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When low-energy electrons pass through an ionized gas, electrons of certain energies pass through the gas as if the gas atoms weren't there and thus have transmission coefficients (tunneling probabilities) \(T\) equal to unity. The gas ions can be modeled approximately as a rectangular barrier. The value of \(T=1\) occurs when an integral or half-integral number of de Broglie wavelengths of the electron as it passes over the barrier equal the width \(L\) of the barrier. You are planning an experiment to measure this effect. To assist you in designing the necessary apparatus, you estimate the electron energies \(E\) that will result in \(T=1\). You assume a barrier height of \(10 \mathrm{eV}\) and a width of \(1.8 \times 10^{-10} \mathrm{~m} .\) Calculate the three lowest values of \(E\) for which \(T=1\)

Short Answer

Expert verified
The three lowest values of \(E\) for which \(T=1\) are calculated to be approximately 0.354 eV, 3.18 eV and 7.15 eV respectively.

Step by step solution

01

Understand the De Broglie Wavelength

The De Broglie wavelength \(\lambda\) is given by \(\lambda = \frac{h}{mv}\), where \(h\) is the Planck’s constant, \(m\) is the mass of the particle and \(v\) is the speed of the particle. But the kinetic energy of a moving particle is equal to \(E = \frac{1}{2}mv^2\). Using these two equations, we can derive a formula for the kinetic energy of the electron in terms of its de Broglie wavelength: \(E = \frac{h^2}{2m\lambda^2}\).
02

Apply the Condition for T=1

The condition for \(T = 1\) is that an integral or half-integral number of de Broglie wavelengths equal the width \(L\) of the barrier. This can be represented as \(L=n\lambda/2\) where \(n\) is an integer. We are asked to calculate the energies that will result in \(T = 1\), which means we need to calculate the energy for the different values of \(n\).
03

Calculate the values of E for T=1

Using the equations derived in steps 1 and 2 and setting \(L= 1.8 \times 10^{-10} \mathrm{~m}, n= 1, 3, 5\) (as the number should be integer or half-integer, the first three numbers satisfying this condition are 1, 3 and 5), the width of barrier and Planck’s constant \(h= 6.62607015 \times 10^{-34} m^2 Kg / s\), the mass of an electron \(m= 9.11\times10^{-31} Kg\), we can now calculate the respective energies.
04

Conversion of Units

Unit conversion is necessary to ensure the energy values are in eV (electron Volts). Divide the energy values calculated in the last step by the electron charge \(1.6 × 10^{-19} Coulombs\) to convert to eV. This step provides the final answer

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

De Broglie Wavelength
In the quantum world, particles like electrons can exhibit wave-like characteristics. This is beautifully described by the de Broglie wavelength, which gives us a way to think about particle waves.
According to de Broglie, the wavelength of a particle, such as an electron, is defined by the equation: \[ \lambda = \frac{h}{mv} \]where:
  • \( \lambda \) is the de Broglie wavelength,
  • \( h \) is Planck's constant \( (6.62607015 \times 10^{-34} \text{ m}^2 \text{ kg} / \text{s}) \),
  • \( m \) is the mass of the particle,
  • \( v \) is the particle's velocity.
With this relationship, we equate the wave nature and particle nature of electrons. By measuring wavelength, we can determine properties such as energy.
To link these to energy, we use kinetic energy, which is expressed as \( E = \frac{1}{2}mv^2 \), to reformulate our de Broglie relation into an expression for energy in terms of wavelength: \[ E = \frac{h^2}{2m\lambda^2} \] This equation helps understand how an electron's energy correlates to its wave nature, especially when passing through barriers like the potential in ionized gas.
Rectangular Potential Barrier
Imagine the electron's journey through a gas as akin to crossing a hill. In the quantum context, this hill is the potential barrier, formed due to gas ions. The potential barrier can be approximated as a rectangular shape in diagrams.
Electrons have a certain probability of tunneling through this barrier even if they appear to lack sufficient energy to overcome it—this is quantum tunneling.When discussing a rectangular potential barrier, two important terms come into play:
  • Barrier Height: This is the potential energy level of the barrier, given in this scenario as \(10 \text{ eV}\).
  • Barrier Width \(L\): This is the spatial length the electron must traverse, here equal to \(1.8 \times 10^{-10} \text{ m}\).
A crucial concept is the transmission coefficient \(T\), which indicates how likely it is for an electron to pass through the barrier. Here, when the condition \( \text{T} = 1 \) is met, an integral or half-integral number of de Broglie wavelengths must precisely fit the width of the barrier \(L\). This unique condition allows electrons to pass through as if the barrier wasn't there at all.
Electron Energy Calculation
To calculate the energy levels where an electron can tunnel through the barrier at \( \text{T} = 1\), we apply the concept of fitting de Broglie wavelengths within the barrier.The condition is expressed as:\[ L = n\lambda/2 \]where:
  • \(L\) is the barrier width \(1.8 \times 10^{-10} \text{ m}\),
  • \(n\) is an integer or half-integer (i.e., after simplification, for \( T = 1 \), we choose values like 1, 3, 5).
Given these equations, we can solve for the energy \(E\) using the reformulated de Broglie wavelength relation:\[ E = \frac{h^2}{2m\left(\frac{2L}{n}\right)^2} \]For the specific question, the electron mass is \(9.11 \times 10^{-31} \text{ kg}\) and Planck's constant is \(6.62607015 \times 10^{-34} \text{ m}^2 \text{ kg} / \text{s}\).By substituting these constants and solving the equation for each \(n\):
  • \(n=1\), \(n=3\), \(n=5\)
Calculate energies and finally convert them to electron Volts (eV) by dividing by the electron charge \(1.6 \times 10^{-19} \text{ C}\).
This process ensures you find the specific energies for which \(T = 1\).

