Chapter 5: Problem 82
Match the reactions in column I with their reagents in column II. Column I Column II (a) \(\mathrm{CH}_{3}-\mathrm{CH}_{2}=\mathrm{CH}-\mathrm{CHO} \rightarrow \mathrm{CH}_{3} \mathrm{CH}=\mathrm{CHCOOH}\) (p) LiAIH \(_{4}\) (b) \(\mathrm{CH}_{3}-\mathrm{CH}=\mathrm{CH}-\mathrm{CHO} \rightarrow \mathrm{CH}_{3} \mathrm{CH}=\mathrm{CH}-\mathrm{CH}_{2} \mathrm{OH}\) (q) \(\mathrm{NaBH}_{4}\) (c) Ph-CH=CH-CHO \(\rightarrow\) Ph-CH \(_{2}-\mathrm{CH}_{2}-\mathrm{CHO}\) (r) \(\mathrm{Pd}-\mathrm{C} / \mathrm{H}_{2}\) (d) \(\mathrm{CH}_{2}=\mathrm{CH}-\mathrm{CH}_{2} \mathrm{CHO} \rightarrow \mathrm{CH}_{2}=\mathrm{CH}-\mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{OH}\) (s) \(\mathrm{Ag}\left(\mathrm{NH}_{3}\right)_{2}^{\oplus}\)
Short Answer
Step by step solution
Identify Possible Reactions for Each Option
Analyze Reaction (a)
Analyze Reaction (b)
Analyze Reaction (c)
Analyze Reaction (d)
Match Each Reaction with Reagents
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Reduction Reagents in Organic Chemistry
Reduction is a central theme in synthetic organic chemistry, allowing chemists to selectively reduce specific groups without altering others. This selectivity enables the fine-tuning of molecular structures for desired properties and reactivities.
- 尝颈础濒贬鈧 is a strong reducing agent used for reducing esters, carboxylic acids, and amides to alcohols.
- 狈补叠贬鈧 is milder, suitable for converting aldehydes and ketones to alcohols.
Oxidation Reagents in Organic Chemistry
One common application is the conversion of aldehydes to carboxylic acids, often using reagents like Tollens' reagent, which is known for its specificity and reliability.
- Oxidation is critical in extending the functionality of compounds, enabling further chemical reactions.
- Common oxidation procedures involve not only Tollens' reagent but also other oxidizing agents like KMnO鈧 and CrO鈧, depending on the desired transformation.
Hydrogenation
Through hydrogenation, alkenes are converted to alkanes, providing a means to "saturate" molecules. This reaction is widely used in the food industry to harden oils, and in fine chemical synthesis, to stabilize structures by replacing reactive unsaturated bonds with more stable single bonds.
- Hydrogenation helps produce reduced compounds with increased stability.
- Typical catalysts used include Pd-C, platinum, and nickel, each suiting specific substrates and conditions.
Tollens' Reagent
Its main function is the oxidation of aldehydes to carboxylic acids, resulting in the formation of a silver mirror when aldehydes are oxidized. This silver mirror test is a hallmark of Tollens' reagent, serving as a qualitative analytic tool.
- Its use is confined to aldehydes; ketones generally do not react.
- The silver mirror indicates the presence of an aldehyde, providing visual confirmation of the reagent's action.
尝颈础濒贬鈧
Despite its potency, care must be taken when using 尝颈础濒贬鈧 as it reacts violently with water, requiring anhydrous conditions for safe handling.
- 尝颈础濒贬鈧 provides extensive applications in drastically reducing various functional groups.
- Its reactivity demands careful control, yet its effectiveness in reducing complex structures is renowned.
狈补叠贬鈧
One of the advantages of 狈补叠贬鈧 is its selectivity and safety, as it can be utilized in aqueous or alcoholic solutions without the explosive risks associated with stronger reducing agents.
- 狈补叠贬鈧's role is crucial for selective reduction where precision is needed.
- Its compatibility with mild conditions allows for reductions without adverse reactions with other functional groups.
Pd-C Catalysis
Pd-C's role extends to a range of transformations, offering chemists the means to control molecular structure via selective saturation of specific unsaturated sites.
- Pd-C often operates under mild conditions, offering high selectivity.
- Its efficiency makes it a tool of choice in various applications, from pharmaceutical synthesis to petrochemical processing.