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A buffer can be defined as: a. a strong acid plus a strong base b. a weak acid plus the salt of the acid c. a strong acid plus the salt of the acid d. a salt solution

Short Answer

Expert verified
The correct answer is b. a weak acid plus the salt of the acid.

Step by step solution

01

Identify Buffer Components

A buffer solution must contain a weak acid and its conjugate base or a weak base and its conjugate acid.
02

Evaluate Option A

Option A suggests a strong acid plus a strong base. This combination does not form a buffer because both are fully dissociated in water.
03

Evaluate Option B

Option B suggests a weak acid plus the salt of the acid. This combination forms a buffer because the weak acid can donate protons and the salt (conjugate base) can accept protons, maintaining the pH balance.
04

Evaluate Option C

Option C suggests a strong acid plus the salt of the acid. This combination does not form a buffer because the strong acid fully dissociates in water.
05

Evaluate Option D

Option D suggests a salt solution. This alone does not form a buffer as it doesn't have both a weak acid/base and its conjugate form.
06

Conclusion

The correct choice is Option B, a weak acid plus the salt of the acid, as this combination forms a buffer.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Weak Acid and Conjugate Base
A buffer solution typically comprises a weak acid and its conjugate base. The weak acid doesn鈥檛 fully dissociate in water. Instead, it remains partially in its molecular form. On the other hand, the conjugate base is formed when the weak acid loses a proton.

For example, consider acetic acid (CH鈧僀OOH), which is a weak acid. When acetic acid dissociates, it forms its conjugate base, acetate (CH鈧僀OO鈦). The reaction can be represented as follows:
\[ \text{CH}_3\text{COOH} \rightleftharpoons \text{CH}_3\text{COO}^- + \text{H}^+ \]

This equilibrium allows the buffer to resist changes in pH, as the components can neutralize added acids or bases. Therefore, a weak acid and its conjugate base are essential for creating an effective buffer solution.
Buffer Components
To form a buffer, two critical components are required: a weak acid with its conjugate base or a weak base with its conjugate acid. These components work in tandem to stabilize the pH of the solution.

When a small amount of an acid (H鈦 ions) is added to the buffer, the conjugate base present in the buffer neutralizes the added acid by forming more of the weak acid. Conversely, when a base (OH鈦 ions) is added, the weak acid in the buffer neutralizes the base by forming its conjugate base and water.

For instance, in a buffer containing acetic acid (weak acid) and sodium acetate (conjugate base), the following reactions help maintain the pH:
When acid is added: \[ \text{CH}_3\text{COO}^- + \text{H}^+ \rightleftharpoons \text{CH}_3\text{COOH} \]
When base is added: \[ \text{CH}_3\text{COOH} + \text{OH}^- \rightleftharpoons \text{CH}_3\text{COO}^- + \text{H}_2\text{O} \]

These reactions illustrate how the buffer components interact to minimize changes in pH, making them vital for systems requiring pH stability.
pH Balance in Buffers
The primary function of a buffer solution is to maintain a stable pH when small amounts of acids or bases are added. This pH balance is fundamental in many biological and chemical processes.

The ability of a buffer to maintain its pH value is called buffer capacity. It primarily depends on the concentration of the weak acid and its conjugate base in the solution.

Consider the Henderson-Hasselbalch equation, which helps calculate the pH of a buffer solution:
\[ \text{pH} = \text{p}K_a + \text{log} \frac{[\text{A}^-]}{[\text{HA}]} \]
In this equation, \text{p}K_a is the acid dissociation constant, \text{[\text{A}^-]} represents the concentration of the conjugate base, and \text{[\text{HA}]} represents the concentration of the weak acid.

A buffer solution maintains its pH through the equilibrium established between the weak acid and its conjugate base. If more H鈦 ions are added, they are consumed by the conjugate base, and if more OH鈦 ions are added, they are neutralized by the weak acid.

This self-regulating interaction helps the buffer maintain its pH within a narrow range, which is crucial in many scientific fields including biochemistry and environmental science.

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