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The equilibrium constant for the reaction QRis 25.

  1. If 50Mof Q is mixed with 50Mof R, which way will the reaction proceed to generate more Q or more R?
  2. Calculate the equilibrium concentrations of Q and R.

Short Answer

Expert verified

In the solution (a), equal concentration of QandR is mixed, the reaction will proceed to produce more R molecules.

In the solution (b), the equilibrium concentration ofQ= 3.85渭M and R= 96.15渭M.

Step by step solution

01

Given data

Q=3.85M=96.15M

Keqfor the given reactionQR is 25.

Then,

Keq=RQ=25

02

In solution (a), the reaction will proceed to generate more R.

Keq=RQ=25

Therefore,

R=25times ofQ

At equilibrium, R molecules are 25 times more than the Q molecules.

However, when equal concentration of QandR are mixed, the reaction will proceed forward and more Q molecules are converted to R molecules.

03

In solution (b), calculation of equilibrium concentration of Q and R.

Let us assume that the amount of Q converted to R is x.

Then,

R= 50 + xQ= 50 - xCalculating the value of x,Keq=RQ25 =50 + x50 - x50 + x = 2550 - xx = 46.15

Now, calculating equilibrium constants,

Q= 50 - 46.15 = 3.85渭M

Similarly,

R= 50 + 46.15 = 96.15渭M

Hence, the equilibrium constant of [Q] is 3.85碌M and [R] is 96.15 碌M.

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