Chapter 20: Problem 1
Although the earth was formed from the same interstellar material as the sun, there is little elemental hydrogen \(\left(\mathrm{H}_{2}\right)\) in the earth's atmosphere. Explain.
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Chapter 20: Problem 1
Although the earth was formed from the same interstellar material as the sun, there is little elemental hydrogen \(\left(\mathrm{H}_{2}\right)\) in the earth's atmosphere. Explain.
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Molten \(\mathrm{CaCl}_{2}\) is electrolyzed for 8.00 \(\mathrm{h}\) to produce \(\mathrm{Ca}(s)\) and \(\mathrm{Cl}_{2}(g) .\) a. What current is needed to produce 5.52 \(\mathrm{kg}\) of calcium metal? b. If 5.52 \(\mathrm{kg}\) calcium metal is produced, what mass (in kg) of \(\mathrm{Cl}_{2}\) is produced?
What mass of barium is produced when molten \(\mathrm{BaCl}_{2}\) is electrolyzed by a current of \(2.50 \times 10^{5} \mathrm{A}\) for 6.00 \(\mathrm{h} ?\)
In large doses, selenium is toxic. However, in moderate intake, selenium is a physiologically important element. How is selenium physiologically important?
While selenic acid has the formula \(\mathrm{H}_{2} \mathrm{SeO}_{4}\) and thus is directly related to sulfuric acid, telluric acid is best visualized as \(\mathrm{H}_{6} \mathrm{TeO}_{6}\) or \(\mathrm{Te}(\mathrm{OH})_{6}\) a. What is the oxidation state of tellurium in Te(OH) \(_{6} ?\) b. Despite its structural differences with sulfuric and selenic acid, telluric acid is a diprotic acid with \(\mathrm{p} K_{\mathrm{a}_{1}}=7.68\) and \(\mathrm{p} K_{\mathrm{a}_{2}}=11.29 .\) Telluric acid can be prepared by hydrolysis of tellurium hexafluoride according to the equation $$ \mathrm{TeF}_{6}(g)+6 \mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{Te}(\mathrm{OH})_{6}(a q)+6 \mathrm{HF}(a q) $$ Tellurium hexafluoride can be prepared by the reaction of elemental tellurium with fluorine gas: $$ \mathrm{Te}(s)+3 \mathrm{F}_{2}(g) \longrightarrow \mathrm{TeF}_{6}(g) $$ If a cubic block of tellurium (density \(=6.240 \mathrm{g} / \mathrm{cm}^{3} )\) measuring 0.545 \(\mathrm{cm}\) on edge is allowed to react with 2.34 \(\mathrm{L}\) fluorine gas at 1.06 \(\mathrm{atm}\) and \(25^{\circ} \mathrm{C},\) what is the pH of a solution of \(\mathrm{Te}(\mathrm{OH})_{6}\) formed by dissolving the isolated TeF \(_{6}(g)\) in 115 \(\mathrm{mL}\) solution? Assume 100\(\%\) yield in all reactions.
A cylinder fitted with a movable piston initially contains 2.00 moles of \(\mathrm{O}_{2}(g)\) and an unknown amount of \(\mathrm{SO}_{2}(g) .\) The oxygen is known to be in excess. The density of the mixture is 0.8000 \(\mathrm{g} / \mathrm{L}\) at some \(T\) and \(P\) . After the reaction has gone to completion, forming \(\mathrm{SO}_{3}(g),\) the density of the resulting gaseous mixture is 0.8471 \(\mathrm{g} / \mathrm{L}\) at the same \(T\) and \(P\) . Calculate the mass of \(\mathrm{SO}_{3}\) formed in the reaction.
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