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Most popular questions from this chapter

One advantage of the quantum dot is that, compared to many other fluorescent materials, excited states have relatively long lifetimes (10 ns). What does this mean for the spread in the energy of the photons emitted by quantum dots? (a) Quantum dots emit photons of more well-defined energies than do other fluorescent materials. (b) Quantum dots emit photons of less well-defined energies than do other fluorescent materials. (c) The spread in the energy is affected by the size of the dot, not by the lifetime. (d) There is no spread in the energy of the emitted photons, regardless of the lifetime.

When a hydrogen atom undergoes a transition from the \(n=2\) to the \(n=1\) level, a photon with \(\lambda=122 \mathrm{nm}\) is emitted. (a) If the atom is modeled as an electron in a one-dimensional box, what is the width of the box in order for the \(n=2\) to \(n=1\) transition to correspond to emission of a photon of this energy? (b) For a box with the width calculated in part (a), what is the ground-state energy? How does this correspond to the ground-state energy of a hydrogen atom? (c) Do you think a one-dimensional box is a good model for a hydrogen atom? Explain. (Hint: Compare the spacing between adjacent energy levels as a function of \(n .)\)

A particle with mass \(m\) is in a one-dimensional box with width \(L\). If the energy of the particle is \(9 \pi^{2} \hbar^{2} / 2 m L^{2},\) (a) what is the linear momentum of the particle and (b) what is the ratio of the width of the box to the de Broglie wavelength \(\lambda\) of the particle?

In your research on new solid-state devices, you are studying a solid-state structure that can be modeled accurately as an electron in a one-dimensional infinite potential well (box) of width \(L\). In one of your experiments, electromagnetic radiation is absorbed in transitions in which the initial state is the \(n=1\) ground state. You measure that light of frequency \(f=9.0 \times 10^{14} \mathrm{~Hz}\) is absorbed and that the next higher absorbed frequency is \(16.9 \times 10^{14} \mathrm{~Hz}\). (a) What is quantum number \(n\) for the final state in each of the transitions that leads to the absorption of photons of these frequencies? (b) What is the width \(L\) of the potential well? (c) What is the longest wavelength in air of light that can be absorbed by an electron if it is initially in the \(n=1\) state?

The Schrödinger equation for the quantum- mechanical harmonic oscillator in Eq. (40.44) may be written as $$ -\frac{\hbar^{2}}{2 m} \psi^{\prime \prime}+\frac{1}{2} m \omega^{2} x^{2} \psi=E \psi $$ where \(\omega=\sqrt{k^{\prime} / m}\) is the angular frequency for classical oscillations. Its solutions may be cleverly addressed using the following observations: The difference in applying two operations \(A\) and \(B,\) in opposite order, called a commutator, is denoted by \([A, B]=A B-B A\). For example, if \(A\) represents differentiation, so that \(A f=\frac{d f}{d x},\) where \(f=f(x)\) is a function, and \(B\) represents multiplication by \(x,\) then \([A, B]=\left[\frac{d}{d x}, x\right] f=\frac{d}{d x}(x f)-x \frac{d f}{d x} .\) Applying the product rule for differentiation on the first term, we determine \(\left[\frac{d}{d x}, x\right] f=f,\) which we summarize by writing \(\left[\frac{d}{d x}, x\right]=1 .\) Similarly, consider the two operators \(a_{+}\) and \(a_{-}\) defined by \(a_{\pm}=1 / \sqrt{2 m \hbar \omega}\left(\mp \hbar \frac{d}{d x}+m \omega x\right)\) (a) Determine the commutator \(\left[a_{-}, a_{+}\right]\). (b) Compute \(a_{+} a_{-\psi}\) in terms of \(\psi\) and \(\psi^{\prime \prime},\) where \(\psi=\psi(x)\) is a wave function. Be mindful that \(\frac{d}{d x}(x \psi)=\psi+x \psi^{\prime} .\) (c) The Schrödinger equation above may be written as \(H \psi=E \psi,\) where \(H\) is a differential operator. Use your previous result to write \(H\) in terms of \(a_{+}\) and \(a_{-}\) (d) Determine the commutators \(\left[H, a_{\pm}\right] .\) (e) Consider a wave function \(\psi_{n}\) with definite energy \(E_{n},\) whereby \(H \psi_{n}=E_{n} \psi_{n} .\) If we define a new function \(\psi_{n+1}=a_{+} \psi_{n},\) then we can readily determine its energy by computing \(H \psi_{n+1}=H a_{+} \psi_{n}=\left(a_{+} H+\left[H, a_{+}\right]\right) \psi_{n}\) and comparing the result with \(E_{n+1} \psi_{n+1}\). Finish this calculation by inserting what we have determined to find \(E_{n+1}\) in terms of \(E_{n}\) and \(n .\) (f) We can prove that the lowest-energy wave function \(\psi_{0}\) is annihilated by \(a_{-},\) meaning that \(a_{-} \psi_{0}=0 .\) Using your expression for \(H\) in terms of \(a_{\pm},\) determine the ground-state energy \(E_{0}\). (g) By applying \(a_{+}\) repeatedly, we can generate all higher states. The energy of the \(n\) th excited state can be determined by considering \(\mathrm{Ha}_{+}^{n} \psi_{0}=E_{0} \psi_{0}\). Using the above results, determine \(E_{n}\). (Note: We did not have to solve any differential equations or take any derivatives to determine the spectrum of this theory.)

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