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Chapter 22: Problem 44

Describe and give examples of the applications of coordination compounds.

Short Answer

Expert verified
Coordination compounds are used in medicine, industrial catalysis, biological processes, dyes, and water treatment.

Step by step solution

01

Understanding Coordination Compounds

Coordination compounds are complex molecules that consist of a central metal atom or ion surrounded by molecules or ions called ligands. These compounds are found in a variety of chemical and biological systems and have widespread applications in different fields.
02

Application in Medicine

Coordination compounds are used in medicine as diagnostic and therapeutic agents. For example, cisplatin, a platinum-based coordination compound, is widely used in cancer chemotherapy to treat various types of cancer.
03

Use in Industrial Catalysis

Coordination compounds play a critical role in industrial catalysis. For instance, the Wilkinson's catalyst, which is a rhodium-based coordination compound, is used in the hydrogenation of alkenes in organic synthesis.
04

Role in Biological Processes

In biological systems, coordination compounds such as hemoglobin and chlorophyll are essential. Hemoglobin, which contains iron as the central metal, is crucial for oxygen transport in the blood, while chlorophyll, with magnesium as the central metal, is vital for photosynthesis in plants.
05

Application in Coloration

Coordination compounds are also used in dyes and pigments. For example, the pigment Prussian blue, composed of iron, is used in paints and inks for its intense blue color.
06

Use in Water Softening

In water treatment, coordination compounds called chelating agents are used to bind metal ions and prevent scale formation. EDTA (ethylenediaminetetraacetic acid) is a common chelating agent that removes calcium and magnesium ions in water softening processes.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ligands
Ligands are key players in the world of coordination compounds. They are molecules or ions that bind to a central metal atom to form a complex. Ligands donate electron pairs to the metal, creating a coordinate covalent bond. Their nature can be quite diverse, ranging from simple ions like chloride (Cl鈦�) to large organic molecules.
  • Types of Ligands: Ligands can be classified based on the number of points they attach to the metal.
    • Monodentate ligands: Attach through a single donor atom, like ammonia (NH鈧�).
    • Bidentate ligands: Attach through two donor atoms, such as ethylenediamine (en).
    • Polydentate ligands: Bind through multiple atoms, like EDTA.
  • Importance: Ligands influence stability, reactivity, and color of coordination compounds.
Without ligands, the central metal ion would not be able to form the complex structures seen in so many applications.
Cisplatin
Cisplatin is a prime example of a coordination compound used in medicine. It is a coordination complex with a platinum ion at its center surrounded by two chloride ions and two ammonia molecules. This structure makes it highly effective as a chemotherapy drug.
  • How it Works: Cisplatin works by forming cross-links with DNA in cancer cells, which interferes with their replication and ultimately induces cell death.
  • Applications: It is primarily used to treat testicular, ovarian, bladder, and lung cancers.
  • Advantages: It has been successful in increasing survival rates significantly.
Cisplatin showcases the vital role of coordination compounds in modern medicine, especially in cancer treatment.
Wilkinson's Catalyst
Wilkinson's catalyst is a well-known coordination compound used in reducing alkenes to alkanes through hydrogenation. This catalyst contains rhodium as its central metal, coordinated with specific ligands.
  • Composition: The catalyst is a coordination compound formed by rhodium, chlorine, and triphenylphosphine ligands (RhCl(PPh鈧�)鈧�).
  • Function: It facilitates the addition of hydrogen to double bonds in alkenes, converting them into saturated hydrocarbons.
  • Industrial Use: It is significant in producing fine chemicals and pharmaceuticals that require hydrogen addition.
Wilkinson's catalyst demonstrates the critical role of coordination compounds in industrial chemistry, optimizing reactions to be more efficient and selective.
Hemoglobin
Hemoglobin is a vital coordination compound crucial in the biological realm, especially for oxygen transport in mammals. The central metal in hemoglobin is iron, which is bonded to four nitrogen atoms from a porphyrin ring, creating a heme group.
  • Oxygen Binding: Hemoglobin can bind oxygen molecules, transporting them from the lungs to tissues.
  • Structure: Each hemoglobin molecule comprises four polypeptide chains, each containing a heme group.
  • Function: It efficiently releases oxygen in tissues where it is needed and picks up carbon dioxide for return transport to the lungs.
This process underscores the essential nature of coordination compounds like hemoglobin in maintaining life through efficient gas exchange. Hemoglobin's ability to carry oxygen makes it indispensable for energy production in cells.

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Most popular questions from this chapter

Complete the following statements for the complex ion \(\left[\mathrm{Co}(\mathrm{en})_{2}\left(\mathrm{H}_{2} \mathrm{O}\right) \mathrm{CN}\right]^{2+}\). (a) en is the abbreviation for______ (b) The oxidation number of \(\mathrm{Co}\) is _________ (c) The coordination number of Co is ________ (d) _________ is a bidentate ligand.

The \(\mathrm{Cr}^{3+}\) ion forms octahedral complexes with two neutral ligands \(\mathrm{X}\) and \(\mathrm{Y}\). The color of \(\mathrm{Cr} \mathrm{X}_{6}^{3+}\) is blue while that of \(\mathrm{Cr} \mathrm{Y}_{6}^{3+}\) is yellow. Which is a stronger field ligand, X or Y?

What are the systematic names for the following ions and compounds? (a) \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Cl}_{2}\right]^{+}\) (c) \(\left[\mathrm{Co}(\mathrm{en})_{2} \mathrm{Br}_{2}\right]^{+}\) (b) \(\left[\mathrm{Cr}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{Cl}_{3}\right]\) (d) \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right] \mathrm{Cl}_{3}\)

The absorption maximum for the complex ion \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\) occurs at \(470 \mathrm{nm} .\) (a) Predict the color of the complex, and (b) calculate the crystal field splitting in \(\mathrm{kJ} / \mathrm{mol}\)

A student in 1895 prepared three coordination compounds containing chromium, with the following properties: $$ \begin{array}{llc} & & \text { Cl }^{-} \text {Ions in Solution } \\ \text { Formula } & \text { Color } & \text { per Formula Unit } \\ \hline \text { (a) } \mathrm{Cr} \mathrm{Cl}_{3} \cdot 6 \mathrm{H}_{2} \mathrm{O} & \text { Violet } & 3 \\ \text { (b) } \mathrm{Cr} \mathrm{Cl}_{3} \cdot 6 \mathrm{H}_{2} \mathrm{O} & \text { Light green } & 2 \\ \text { (c) } \mathrm{Cr} \mathrm{Cl}_{3} \cdot 6 \mathrm{H}_{2} \mathrm{O} & \text { Dark green } & 1 \end{array} $$ Write modern formulas for these compounds, and suggest a method for confirming the number of \(\mathrm{Cl}^{-}\) ions present in solution in each case.
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