Chapter 4: Problem 80
Distilled water must be used in the gravimetric analysis of chlorides. Why?
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Chapter 4: Problem 80
Distilled water must be used in the gravimetric analysis of chlorides. Why?
These are the key concepts you need to understand to accurately answer the question.
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A \(5.00 \times 10^{2} \mathrm{~mL}\) sample of \(2.00 \mathrm{M} \mathrm{HCl}\) solution is treated with \(4.47 \mathrm{~g}\) of magnesium. Calculate the concentration of the acid solution after all the metal has reacted. Assume that the volume remains un- changed.
A quantity of \(25.0 \mathrm{~mL}\) of a solution containing both \(\mathrm{Fe}^{2+}\) and \(\mathrm{Fe}^{3+}\) ions is titrated with \(23.0 \mathrm{~mL}\) of \(0.0200 M \mathrm{KMnO}_{4}\) (in dilute sulfuric acid). As a result, all of the \(\mathrm{Fe}^{2+}\) ions are oxidized to \(\mathrm{Fe}^{3+}\) ions. Next, the solution is treated with Zn metal to convert all of the \(\mathrm{Fe}^{3+}\) ions to \(\mathrm{Fe}^{2+}\) ions. Finally, the solution containing only the \(\mathrm{Fe}^{2+}\) ions requires \(40.0 \mathrm{~mL}\) of the same \(\mathrm{KMnO}_{4}\) solution for oxidation to \(\mathrm{Fe}^{3+}\). Calculate the molar concentrations of \(\mathrm{Fe}^{2+}\) and \(\mathrm{Fe}^{3+}\) in the original solution. The net ionic equation is \(\mathrm{MnO}_{4}^{-}+5 \mathrm{Fe}^{2+}+8 \mathrm{H}^{+} \longrightarrow\) \(\mathrm{Mn}^{2+}+5 \mathrm{Fe}^{3+}+4 \mathrm{H}_{2} \mathrm{O}\)
Oxygen \(\left(\mathrm{O}_{2}\right)\) and carbon dioxide \(\left(\mathrm{CO}_{2}\right)\) are colorless and odorless gases. Suggest two chemical tests that would enable you to distinguish between these two gases.
You are given two colorless solutions, one containing \(\mathrm{NaCl}\) and the other sucrose \(\left(\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}\right) .\) Suggest a chemical and a physical test that would allow you to distinguish between these two solutions.
Classify the following redox reactions. (a) \(2 \mathrm{H}_{2} \mathrm{O}_{2} \longrightarrow 2 \mathrm{H}_{2} \mathrm{O}+\mathrm{O}_{2}\) (b) \(\mathrm{Mg}+2 \mathrm{AgNO}_{3} \longrightarrow \mathrm{Mg}\left(\mathrm{NO}_{3}\right)_{2}+2 \mathrm{Ag}\) (c) \(\mathrm{NH}_{4} \mathrm{NO}_{2} \longrightarrow \mathrm{N}_{2}+2 \mathrm{H}_{2} \mathrm{O}\) (d) \(\mathrm{H}_{2}+\mathrm{Br}_{2} \longrightarrow 2 \mathrm{HBr}\)
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