Chapter 21: Problem 34
Deforestation contributes to the greenhouse effect in two ways. What are they?
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Chapter 21: Problem 34
Deforestation contributes to the greenhouse effect in two ways. What are they?
These are the key concepts you need to understand to accurately answer the question.
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Methyl bromide \(\left(\mathrm{CH}_{3} \mathrm{Br},\right.\) b.p. \(\left.=3.6^{\circ} \mathrm{C}\right)\) is used as a soil fumigant to control insects and weeds. It is also a marine by-product. Photodissociation of the \(\mathrm{C}-\mathrm{Br}\) bond produces \(\mathrm{Br}\) atoms that can react with ozone similar to Cl, except more effectively. Do you expect \(\mathrm{CH}_{3} \mathrm{Br}\) to be photolyzed in the troposphere? The bond enthalpy of the \(\mathrm{C}-\mathrm{Br}\) bond is about \(293 \mathrm{~kJ} / \mathrm{mol}\).
The safety limits of ozone and carbon monoxide are 120 ppb by volume and 9 ppm by volume, respectively. Why does ozone have a lower limit?
The equilibrium constant \(\left(K_{P}\right)\) for the reaction \(2 \mathrm{CO}(g)\) \(+\mathrm{O}_{2}(g) \rightleftarrows 2 \mathrm{CO}_{2}(g)\) is \(1.4 \times 10^{90}\) at \(25^{\circ} \mathrm{C}\). Given this enormous value, why doesn't \(\mathrm{CO}\) convert totally to \(\mathrm{CO}_{2}\) in the troposphere?
The balance between \(\mathrm{SO}_{2}\) and \(\mathrm{SO}_{3}\) is important in understanding acid rain formation in the troposphere. From the following information at \(25^{\circ} \mathrm{C}\) : $$ \begin{aligned} \mathrm{S}(s)+\mathrm{O}_{2}(g) & \rightleftarrows \mathrm{SO}_{2}(g) & & K_{1}=4.2 \times 10^{52} \\ 2 \mathrm{~S}(s)+3 \mathrm{O}_{2}(g) & \rightleftarrows 2 \mathrm{SO}_{3}(g) & & K_{2}=9.8 \times 10^{128} \end{aligned} $$ calculate the equilibrium constant for the reaction: $$ 2 \mathrm{SO}_{2}(g)+\mathrm{O}_{2}(g) \rightleftarrows 2 \mathrm{SO}_{3}(g) $$
How are past temperatures determined from ice cores obtained from the Arctic or Antarctica? (Hint: Look up the stable isotopes of hydrogen and oxygen. How does energy required for vaporization depend on the masses of \(\mathrm{H}_{2} \mathrm{O}\) molecules containing different isotopes? How would you determine the age of an ice core?)
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