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Which of the following reactions written here are correct? (1) \(\mathrm{B}+\mathrm{NaOH} \longrightarrow 2 \mathrm{Na}_{3} \mathrm{BO}_{3}+\mathrm{H}_{2}\) (2) \(\mathrm{P}_{4}+\mathrm{NaOH}+\mathrm{H}_{2} \mathrm{O} \longrightarrow \mathrm{NaH}_{2} \mathrm{PO}_{2}+\mathrm{PH}_{3}\) (3) \(\mathrm{S}+\mathrm{NaOH} \longrightarrow \mathrm{Na}_{2} \mathrm{~S}_{2} \mathrm{O}_{3}+\mathrm{Na}_{2} \mathrm{~S}+\mathrm{H}_{2} \mathrm{O}\) (a) 1 only (b) 3 only (c) 2 and 3 (d) 1,2 and 3

Short Answer

Expert verified
Reaction 3 only is correct, so the answer is (b) 3 only.

Step by step solution

01

Analyze Reaction 1

The reaction involves boron (\( \mathrm{B} \)) and sodium hydroxide (\( \mathrm{NaOH} \)) producing sodium borate (\( \mathrm{Na}_{3} \mathrm{BO}_{3} \)) and hydrogen gas (\( \mathrm{H}_{2} \)). The balanced equation should reflect the conservation of mass. However, the proposed equation is not balanced. The presence of sodium doesn't match on both sides, which indicates this equation is incorrect.
02

Examine Reaction 2

This reaction involves phosphorus tetramer (\( \mathrm{P}_{4} \)), sodium hydroxide (\( \mathrm{NaOH} \)), and water yielding sodium hypophosphite (\( \mathrm{NaH}_{2} \mathrm{PO}_{2} \)) and phosphine (\( \mathrm{PH}_{3} \)). The balanced form of this equation is \( \mathrm{P}_{4} + 3\mathrm{NaOH} + 3\mathrm{H}_{2}\mathrm{O} \longrightarrow 3\mathrm{NaH}_{2}\mathrm{PO}_{2} + \mathrm{PH}_{3} \). However, the provided reaction doesn't match this stoichiometry; therefore, it is also incorrect.
03

Check Reaction 3

The reaction should be between sulfur (\( \mathrm{S} \)) and sodium hydroxide (\( \mathrm{NaOH} \)) to yield sodium thiosulfate (\( \mathrm{Na}_{2} \mathrm{S}_{2} \mathrm{O}_{3} \)), sodium sulfide (\( \mathrm{Na}_{2} \mathrm{S} \)), and water (\( \mathrm{H}_{2} \mathrm{O} \)). This is a feasible reaction and is known in chemistry, thus making this equation correct as written.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Balancing Chemical Equations
In chemistry, balancing chemical equations is essential because it ensures the law of conservation of mass is respected. This law states that atoms are neither created nor destroyed in a chemical reaction. Therefore, for any given chemical equation, the number of each type of atom must be the same on both sides of the equation.

To balance an equation, follow these steps:
  • Write down the unbalanced equation.
  • List all reactants (on the left side of the equation) and all products (on the right side of the equation).
  • Count the number of atoms of each type in both reactants and products.
  • Adjust the coefficients (numbers before formulas) to balance the atoms on both sides.
  • Repeat the count and adjust until the number of each type of atom is equal on both sides.
For instance, if an equation has sodium (\( \mathrm{Na}\)) that doesn't match on both sides, as seen in the first example reaction, it signals the equation is unbalanced and hence inaccurate.

Remember, altering subscripts in chemical formulas to balance an equation is wrong, as subscripts are intrinsic to the compound's identity. Adjust only the coefficients.
Reaction Stoichiometry
Reaction stoichiometry involves understanding and using the quantitative relationships between reactants and products in a chemical reaction, which is grounded in the principles of the balanced equation.

These stoichiometric calculations allow chemists to predict the amounts of substances consumed and produced in a given reaction. The coefficients in the balanced equation tell us the ratio in which reactants turn into products. For example, in a balanced reaction such as: \[\mathrm{P}_{4} + 3\mathrm{NaOH} + 3\mathrm{H}_{2}\mathrm{O} \longrightarrow 3\mathrm{NaH}_{2}\mathrm{PO}_{2} + \mathrm{PH}_{3}\]this implies that one mole of \( \mathrm{P}_{4}\) reacts with three moles of \( \mathrm{NaOH}\) and three moles of water to produce three moles of \( \mathrm{NaH}_{2}\mathrm{PO}_{2}\) and one mole of \( \mathrm{PH}_{3}\).

