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"The rate constant for the reaction: $$ \mathrm{NO}_{2}(g)+\mathrm{CO}(g) \longrightarrow \mathrm{NO}(g)+\mathrm{CO}_{2}(g) $$ is \(1.64 \times 10^{-6} / M \cdot \mathrm{s} . "\) What is incomplete about this statement?

Short Answer

Expert verified
The reaction order or rate law is missing in the statement.

Step by step solution

01

Identifying Reaction Type

First, we need to identify the type of reaction given. The reaction is: \( \mathrm{NO}_{2}(g)+\mathrm{CO}(g) \longrightarrow \mathrm{NO}(g)+\mathrm{CO}_{2}(g) \). This is a bimolecular reaction as it involves two reactants.
02

Understanding Rate Constant Units

The rate constant has units of \( M^{-1} \cdot \mathrm{s}^{-1} \). These units typically correspond to a second-order reaction, where the rate is dependent on the concentration of two reactants.
03

Determining Missing Information

Since the reaction is bimolecular and the units suggest a second-order reaction, we must check if the statement includes the necessary information for this reaction order. For a complete description, the rate law itself or the reaction order should be explicitly mentioned to ensure clarity.
04

Conclusion on Incompleteness

The statement is incomplete because it does not specify the reaction order or the rate law directly. For completeness, either the order of reaction (e.g., first order, second order) should be stated, or the rate mechanism should be provided.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Reaction Rate
In chemical kinetics, the term 'reaction rate' refers to how fast a chemical reaction occurs. It is essentially the speed at which reactants are converted into products. The reaction rate can be affected by several factors, such as the concentration of the reactants, temperature, and the presence of catalysts.
In general, understanding reaction rate helps chemists to predict how quickly a reaction reaches completion and to control the process effectively. By controlling variables, researchers can optimize product yields in industrial settings or fine-tune reaction conditions in a laboratory to achieve desired outcomes swiftly.
Rate Constant
The rate constant is a crucial component in understanding the speed of a chemical reaction. It is typically represented by the symbol \( k \). The value of the rate constant is determined experimentally and varies with different reactions. For the given reaction: \( \mathrm{NO}_{2}(g) + \mathrm{CO}(g) \longrightarrow \mathrm{NO}(g) + \mathrm{CO}_{2}(g) \), the rate constant is provided as \( 1.64 \times 10^{-6} / M \cdot \mathrm{s} \).
The units of the rate constant help determine the reaction order, which relates to how the concentration of reactants affects the reaction rate. Specifically, the units \( M^{-1} \cdot \mathrm{s}^{-1} \) suggest a second-order reaction, indicating that the rate depends on the concentrations of two reactants involved. This information is vital for understanding how to effectively manipulate reaction conditions to achieve the desired speed and efficiency.
Bimolecular Reaction
A bimolecular reaction involves two reactant molecules that collide and react with each other during the process. In the given exercise, the reaction between \( \mathrm{NO}_2(g) \) and \( \mathrm{CO}(g) \) is classified as a bimolecular reaction.
Such reactions play a prominent role in understanding mechanisms that involve intermediate steps and further transformations. Bimolecular reactions are common in both organic and inorganic chemistry, where molecular interactions are key to transforming substances. The study of these interactions is essential for designing catalysts, understanding reaction pathways, and predicting reaction outcomes.
Reaction Order
Reaction order is a fundamental concept in chemical kinetics that dictates how the concentration of reactants influences the rate of a reaction. It is not directly derived from the stoichiometry of the reaction but is determined experimentally.
  • In a first-order reaction, the rate depends on the concentration of one reactant.
  • In a second-order reaction, the rate is proportional to the concentration of two reactants or the square of the concentration of a single reactant.
For the reaction given in the exercise, the units of the rate constant indicate it's a second-order reaction.
Understanding the order helps chemists control reaction conditions to optimize industrial processes, ensuring that reactions proceed at desired speeds and producing targeted amounts of products efficiently.

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Most popular questions from this chapter

Consider the reaction: $$ \mathrm{A} \longrightarrow \mathrm{B} $$ The rate of the reaction is \(1.6 \times 10^{-2} \mathrm{M} / \mathrm{s}\) when the concentration of A is \(0.15 M\). Calculate the rate constant if the reaction is (a) first order in \(\mathrm{A}\) and \((\mathrm{b})\) second order in \(\mathrm{A}\).

The activity of a radioactive sample is the number of nuclear disintegrations per second, which is equal to the first-order rate constant times the number of radioactive nuclei present. The fundamental unit of radioactivity is the curie \((\mathrm{Ci})\), where \(1 \mathrm{Ci}\) corresponds to exactly \(3.70 \times 10^{10}\) disintegrations per second. This decay rate is equivalent to that of \(1 \mathrm{~g}\) of radium-226. Calculate the rate constant and half- life for the radium decay. Starting with \(1.0 \mathrm{~g}\) of the radium sample, what is the activity after \(500 \mathrm{yr}\) ? The molar mass of Ra-226 is \(226.03 \mathrm{~g} / \mathrm{mol}\).

Determine the molecularity, and write the rate law for each of the following elementary steps: (a) \(\mathrm{X} \longrightarrow\) products (b) \(\mathrm{X}+\mathrm{Y} \longrightarrow\) products (c) \(\mathrm{X}+\mathrm{Y}+\mathrm{Z} \longrightarrow\) products (d) \(\mathrm{X}+\mathrm{X} \longrightarrow\) products (e) \(\mathrm{X}+2 \mathrm{Y} \longrightarrow\) products

In a certain industrial process involving a heterogeneous catalyst, the volume of the catalyst (in the shape of a sphere) is \(10.0 \mathrm{~cm}^{3} .\) Calculate the surface area of the catalyst. If the sphere is broken down into eight smaller spheres, each having a volume of \(1.25 \mathrm{~cm}^{3},\) what is the total surface area of the spheres? Which of the two geometric configurations of the catalyst is more effective? (The surface area of a sphere is \(4 \pi r^{2}\), where \(r\) is the radius of the sphere.) Based on your analysis here, explain why it is sometimes dangerous to work in grain elevators.

A protein molecule \(\mathrm{P}\) of molar mass \(\mathscr{M}\) dimerizes when it is allowed to stand in solution at room temperature. A plausible mechanism is that the protein molecule is first denatured (i.e., loses its activity due to a change in overall structure) before it dimerizes: \(\mathrm{P} \stackrel{k}{\longrightarrow} \mathrm{P}^{*}(\) denatured \() \quad\) (slow) $$ 2 \mathrm{P}^{*} \longrightarrow \mathrm{P}_{2} $$ (fast) where the asterisk denotes a denatured protein molecule. Derive an expression for the average molar mass (of \(\mathrm{P}\) and \(\left.\mathrm{P}_{2}\right), \bar{U},\) in terms of the initial protein concentration \([\mathrm{P}]_{0}\) and the concentration at time \(t,[\mathrm{P}]_{t},\) and \(\mathscr{M} .\) Describe how you would determine \(k\) from molar mass measurements.

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