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Assume that the researchers place an atom in a state with \(n=100, l=2 .\) What is the magnitude of the orbital angular momentum \(\overrightarrow{\boldsymbol{L}}\) associated with this state? (a) \(\sqrt{2} h ;\) (b) \(\sqrt{6} h ;\) (c) \(\sqrt{200} h\) (d) \(\sqrt{10.100} h\)

Short Answer

Expert verified
The magnitude of the orbital angular momentum associated with the given state of the atom is \( \sqrt{6} h \), which corresponds to option (b).

Step by step solution

01

Identify the given values

In the given exercise, it is said that the researchers place an atom in a state with \( n=100, l=2 \). So, the value of \( l \), the azimuthal quantum number, is provided as 2.
02

Apply the formula for the magnitude of orbital angular momentum

The magnitude of the orbital angular momentum \( L \) can be calculated using the formula: \( L = \sqrt{l (l + 1)} h \), where \( h \) is the reduced Planck constant. Substituting the given value of \( l = 2 \) in the formula, we get: \( L = \sqrt{2 (2 + 1)} h = \sqrt{6} h \)
03

Identify the correct answer

Comparing the calculated value with the options given in the exercise, it is found that the magnitude of the orbital angular momentum, \( L \), is \(\sqrt{6} h\), which corresponds to option (b).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Quantum Number
In the realm of quantum mechanics, a quantum number is a discrete value that describes the quantum state of a particle. Quantum numbers arise naturally from the mathematical solutions of the Schr?dinger equation, which is the fundamental equation of motion in quantum mechanics. They are vital for understanding the arrangement of electrons in atoms and molecules.

There are four types of quantum numbers: principal (n), azimuthal (l), magnetic (m), and spin (s). The principal quantum number () determines the energy level and size of the electron orbit, and as it increases, the electron moves further away from the nucleus and possesses more energy. For example, in the exercise, the principal quantum number is given as 100, which indicates a very high energy level for the electron.
Azimuthal Quantum Number
The azimuthal quantum number (), also known as the angular momentum quantum number, describes the shape of an electron's orbit, and it takes on integer values from 0 to n-1 for each value of n. Each value of l corresponds to a different subshell (s, p, d, f, etc.), with l = 0 for s, l = 1 for p, and so on.

In the context of our exercise, the azimuthal quantum number is given as 2, meaning the electron occupies the d subshell. This quantum number is directly related to the electron's orbital angular momentum, which in quantum mechanics has a quantized magnitude given by the formula (L = t(l (l + 1)) h), where h represents the reduced Planck constant.
Reduced Planck Constant
The reduced Planck constant (h), often denoted as h-bar (tt(h / 2ttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttttt?ntttt膂 膂膂膂膂膂 膂膂// 2ttt tttt tttt tttt tttt tttt tttt tttt tttt tttt 膂 膂膂tl膂膂膂膂膂膂 膂// 2 tttt tttt tttt tttt tttt tttt tttt tttt tttt tttt 膂 膂膂膂 膂膂lg 膂膂膂 膂膂膂膂膂膂 膂// 2ttt tttt tttt tttt tttt tttt tttt tttt tttt tttt tttt 膂膂), is an essential physical constant in the field of quantum mechanics. It is related to the Planck constant (h), which is a proportionality factor between the minimum increment of energy, E, associated with a photon and the frequency of its corresponding electromagnetic wave. The reduced Planck constant is equal to the Planck constant divided by 2π. It appears in the quantization of energy levels, the definition of angular momentum, and Heisenberg's uncertainty principle, amongst other fundamental equations.

The importance of the reduced Planck constant in quantum mechanics cannot be overstated. In our exercise, we use the reduced Planck constant (h) for calculating the magnitude of orbital angular momentum, illustrating the deep connection between quantum physics and Planck's discovery.
Quantum Mechanics
Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. Contrasting with classical mechanics, where physical properties are determined by quantities like mass and velocity, quantum mechanics introduces the concept of quantization, which means that certain properties, like energy or angular momentum, can only take on discrete, set values, or 'quanta'.

One of the revolutionary ideas in quantum mechanics is the wave-particle duality, which proposes that every particle or quantum entity can be described as either a particle or a wave. Moreover, quantum mechanics is known for its inherent probabilities; unlike classical mechanics, where outcomes can be predicted exactly, quantum mechanics only provides the probability of finding a particle in a certain state.

In our exercise, we've applied quantum mechanics principles to compute the orbital angular momentum of an atom in a specific quantum state. This is just one application of quantum mechanics that shows how its principles govern the microscopic world.

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Most popular questions from this chapter

The hydrogen spectrum includes four visible lines. Of these, the blue line corresponds to a transition from the \(n=5\) shell to the \(n=2\) shell and has a wavelength of \(434 \mathrm{nm}\). If we look closer, this line is broadened by fine structure due to spin-orbit coupling and relativistic effects. (a) How many different sets of \(l\) and \(j\) quantum numbers are there for the \(n=5\) shell and for the \(n=2\) shell? (b) How many different energy levels are there for \(n=5\) and for \(n=2 ?\) For each of these levels, what is their energy difference in eV from \(-(13.6 \mathrm{eV}) / n^{2} ?\) (c) In a transition that emits a photon the quantum number \(l\) must change by \(\pm 1 .\) Which transition in the fine structure of the hydrogen blue line emits a photon of the shortest wavelength? For this photon what is the shift in wavelength due to the fine structure? (d) Which transition in the fine structure emits a photon of the longest wavelength? For this photon what is the shift in wavelength due to the fine structure? (e) By what total extent, in \(\mathrm{nm}\), is the wavelength of the blue line broadened around the \(434 \mathrm{nm}\) value?

CP Electron Spin Resonance. Electrons in the lower of two spin states in a magnetic field can absorb a photon of the right frequency and move to the higher state. (a) Find the magnetic-field magnitude \(B\) required for this transition in a hydrogen atom with \(n=1\) and \(l=0\) to be induced by microwaves with wavelength \(\lambda\). (b) Calculate the value of \(B\) for a wavelength of \(4.20 \mathrm{~cm}\)

(a) The doubly charged ion \(\mathrm{N}^{2+}\) is formed by removing two electrons from a nitrogen atom. What is the ground-state electron configuration for the \(\mathrm{N}^{2+}\) ion? (b) Estimate the energy of the least strongly bound level in the \(L\) shell of \(\mathrm{N}^{2+}\). (c) The doubly charged ion \(\mathrm{P}^{2+}\) is formed by removing two electrons from a phosphorus atom. What is the ground-state electron configuration for the \(\mathrm{P}^{2+}\) ion? (d) Estimate the energy of the least strongly bound level in the \(M\) shell of \(\mathrm{P}^{2+}\)

Take the size of a Rydberg atom to be the diameter of the orbit of the excited electron. If the researchers want to perform this experiment with the rubidium atoms in a gas, with atoms separated by a distance 10 times their size, the density of atoms per cubic centimeter should be about (a) \(10^{5}\) atoms \(/ \mathrm{cm}^{3} ;\) (b) \(10^{8}\) atoms \(/ \mathrm{cm}^{3} ;\) (c) \(10^{11}\) atoms \(/ \mathrm{cm}^{3}\) (d) \(10^{21}\) atoms \(/ \mathrm{cm}^{3}\).

In a particular state of the hydrogen atom, the angle between the angular momentum vector \(\vec{L}\) and the \(z\) -axis is \(\theta=26.6^{\circ}\). If this is the smallest angle for this particular value of the orbital quantum number \(l\). what is \(l ?\)

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