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Which of the following are ionic compounds? Which are covalent compounds? \(\mathrm{RbCl}, \mathrm{PF}_{5}, \mathrm{BrF}_{3},\) \(\mathrm{KO}_{2}, \mathrm{CI}_{4}\)

Short Answer

Expert verified
\(\mathrm{RbCl}\) and \(\mathrm{KO}_{2}\) are ionic compounds, while \(\mathrm{PF}_{5}, \mathrm{BrF}_{3},\) and \(\mathrm{CI}_{4}\) are covalent compounds.

Step by step solution

01

Understanding Compound Properties

Remember that ionic compounds form when a metal and nonmetal exchange electrons, whereas covalent compounds form when two or more nonmetals share electrons. In an elemental context, metals tend to occupy the left-hand side of the periodic table, while nonmetals occupy the right.
02

Identifying Ionic Compounds

\(\mathrm{RbCl}\) and \(\mathrm{KO}_{2}\) are both ionic compounds. They form when the metal atoms Rb and K lose electrons and the nonmetal atoms Cl and O gain them.
03

Identifying Covalent Compounds

\(\mathrm{PF}_{5}, \mathrm{BrF}_{3},\) and \(\mathrm{CI}_{4}\) are covalent compounds. These compounds form when the nonmetal atoms P, F, Br, and Cl share electrons.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ionic Compounds
Ionic compounds are fascinating chemical structures formed from the interaction between metals and nonmetals. When an ionic compound forms, a metal atom transfers one or more of its electrons to a nonmetal atom. This electron transfer is a key characteristic of ionic bonds.
This process creates ions: a positively charged cation (from the metal) and a negatively charged anion (from the nonmetal). These ions then attract each other, forming a strong, electrostatic bond.
Some indicators of ionic compounds include:
  • Formation from a metal and nonmetal combination.
  • High melting and boiling points due to strong bonds.
  • They often form crystalline structures.
When looking at compound examples like \(\mathrm{RbCl}\) (rubidium chloride) and \(\mathrm{KO}_{2}\) (potassium dioxide), these fit neatly into this category. Rubidium (Rb) and potassium (K) are metals that lose electrons to chlorine (Cl) and oxygen (O), respectively, forming ionic bonds.
Covalent Compounds
Covalent compounds are different from ionic compounds because they involve the sharing of electrons rather than the transfer. These compounds typically form between nonmetal atoms. Electron sharing enables each atom to fill its outer shell, creating a stable molecule.
Covalent compounds exhibit several distinct properties:
  • Usually consist of two or more nonmetals.
  • Have lower melting and boiling points compared to ionic compounds.
  • Tend to be flexible and not conduct electricity.
In the compounds \(\mathrm{PF}_{5}\) (phosphorus pentafluoride), \(\mathrm{BrF}_{3}\) (bromine trifluoride), and \(\mathrm{CI}_{4}\) (carbon tetraiodide), we find nonmetals like phosphorus (P), bromine (Br), fluorine (F), and iodine (I) engaging in covalent bonding.
Electron Sharing
Electron sharing is the hallmark of covalent bonds. In covalent compounds, atoms achieve stability by sharing electrons. Each atom contributes at least one electron to the bond, allowing all involved to attain full outer shells. This mechanism contrasts with ionic bonding, where no electrons are shared, only transferred.
Some examples of electron sharing include:
  • The single bond in hydrogen molecules \((\mathrm{H}_2)\), where each hydrogen shares one electron.
  • Double bonds like in oxygen \((\mathrm{O}_2)\), where each oxygen shares two electrons.
  • Complex bonds like in \(\mathrm{BrF}_3\) where multiple nonmetals share electrons.
This approach to bonding allows for the multitude of covalent compounds found throughout nature and is crucial for life as we know it.
Electron Transfer
Electron transfer underpins the formation of ionic bonds. In this process, electrons completely move from one atom to another—usually from a metal to a nonmetal. This transfer transforms the metals into cations and nonmetals into anions, which are energetically more stable compared to their neutral forms.
Key aspects of electron transfer include:
  • Occurs mainly in compounds involving metals and nonmetals.
  • Leads to the formation of charged particles, or ions.
  • Results in the creation of a strong electrostatic force of attraction.
For instance, in \(\mathrm{RbCl}\), the rubidium atom loses an electron, becoming \(\mathrm{Rb}^+\), while chlorine gains an electron to become \(\mathrm{Cl}^-\). This exchange of electrons is fundamental to the structure and stability of ionic compounds.

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Most popular questions from this chapter

A rule for drawing plausible Lewis structures is that the central atom is invariably less electronegative than the surrounding atoms. Explain why this is so. Why does this rule not apply to compounds like \(\mathrm{H}_{2} \mathrm{O}\) and \(\mathrm{NH}_{3} ?\)

Shown here is a skeletal structure of borazine \(\left(\mathrm{B}_{3} \mathrm{~N}_{3} \mathrm{H}_{6}\right) .\) Draw two resonance structures of the molecule, showing all the bonds and formal charges. Compare its properties with the isoelectronic molecule benzene.

Summarize the essential features of the Lewis octet rule.

Comment on the correctness of the statement, "All compounds containing a noble gas atom violate the octet rule."

A new allotrope of oxygen, \(\mathrm{O}_{4}\), has been reported. The exact structure of \(\mathrm{O}_{4}\) is unknown, but the \(\operatorname{sim}-\) plest possible structure would be a four-member ring consisting of oxygen-oxygen single bonds. The report speculated that the \(\mathrm{O}_{4}\) molecule might be useful as a fuel "because it packs a lot of oxygen in a small space, so it might be even more energy-dense than the liquefied ordinary oxygen used in rocket fuel." (a) Draw a Lewis structure for \(\mathrm{O}_{4}\) and write a balanced chemical equation for the reaction between ethane, \(\mathrm{C}_{2} \mathrm{H}_{6}(g),\) and \(\mathrm{O}_{4}(g)\) to give carbon dioxide and water vapor. (b) Estimate \(\Delta H^{\circ}\) for the reaction. (c) Write a chemical equation illustrating the standard enthalpy of formation of \(\mathrm{O}_{4}(g)\) and estimate \(\Delta H_{\mathrm{f}}^{\circ}\) (d) Assuming the oxygen allotropes are in excess, which will release more energy when reacted with ethane (or any other fuel): \(\mathrm{O}_{2}(g)\) or \(\mathrm{O}_{4}(g) ?\) Explain using your answers to parts (a)-(c).

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