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Use the heat equation to calculate the energy, in joules and calories, for each of the following (see Table 3.11):

a. to heat 5.25gof water from 5.5°Cto 64.8C6

b. lost when 75.0gof water cools from86.4°Cto 2.1°C

c. to heat 10.0gof silver from112°Cto 275°C

d. lost when18.0gof gold cools from224°Cto 118°C

Short Answer

Expert verified

(part a) As a result, the required heat is 311 cal.

(part b) As a result, the heat lost is633×10′cal

(part c) As a result, the required heat is91.6cal

(part d) As a result, the heat lost is58.8cal

Step by step solution

01

Given data (part a)

(a) The mass of water is5.25g, and the specific heat (SH)for water is localid="1653052589831" 4.184J/g°CThe initial temperature is Tinitialis localid="1653052595971" 5.5°C.

The final temperature isTfinalislocalid="1653052605136" 64.8°C.

The heat lost can be converted from joules to calories using the conversion factor shown below.

02

Step 2:The tempature change (part a) 

The temperature change (ΔT)can be calculated by using the following formula:

ΔT=Tfinal−Tinitial

localid="1653052613916" =64.8∘C−5.5∘C

localid="1653052620116" =59.3°C

The temperature change (ΔT)is localid="1653052626606" 59.3°C.

03

The heat equation (part a) 

The heat equation is as follows.

Heat =mass ×ΔT×SH

By substituting the value in the preceding equation, we obtain

localid="1653052638163" Heat=5.25g×59.3°C×4.184J/g°C

localid="1653052645235" =13.0×102J

As a result, the required heat islocalid="1653052651623" 13.0×102J

04

Step 4:The heat required can be converted from joules into calories (part a) 

The heat lost can be converted from joules to calories using the conversion factor shown below.

lcal=4.184J

1cal4.184J

The heat required is

Heat=13.0×102J

=13.0×102J×1.00cal4.184J

=311Cal

As a result, the required heat is 311cal.

05

Step 5:Given data (part b)

(b) The mass of water is 75.0g, and the specific heat (SH)for water is localid="1653052717859" 4.184J/gC∘The initial temperature isTinitialislocalid="1653052723774" 86.4°C.

The final temperature isTfinalis localid="1653052729775" 2.1°C.

The heat lost can be converted from joules to calories using the conversion factor shown below.

06

Step 6:The temperature change  (part b) 

The temperature change (ΔT)can be calculated by using the following formula:

ΔT=Tfinal−Tinitial

localid="1653052740468" =2.1∘C−86.4∘C

localid="1653052747540" =-84.3°C

Therefore, the temperature change is localid="1653052754087" -84.3°C.

07

Step 7:The heat equation  (part b) 

The heat equation is as follows.

Heat=mass ×ΔT×SH

By substituting the value in the preceding equation, we obtain

localid="1653052765500" Heat=75.0g×-84.3°C×4.184J/g°C

The minus sign denotes that heat is lost during the process.. Therefore, the heat lost is localid="1653052771541" 265×102J.

08

Step 8:The heat lost can be converted from joules into calories  (part b) 

The heat lost can be converted from joules to calories using the conversion factor shown below.:

1.00cal=4.184J

1cal4.184J

The heat required is

Heat =265×102J

=265×102I×1.00cal4.184I

=633×10′cal

As a result, the required heat is 633×101cal.

09

Step 9:Given data (part c)

(c) The mass of silver is 10.0g, and the specific heat (SH)for silver islocalid="1653052830136" 0.235J/gC∘. The initial temperature is Tinitialis localid="1653052824312" 112°C.

The final temperature is Tfinalis localid="1653052838424" 275°C.

The heat lost can be converted from joules to calories using the conversion factor shown below.

10

Step 10:The temperature change  (part c) 

The temperature change (ΔT)can be calculated by using the following formula:

ΔT=Tfinal−Tinitial

localid="1653052848805" =275∘C−112∘C

localid="1653052855023" =163°C

As a result, the required heat is localid="1653052861088" 163°C.

11

Step 11:The heat equation  (part c) 

The heat equation is as follows.

Heat=mass×ΔT×SH

By substituting the value in the preceding equation, we obtain

Heat localid="1653052871100" =10.0g×163°C×0.235J/g°C

localid="1653052877473" =385J

As a result, the required heat is localid="1653052883588" 385J

12

Step 12:The heat required can be converted from joules into calories  (part c) 

The heat lost can be converted from joules to calories using the conversion factor shown below.

1.00cal=4.184J

1cal4.184J

The heat required is

Heat=383J

=383J×1.00cal4.184J

=91.6Cal

As a result, the required heat is 91.6cal.

13

Step 13:Given data (part d)

(d) The mass of gold is 18.0g, and the specific heatSH)for iron is localid="1653052968300" 0.129J/gC∘. The initial temperature is Tinitialislocalid="1653052974647" 224°C.

The final temperature isTfinalis localid="1653052981118" 118°C.

We must calculate the required heat in joules and calories.

14

Step 14:The temperature change (part d) 

The temperature change (ΔT)can be calculated by using the following formula:

ΔT=Tfinal−Tinitial

localid="1653052992535" =118∘C−224∘C

localid="1653052999068" =-106°C

Therefore, the temperature change is localid="1653053006237" -106°C

The heat equation is

Heat=mass×ΔT×SH

By substituting the value in the preceding equation, we obtain

localid="1653053015039" Heat=18.0g×−106∘C×0.129J/g∘C

localid="1653053025035" =-246J

The minus sign indicates that the heat is lost in the process. Therefore, the heat lost is246J.

The heat lost can be converted from joules to calories using the conversion factor shown below

localid="1653053054078" 1.00cal=4.184J

localid="1653053062424" 1.00cal4.184J

The heat lost is

Heat localid="1653053073495" =246J

localid="1653053087241" =246J×1.00cal4.184J

= 588 cal

As a result, the required heat is 58.8 cal.

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