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Problem 1

Which of the following statements is correct? (a) The Ruff procedure lengthens an aldose chain and gives a single product. (b) (c) The Kiliani-Fischer procedure shortens an aldose chain and gives a single product. (d) The Kiliani-Fischer procedure lengthens an aldose chain and gives two epimers.

Problem 2

Which of the following is \(/\) are co-polymer (s)? (a) Nylon-66 (b) Bakelite (c) Teflon (d) Polystyrene

Problem 2

Which of the following is not a disaccharide? (a) sucrose (b) mannose (c) lactose (d) maltose

Problem 3

Which of the following do not undergo hydrolysis? (a) Glucose (b) Fructose (c) Cane sugar (d) Maltose

Problem 3

Which statement about the pyranose form of mannose is not correct? (a) it exists as two anomeric stereoisomers. (b) it reacts with Tollen's reagent to give a silver mirror (i.e., it is a reducing sugars). (c) reaction with excess \(\mathrm{CH}_{3} \mathrm{I}\) and \(\mathrm{AgOH}\) gives a non-reducing penta-O-methyl derivative. (d) it resists reduction with aqueous sodium borohydride.

Problem 4

Two aldopentoses \(\mathrm{X}\) and \(\mathrm{Y}\) give the same osazone derivative. \(\mathrm{X}\) is oxidised to an optically active aldaric acid by dilute nitric acid. Ruff degradation of \(Y\) gave a tetrose which was similarly oxidised to an optically active aldaric acid. Assign the structures of \(X\) and \(Y\) from the following list.

Problem 4

Among the following polymers, peptide linkage is present in (a) Nylon-66 (b) Protein (c) Nylon-6 (d) Tafflon

Problem 6

What is invert sugar, and why is it so named? (a) the sugar mixture from hydrolysis of sucrose; fructose is isomerised to glucose. (b) the sugar mixture from hydrolysis of sucrose; the optical rotation changes from \((+)\) to \((-)\). (c) the sugar mixture from hydrolysis of starch; \(\alpha\) -glycosidic bonds are changed to \beta-glycosidic bonds. (d) the sugar mixture from hydrolysis of starch; glucose is isomerised to fructose.

Problem 8

Among the following polymers, identify the co-polymer (a) Nylon-6 (b) Buna-N (c) Buna-S (d) Protein

Problem 9

Among the following polymers, identify the co-polymer (a) Terylene (b) Glyptal (c) PVC (d) Protein

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