Chapter 9: Problem 6
Explain what an ionic bond is.
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Chapter 9: Problem 6
Explain what an ionic bond is.
These are the key concepts you need to understand to accurately answer the question.
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Which of the following are ionic compounds? Which are covalent compounds? \(\mathrm{RbCl}, \mathrm{PF}_{5}, \mathrm{BrF}_{3},\) \(\mathrm{KO}_{2}, \mathrm{CI}_{4}\)
From the lattice energy of \(\mathrm{KCl}\) in Table 9.1 and the ionization energy of \(\mathrm{K}\) and electron affinity of \(\mathrm{Cl}\) in Tables 8.2 and 8.3 , calculate the \(\Delta H^{\circ}\) for the reaction $$ \mathrm{K}(g)+\mathrm{Cl}(g) \longrightarrow \mathrm{KCl}(s) $$ (a) Draw three resonance structures to represent the ion. (b) Given the following information $$ 2 \mathrm{H}+\mathrm{H}^{+} \longrightarrow \mathrm{H}_{3}^{+} \quad \Delta H^{\circ}=-849 \mathrm{~kJ} / \mathrm{mol} $$ and $$ \mathrm{H}_{2} \longrightarrow 2 \mathrm{H} \quad \Delta H^{\circ}=436.4 \mathrm{~kJ} / \mathrm{mol} $$ calculate \(\Delta H^{\circ}\) for the reaction $$ \mathrm{H}^{+}+\mathrm{H}_{2} \longrightarrow \mathrm{H}_{3}^{+} $$
Write Lewis structures for the following ions: (a) \(\mathrm{NO}_{2}^{+},\) (b) \(\mathrm{S}_{2}^{2-},\) (c) \(\mathrm{BrF}_{2}^{+}\), (d) \(\mathrm{SCN}^{-}\). Show formal charges.
The following species have been detected in interstellar space: (a) \(\mathrm{CH},(\mathrm{b}) \mathrm{OH},(\mathrm{c}) \mathrm{C}_{2},(\mathrm{~d}) \mathrm{HNC},(\mathrm{e}) \mathrm{HCO} .\) Draw Lewis structures for these species and indicate whether they are diamagnetic or paramagnetic.
Although nitrogen dioxide \(\left(\mathrm{NO}_{2}\right)\) is a stable compound, there is a tendency for two such molecules to combine to form dinitrogen tetroxide \(\left(\mathrm{N}_{2} \mathrm{O}_{4}\right) .\) Why? Draw four resonance structures of \(\mathrm{N}_{2} \mathrm{O}_{4},\) showing formal charges.
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