When examining reaction stoichiometry:
  • Identify the balanced equation.
  • Recognize the molar relationships between substances.
  • Use these ratios for conversions between moles of reactant and product.
This stepwise approach helps in accurate calculations when determining the mass or volume of reactants and products involved.
Inorganic Chemistry
Inorganic chemistry is a branch of chemistry focusing on compounds that are not primarily based on carbon-hydrogen bonds. This field includes a vast array of substances like minerals, metals, and metalloproteins.

Many reactions in inorganic chemistry involve elements like sulfur and phosphorus and their combinations with metals and nonmetals. A case in point is the third reaction involving sulfur and sodium hydroxide. This mixture can effectively produce compounds like sodium thiosulfate (\( \mathrm{Na}_{2}\mathrm{S}_{2}\mathrm{O}_{3}\)) and sodium sulfide (\( \mathrm{Na}_{2}\mathrm{S}\)).

Inorganic reactions are crucial in numerous industrial processes, including the production of fertilizers and the treatment of wastewater. As students delve into such reactions:
  • Gain familiarity with periodic table elements' properties.
  • Understand the typical characteristics of the groups and periods in the table.
  • Explore how these properties influence compound formation and reactivity.
Through exploring topics in inorganic chemistry, students build foundational knowledge that supports the broader study of chemical reactions and compounds.

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Most popular questions from this chapter

\(\mathrm{KO}_{2}\) (potassium super oxide) is used in oxygen cylinders in space and submarines because it (a) produces ozone (b) absorbs \(\mathrm{CO}_{2}\) (c) absorbs \(\mathrm{CO}_{2}\) and increase \(\mathrm{O}_{2}\) contents (d) eliminates moisture

Consider the following reactions: 1\. \(2 \mathrm{Na}+2 \mathrm{H}_{2} \mathrm{O} \longrightarrow 2 \mathrm{NaOH}+\mathrm{H}_{2}\) 2\. \(2 \mathrm{NaOH}+\mathrm{Cl}_{2} \longrightarrow \mathrm{NaCl}+\mathrm{NaOCl}+\mathrm{H}_{2} \mathrm{O}\) \(3.4 \mathrm{OH}^{-} \longrightarrow \mathrm{O}_{2}+2 \mathrm{H}_{2} \mathrm{O}+4 \mathrm{e}\) \(4.2 \mathrm{Cl}^{-} \longrightarrow \mathrm{Cl}_{2}+2 \mathrm{e}^{-}\) In the diaphragm cell used for the electrolysis of brine, the reactions that occur would include (a) \(2,3,4\) (b) \(1,3,4\) (c) \(1,2,3\) (d) \(1,2,4\)

Select the correct statement(s) are: (a) \(\mathrm{Na}_{2} \mathrm{CO}_{3} \cdot \mathrm{NaHCO}_{3} \cdot 2 \mathrm{H}_{2} \mathrm{O}\) is a mineral called trona. (b) \(\mathrm{Li}_{2} \mathrm{CO}_{3}\) and \(\mathrm{MgCO}_{3}\), both are thermally stable (c) \(\mathrm{Li}_{2} \mathrm{CO}_{3}\) is only sparingly soluble in water and no \(\mathrm{LiHCO}_{3}\) has been isolated. (d) \(\mathrm{K}_{2} \mathrm{CO}_{3}\) cannot be made by a method similar to the ammonia-soda process.

Consider the following statements: 1\. \(\mathrm{Cs}^{+}\)ion is more highly hydrated than other alkali metal ions 2\. Among the alkali metals \(\mathrm{Li}, \mathrm{Na}, \mathrm{K}\) and \(\mathrm{Rb}\), Li has the higher melting point 3\. Among the alkali metals, only Li form a stable nitride by direct combination (a) 1 and 3 are correct (b) 2 and 3 are correct (c) 1,2 and 3 are correct (d) 1 and 2 are correct

Which of the following oxides have rock salt structure with coordination number \(6: 6\). (a) \(\mathrm{MgO}\) (b) \(\mathrm{CaO}\) (c) \(\mathrm{SrO}\) (d) \(\mathrm{B}_{2} \mathrm{O}_{3}\)

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