Chapter 16: Problem 162
Use Le Ch芒telier's principle to predict the effect of the following changes on the extent of hydrolysis of sodium nitrite \(\left(\mathrm{NaNO}_{2}\right)\) solution: (a) \(\mathrm{HCl}\) is added, (b) \(\mathrm{NaOH}\) is added, (c) \(\mathrm{NaCl}\) is added, (d) the solution is diluted.
Short Answer
Expert verified
(a) Decreases hydrolysis, (b) Increases hydrolysis, (c) No significant effect, (d) Increases hydrolysis.
Step by step solution
01
Understand the Reaction
Sodium nitrite (NaNO鈧) can be represented by the dissociation reaction: \[ \text{NaNO}_2 \rightleftharpoons \text{Na}^+ + \text{NO}_2^- \]. The NO鈧傗伝 anion can further react with water in a hydrolysis reaction: \[ \text{NO}_2^- + \text{H}_2\text{O} \rightleftharpoons \text{HNO}_2 + \text{OH}^- \]. Le Ch芒telier's principle states that if a system at equilibrium experiences a change in concentration, temperature, or pressure, the system will adjust to counteract that change and re-establish equilibrium.
02
Effect of Adding HCl
Adding HCl increases the concentration of H鈦 ions in the solution. According to Le Ch芒telier's principle, the equilibrium will shift to the left to produce more NO鈧傗伝 and consume OH鈦 ions, decreasing the extent of hydrolysis, while also forming water by reacting with H鈦 ions.
03
Effect of Adding NaOH
Adding NaOH increases the concentration of OH鈦 ions in the solution. The equilibrium will shift to the right to produce more HNO鈧 and consume the added OH鈦 ions to decrease the amount of excess OH鈦, increasing the extent of hydrolysis.
04
Effect of Adding NaCl
Adding NaCl, a common ion, increases the concentration of Na鈦 ions. According to Le Ch芒telier's principle, adding a common ion generally decreases the extent of a solubility reaction. However, since Na鈦 does not participate directly in the hydrolysis reaction of NO鈧傗伝, the extent of hydrolysis is largely unaffected by adding NaCl.
05
Effect of Dilution
Diluting the solution decreases the concentration of all species, shifting the equilibrium towards the side with a greater number of particles to re-establish equilibrium. This means the hydrolysis reaction of NO鈧傗伝 will shift to the right, increasing the extent of hydrolysis.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chemistry Equilibrium
Chemistry equilibrium refers to a state in a chemical reaction where the rate of the forward reaction equals the rate of the backward reaction, leading to a stable concentration of reactants and products. In the context of sodium nitrite hydrolysis, we observe an equilibrium reaction, where
虏鈦 and water react to form HNO鈧 and OH鈦 ions. Adjustments in this balance, due to external changes, follow Le Ch芒telier's principle. Essentially, when a change is introduced to the system, such as adding HCl or NaOH, the system naturally adjusts to minimize the impact of that change. This could result in the reaction shifting to favor the creation of products or reactants to bring the system back to equilibrium. When carefully understood, equilibrium helps predict the outcome of reactions when subjected to different conditions.
Acid-Base Reactions
Acid-base reactions are fundamental to understanding many chemical processes, including the behavior of
虏鈦 during hydrolysis. Acidic or basic substances dissolve in water to alter the pH of the solution. When
ON鈧
d is added to an aqueous solution, it interacts with water, causing hydrolysis, an acid-base reaction producing HNO鈧 (a weak acid) and OH鈦 ions.
This is further influenced by adding acids like HCl, which increases H鈦 concentration, thereby driving the equilibrium to lower OH鈦 by consuming it. Furthermore, the addition of a base such as NaOH will add more OH鈦 ions, promoting the formation of more HNO鈧 in an attempt to counterbalance the increased OH鈦, enhancing hydrolysis. Recognizing these interactions aids in comprehending how solutions respond to variations in acidity and basicity.
Solution Concentration
Solution concentration plays a critical role in determining the direction of equilibrium shifts. By altering concentrations, like when NaCl is added sourcing a common ion (Na鈦), we might expect changes due to the common ion effect. However, in our specific reaction, Na鈦 is not directly involved in the hydrolysis process. Hence, its presence, while increasing primary ion concentration, does not impact the ongoing equilibrium between
O鈧傗伝 and water. For dilution, reducing overall concentration nudges the system toward the formation of more ions (in this case HNO鈧 and OH鈦), because the system attempts to reach a new equilibrium by producing more output to compensate for the decrease in concentration density. Therefore, dynamic solutions facilitate gaining insight into how systems adjust upon concentration shifts.
Ionic Compounds
Ionic compounds, like sodium nitrite (NaNO鈧), dissociate in water to form ions that participate in various chemical reactions. These compounds consist of ions held together by electrostatic forces, disbanding in solution to forge new pathways, such as hydrolysis in this scenario. When NaNO鈧 dissociates, it forms Na鈦 and NO鈧傗伝 ions, the latter engaging in equilibrium reactions with water.
The behavior of such ions under varying conditions鈥攚hether in presence of acids, bases, or changes in concentration鈥攊s remarkably predictable using principles like Le Ch芒telier's. They highlight how equilibrium can pivotingly hinge on bond strength and ion interaction property. Understanding ionic behavior is integral to mastering the nuances of chemical reactions.