Chapter 16: Problem 1
Define Br贸nsted acids and bases. Give an example of a conjugate pair in an acid-base reaction.
Short Answer
Expert verified
Br枚nsted acids donate protons, and bases accept them. Example: NH鈧勨伜/NH鈧.
Step by step solution
01
Understand Br枚nsted Acids
A Br枚nsted acid is defined as a substance that donates a proton (H鈦) in a chemical reaction. This proton donation is what characterizes a Br枚nsted acid.
02
Understand Br枚nsted Bases
A Br枚nsted base is a substance that accepts a proton (H鈦) in a chemical reaction. The acceptance of a proton is what distinguishes a Br枚nsted base.
03
Recognize Conjugate Acid-Base Pairs
In an acid-base reaction, a Br枚nsted acid will lose a proton to become its conjugate base, and a Br枚nsted base will gain a proton to become its conjugate acid.
04
Example of a Conjugate Pair
Consider the reaction of ammonia with water:
NH鈧 + H鈧侽 鈫 NH鈧勨伜 + OH鈦.
Here, NH鈧 (ammonia) is the Br枚nsted base, accepting a proton to become NH鈧勨伜, and H鈧侽 (water) is the Br枚nsted acid, donating a proton to become OH鈦. NH鈧勨伜 and NH鈧 are a conjugate pair, as are OH鈦 and H鈧侽.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Proton Donation
Br枚nsted acids are special because they can donate a proton, which is a hydrogen ion (
H^+
). When a chemical substance donates a proton during a reaction, it acts as a Br枚nsted acid. This process transforms the acid
- from its original form
- into its conjugate base
Proton Acceptance
Br枚nsted bases play the opposite role compared to acids. They are substances that accept protons in chemical reactions. When a base accepts a proton, it becomes
- a larger molecule or ion
- designated as a conjugate acid
Conjugate Acid-Base Pairs
In an acid-base reaction, conjugate acid-base pairs are the results of proton donation and acceptance. When an acid donates a proton, it becomes its conjugate base. Conversely, when a base accepts a proton, it becomes its conjugate acid. Each pair consists of two species linked by the gain or loss of a single proton.
For example, when water donates a proton to ammonia in a reaction, ammonia receives it to form ammonium ( NH鈧勨伜 ). Here, NH鈧勨伜 and NH鈧 are a conjugate acid-base pair. Similarly, when water becomes hydroxide ( OH鈦 ) after donating a proton, OH鈦 and H鈧侽 form another conjugate pair. These pairs help in understanding reaction mechanisms and the nature of the substances involved.
For example, when water donates a proton to ammonia in a reaction, ammonia receives it to form ammonium ( NH鈧勨伜 ). Here, NH鈧勨伜 and NH鈧 are a conjugate acid-base pair. Similarly, when water becomes hydroxide ( OH鈦 ) after donating a proton, OH鈦 and H鈧侽 form another conjugate pair. These pairs help in understanding reaction mechanisms and the nature of the substances involved.
Acid-Base Reaction Example
A classic example of an acid-base reaction involves ammonia (
NH鈧
) and water (
H鈧侽
). This reaction can be shown as:
These products form the conjugate acid ( NH鈧勨伜 ) and conjugate base ( OH鈦 ) of the original reactants. This example illustrates proton transfer, showcasing the interactions between acids and bases, and the equilibrium that can exist between these dynamic components.
- Reactants: NH鈧 + H鈧侽
- Products: NH鈧勨伜 + OH鈦
These products form the conjugate acid ( NH鈧勨伜 ) and conjugate base ( OH鈦 ) of the original reactants. This example illustrates proton transfer, showcasing the interactions between acids and bases, and the equilibrium that can exist between these dynamic components.