Chapter 20: Problem 2
List two major industrial uses of hydrogen.
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Chapter 20: Problem 2
List two major industrial uses of hydrogen.
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What trade-offs must be made between kinetics and thermodynamics in the Haber process for the production of ammonia? How did the discovery of an appropriate catalyst make the process feasible?
Many lithium salts are hygroscopic (absorb water), but the corresponding salts of the other alkali metals are not. Why are lithium salts different from the others?
Hydrazine is somewhat toxic. Use the following half-reactions to explain why household bleach (highly alkaline solutions of sodium hypochlorite) should not be mixed with household ammonia or glass cleansers that contain ammonia. $$ \mathrm{ClO}^{-}+\mathrm{H}_{2} \mathrm{O}+2 \mathrm{e}^{-} \longrightarrow 2 \mathrm{OH}^{-}+\mathrm{Cl}^{-} \quad \mathscr{E}^{\circ}=0.90 \mathrm{V} $$ $$ \mathrm{N}_{2} \mathrm{H}_{4}+2 \mathrm{H}_{2} \mathrm{O}+2 \mathrm{e}^{-} \longrightarrow 2 \mathrm{NH}_{3}+2 \mathrm{OH}^{-} \quad \mathscr{E}^{\circ}=-0.10 \mathrm{V} $$
In many natural waters, nitrogen and phosphorus are the least abundant nutrients available for plant life. Some waters that become polluted from agricultural runoff or municipal sewage become infested with algae. The algae flourish, and fish life dies off as a result. Describe how these events are chemically related.
Discuss the importance of the \(\mathrm{C}-\mathrm{C}\) and \(\mathrm{Si}-\) Si bond strengths and of \(\pi\) bonding to the properties of carbon and silicon.
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