Chapter 17: Problem 135
Select the incorrect statement(s): (a) Milk of magnesia is an aqueous solution of \(\mathrm{Mg}(\mathrm{OH})_{2}\) (b) \(\mathrm{KOH}\) is a weaker base than \(\mathrm{NaOH}\) (c) \(\mathrm{CaO}_{2}\) is less stable than \(\mathrm{MgO}_{2}\) (d) \(\mathrm{Mg}^{2+}\) ions are precipitated with the addition of \(\mathrm{NH}_{4} \mathrm{OH}\) in the presence of \(\mathrm{NH}_{4} \mathrm{Cl}\)
Short Answer
Step by step solution
Analyze Statement (a)
Analyze Statement (b)
Analyze Statement (c)
Analyze Statement (d)
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Milk of Magnesia
- Composition: Mostly consists of magnesium hydroxide suspended in water.
- Uses: Primarily used to relieve digestive issues like acid indigestion and constipation.
Basicity comparison
- Strong bases dissociate fully in water, meaning \( \mathrm{KOH} \) and \( \mathrm{NaOH} \) have similar functionalities.
- They are often used interchangeably in chemical experiments and industries due to this property.
Stability of metal oxides
- Thermodynamic stability refers to how much energy is required to break a substance into its components. Both \( \mathrm{MgO} \) and \( \mathrm{CaO} \) are extremely stable, making them useful in high-temperature applications.
- These compounds are typically seen as basic oxides, reacting readily with water to form their respective hydroxides.
Precipitation reactions
- The role of \( \mathrm{NH}_{4} \mathrm{Cl} \) is critical as it suppresses the ionization of \( \mathrm{NH}_{4} \mathrm{OH} \), allowing the \( \mathrm{Mg(OH)}_2 \) to precipitate instead of remaining dissolved.
- This is a common laboratory technique used to purify magnesium ions from a mixture by converting them into an easily removable solid form.