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You blow up a spherical balloon to a diameter of \(50.0 \mathrm{~cm}\) until the absolute pressure inside is 1.25 atm and the temperature is \(22.0^{\circ} \mathrm{C}\). Assume that all the gas is \(\mathrm{N}_{2},\) of molar mass \(28.0 \mathrm{~g} / \mathrm{mol}\). (a) Find the mass of a single \(\mathrm{N}_{2}\), molecule. (b) How much translational kinetic energy does an average \(\mathrm{N}_{2}\) molecule have? (c) How many \(\mathrm{N}_{2}\) molecules are in this balloon? (d) What is the total translational kinetic energy of all the molecules in the balloon?

Short Answer

Expert verified
The mass of a single nitrogen molecule, the average translational kinetic energy of a nitrogen molecule, the total number of nitrogen molecules in the balloon, and the total translational kinetic energy of all the molecules in the balloon can be obtained by the equations mentioned in the steps.

Step by step solution

01

Calculate the number of moles

Use the ideal gas law formula, which states that \(PV=nRT\), where P is the pressure, V is the volume, n is the number of moles, R is the ideal gas constant, and T is the temperature in Kelvin. Convert the given conditions to appropriate units and solve for n. Remember, temperature must be in Kelvin and pressure in Pascal for calculating the value of n. Volume can be calculated using the formula for the volume of a sphere, given the diameter. The total number of moles, n, equals \(n = PV/RT\). This value will be used for subsequent steps.
02

Find the mass of a single nitrogen molecule

First, calculate the mass of one mole of nitrogen, which is its molar mass, \(28.0 g\), converted to kilograms. Then, use the Avogadro's number (\(6.02 \times 10^{23}\)) to find the mass of a single nitrogen molecule by dividing the molar mass by Avogadro's number.
03

Calculate the average translational kinetic energy

Use the formula for the average translational kinetic energy per molecule, which is given as \(E = 3/2 kT\), where k is Boltzmann's constant (\(1.38 \times 10^{-23} J/K\)) and T is the temperature in Kelvin.
04

Calculate the number of nitrogen molecules

Multiply the number of moles calculated in Step 1 by Avogadro's number to get the total number of nitrogen molecules in the balloon.
05

Calculate the total translational kinetic energy

Multiply the average translational kinetic energy per molecule calculated in Step 3 by the number of nitrogen molecules calculated in Step 4. This will give the total translational kinetic energy of the gas in the balloon.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Understanding the Ideal Gas Law
The ideal gas law is a fundamental principle in chemistry and physics that relates the pressure, volume, temperature, and number of moles of an ideal gas. It is usually expressed as the equation \(PV = nRT\), where:
  • \(P\) represents the pressure of the gas,
  • \(V\) is the volume it occupies,
  • \(n\) indicates the number of moles of gas,
  • \(R\) is the ideal gas constant, and
  • \(T\) denotes the temperature of the gas in Kelvin.
In practice, one can calculate the amount of gas (in moles) if the other variables are known. Converting conditions to appropriate units is critical; for instance, standard atmospheric pressure is often given in atmospheres (atm) but for calculations, it should be in Pascals (Pa), and temperature always in Kelvin (K). Knowing how to employ the ideal gas law is essential for various calculations in chemistry, such as determining the quantity of gas needed for a reaction, or as in the textbook exercise, finding the number of moles of nitrogen in a balloon.
When confronted with this formula, it's essential to remember that it applies under the assumption that the gas behaves ideally, meaning its molecules do not interact with each other except through elastic collisions and the volume of the gas molecules themselves is negligible compared to the volume the gas occupies.
Discovering the Molar Mass of Nitrogen
The molar mass of a substance is the mass of one mole of that substance. For nitrogen (\(N_2\)), the molar mass is particularly significant in calculations involving the gas in its diatomic form. It's the collective mass of two nitrogen atoms and amounts to approximately 28.0 grams per mole (g/mol). This value is constant and an intrinsic property of nitrogen gas, which becomes the basis for many stoichiometric calculations or gas-related equations.
In the context of the given exercise, knowing the molar mass of nitrogen allows us to calculate the mass of a single nitrogen molecule when combined with Avogadro's number. This calculation paves the way to understanding the microscopic properties of nitrogen gas, connecting the macroscopic measurements we can make (like mass and volume) with the microscopic world of molecules and atoms.
By converting the molar mass from grams to kilograms, we can dive deeper into the realm of physics to relate this to the kinetic energy of molecules. The conversion is necessary since standard units of mass in physics are kilograms (kg), which ensures consistency in formulas that involve kinetic energy or other physical properties.
Exploring Avogadro's Number
Avogadro's number, a cornerstone figure in chemistry, is approximately \(6.02 \times 10^{23}\) and represents the number of constituent particles, usually atoms or molecules, that are contained in one mole of substance. It's an extensive quantity that bridges the gap between the microscale of atoms and the macroscale of grams that we work with in labs and calculations.
This vast number allows chemists to count out atoms or molecules in a way that can be correlated with measurable quantities like mass. In the case of our nitrogen-filled balloon, Avogadro's number is the key to calculating the number of nitrogen molecules from the number of moles computed using the ideal gas law.
Moreover, by dividing the molar mass of nitrogen by Avogadro's number, we determine the mass of a single nitrogen molecule, laying the groundwork for further calculations, such as kinetic energy at the molecular level. It's fascinating how the combination of Avogadro's concept with other physical laws gives us a powerful toolset for understanding and predicting the behavior of gases in various conditions.

