior refers to a molecule's ability to act both as an acid and a base, depending upon the circumstances. The dihydrogen phosphate ion (
H_2PO_4^-
) brilliantly exemplifies this unique dual behavior.
As an acid, H_2PO_4^- can donate a proton, transforming into HPO_4^{2-} . This ability to lose a proton to another molecule highlights its acidic properties.
On the flip side, when acting as a base, H_2PO_4^- accepts a proton, forming H_3PO_4 (phosphoric acid). This addition of a proton underscores its basic capabilities.
Understanding amphoteric behavior is important in assessing how certain compounds react diversely under varying conditions, providing more dynamic roles in chemical equations.
As an acid, H_2PO_4^- can donate a proton, transforming into HPO_4^{2-} . This ability to lose a proton to another molecule highlights its acidic properties.
On the flip side, when acting as a base, H_2PO_4^- accepts a proton, forming H_3PO_4 (phosphoric acid). This addition of a proton underscores its basic capabilities.
Understanding amphoteric behavior is important in assessing how certain compounds react diversely under varying conditions, providing more dynamic roles in chemical equations.