Chapter 3: Problem 75
When baking soda (sodium bicarbonate or sodium hydrogen carbonate, \(\mathrm{NaHCO}_{3}\) ) is heated, it releases carbon dioxide gas, which is responsible for the rising of cookies, doughnuts, and bread. (a) Write a balanced equation for the decomposition of the compound (one of the products is \(\mathrm{Na}_{2} \mathrm{CO}_{3}\) ). (b) Calculate the mass of \(\mathrm{NaHCO}_{3}\) required to produce \(20.5 \mathrm{~g}\) of \(\mathrm{CO}_{2}\)
Short Answer
Step by step solution
Write the Decomposition Reaction
Calculate Moles of CO2 Produced
Use Stoichiometry to Find Moles of NaHCO3 Needed
Calculate Mass of NaHCO3 Required
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Balanced Chemical Equation
For the decomposition of sodium bicarbonate (\(\text{NaHCO}_3\)), the equation is written as:\[ 2\,\text{NaHCO}_{3(s)} \rightarrow \text{Na}_{2}\text{CO}_{3(s)} + \text{H}_{2}\text{O}_{(g)} + \text{CO}_{2(g)} \]
- Each element is counted on both sides to ensure they match.
- For example, there are 2 sodium (Na) atoms on each side.
- This balance ensures that the reaction properly represents actual chemistry occurring at the atomic level.
Stoichiometry
By using the balanced equation for the decomposition of sodium bicarbonate, we establish a proportional relationship between reactants and products:
- The given equation shows that 2 moles of \(\text{NaHCO}_3\) yield 1 mole each of \(\text{Na}_{2}\text{CO}_3\), \(\text{H}_2\text{O}\), and \(\text{CO}_2\).
- This ratio is critical for calculating how much starting material is needed to produce a specific amount of a product.
Mole Calculations
- To calculate how much \(\text{NaHCO}_3\) is required to produce 20.5 grams of \(\text{CO}_2\), the moles of \(\text{CO}_2\) were first calculated.
- Using the formula \( n = \frac{m}{M} \), where \(n\) is the number of moles, \(m\) is mass, and \(M\) is molar mass, we found \(0.466\) moles of \(\text{CO}_2\).
- The balanced equation then indicated that this equates to \(0.932\) moles of \(\text{NaHCO}_3\).
- Finally, by converting these moles back to grams, the required mass of \(\text{NaHCO}_3\) was determined to be approximately 78.24 grams.
Chemical Reactions
- Sodium bicarbonate breaks down into sodium carbonate (\(\text{Na}_{2}\text{CO}_3\)), water (\(\text{H}_{2}\text{O}\)), and carbon dioxide (\(\text{CO}_2\)).
- This reaction is temperature-induced, showcasing how energy inputs can drive changes in chemical substances.