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Most popular questions from this chapter

(a) Show that a projectile with mass \(m\) can "escape" from the surface of a planet if it is launched vertically upward with a kinetic energy greater than \(m g R_{p},\) where \(g\) is the acceleration due to gravity at the planet's surface and \(R_{\mathrm{p}}\) is the planet's radius. Ignore air resistance. (See Problem \(18.70 .\) ) (b) If the planet in question is the earth, at what temperature does the average translational kinetic energy of a nitrogen molecule (molar mass \(28.0 \mathrm{~g} / \mathrm{mol}\) ) equal that required to escape? What about a hydrogen molecule (molar mass \(2.02 \mathrm{~g} / \mathrm{mol}\) )? (c) Repeat part (b) for the moon, for which \(g=1.63 \mathrm{~m} / \mathrm{s}^{2}\) and \(R_{\mathrm{p}}=1740 \mathrm{~km}\) (d) While the earth and the moon have similar average surface temperatures, the moon has essentially no atmosphere. Use your results from parts (b) and (c) to explain why.

Helium gas with a volume of \(3.20 \mathrm{~L}\), under a pressure of 0.180 atm and at \(41.0^{\circ} \mathrm{C}\), is warmed until both pressure and volume are doubled. (a) What is the final temperature? (b) How many grams of helium are there? The molar mass of helium is \(4.00 \mathrm{~g} / \mathrm{mol}\).

It is possible to make crystalline solids that are only one layer of atoms thick. Such "two-dimensional" crystals can be created by depositing atoms on a very flat surface. (a) If the atoms in such a twodimensional crystal can move only within the plane of the crystal, what will be its molar heat capacity near room temperature? Give your answer as a multiple of \(R\) and in \(\mathrm{J} / \mathrm{mol} \cdot \mathrm{K}\). (b) At very low temperatures, will the molar heat capacity of a two-dimensional crystal be greater than, less than, or equal to the result you found in part (a)? Explain why.

Solid water (ice) is slowly warmed from a very low temperature. (a) What minimum external pressure \(p_{1}\) must be applied to the solid if a melting phase transition is to be observed? Describe the sequence of phase transitions that occur if the applied pressure \(p\) is such that \(p

A diver observes a bubble of air rising from the bottom of a lake (where the absolute pressure is \(3.50 \mathrm{~atm}\) ) to the surface (where the pressure is 1.00 atm \() .\) The temperature at the bottom is \(4.0^{\circ} \mathrm{C},\) and the temperature at the surface is \(23.0^{\circ} \mathrm{C}\). (a) What is the ratio of the volume of the bubble as it reaches the surface to its volume at the bottom? (b) Would it be safe for the diver to hold his breath while ascending from the bottom of the lake to the surface? Why or why not?

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