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The atmosphere of Mars is mostly \(\mathrm{CO}_{2}\) (molar mass \(44.0 \mathrm{~g} / \mathrm{mol}\) ) under a pressure of \(650 \mathrm{~Pa}\), which we shall assume remains constant. In many places the temperature varies from \(0.0^{\circ} \mathrm{C}\) in summer to \(-100^{\circ} \mathrm{C}\) in winter. Over the course of a Martian year, what are the ranges of (a) the rms speeds of the \(\mathrm{CO}_{2}\), molecules and (b) the density (in \(\mathrm{mol} / \mathrm{m}^{3}\) ) of the atmosphere?

Short Answer

Expert verified
The rms speeds of the \(CO_{2}\) molecules vary from \(v_{rms(min)}\) to \(v_{rms(max)}\) km/h. The density of the atmosphere varies from \(\rho_{min}\) mol/m^3 to \(\rho_{max}\) mol/m^3.

Step by step solution

01

Calculate rms speed at maximum and minimum temperature

The rms speed is given by the formula: \(v_{rms} = \sqrt{\frac{3kT}{m}}\), where \(k\) is the Boltzmann's constant, \(T\) is the temperature in Kelvin, and \(m\) is the molar mass of the gas. Note that we need to convert the temperatures from Celsius to Kelvin before inputting them into the formula. The maximum temperature is \(0^{\circ}C = 273.15K\) and the minimum temperature is \(-100^{\circ}C = 173.15K\). Substituting these values and \(CO_{2}\) molar mass into the formula gives us the ranges for \(v_{rms}\).
02

Convert rms speed to reasonable units

The speeds calculated in Step 1 will be in meters per second (m/s), which might be a little hard to picture. For easier interpretation, these speeds can be converted to kilometers per hour (km/h) by multiplying the result by \(3.6\).
03

Calculate the density at maximum and minimum temperature

The density of a gas (\(\rho\)) is given by the ideal gas law: \(\rho = \frac{PM}{RT}\), where \(P\) is the pressure, \(M\) is the molar mass, \(R\) is the gas constant, and \(T\) is the temperature. We again need to make sure to use the temperatures in Kelvin. Substituting the given values for the maximum and minimum temperatures into this formula gives us the ranges for the density of the \(CO_{2}\) atmosphere in mol/m^3.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Root Mean Square Speed
The root mean square (rms) speed is a way to express the average speed of particles in a gas. When students study the behavior of gases, one important characteristic is how fast the gas molecules are moving on average. The rms speed is particularly useful because it takes into account the distribution of speeds in a gas due to its temperature—a critical factor in kinetic molecular theory.

Here's the formula for calculating the rms speed:\[ v_{\text{rms}} = \sqrt{\frac{3kT}{m}} \]where:
  • \( v_{\text{rms}} \) is the root mean square speed of the gas molecules,
  • \( k \) is the Boltzmann constant, a fundamental constant in physics,
  • \( T \) is the absolute temperature in Kelvins (K),
  • \( m \) is the molar mass of the gas (measured in kg per mol).
To find the rms speed of CO2 molecules on Mars, we need to know the temperature in Kelvins and the molar mass of CO2. The Martian atmosphere has temperature extremes from 0°C (273.15K) in summer to -100°C (173.15K) in winter. By using these temperatures and the known molar mass for CO2, we can calculate the rms speed at these conditions.
Ideal Gas Law
The ideal gas law is a fundamental equation that relates the pressure, volume, temperature, and number of moles of an ideal gas. This law is usually expressed as:\[ PV = nRT \]where:
  • \( P \) stands for the pressure of the gas,
  • \( V \) is the volume that the gas occupies,
  • \( n \) is the number of moles of gas,
  • \( R \) denotes the gas constant,
  • \( T \) is the absolute temperature in Kelvins.
For the Martian atmosphere, which consists mostly of CO2, the pressure remains constant at 650 Pa. By rearranging the ideal gas law to solve for density \( \rho \), we obtain:\[ \rho = \frac{PM}{RT} \]Using this formula, we can determine the density of the Martian atmosphere by considering variations in temperature due to the seasons.
Density of Gas
Density, often represented by the Greek letter \( \rho \), is a measure of mass per unit volume. In the context of gases, density can tell us how much of a gas is present in a certain volume, which is a key concept when studying atmospheres like that of Mars. As we've established through the ideal gas law, density can be calculated by the equation:\[ \rho = \frac{PM}{RT} \]

For Mars, with its atmospheric pressure of 650 Pa and known molar mass of CO2, we can calculate the density at different temperatures. As we consider the changes from 273.15K to 173.15K, the variation in the density of the Martian atmosphere can be found, contributing to our knowledge about how the Martian atmosphere behaves over seasonal changes.
Molar Mass
Molar mass is the weight of one mole of a substance. It's typically expressed in grams per mole (g/mol) and is pivotal in calculating properties such as the rms speed and the density of gases. The molar mass of a molecule like CO2 can be found by adding the molar masses of each atom within the molecule.

For CO2, with carbon having a molar mass of about 12.01 g/mol and oxygen having about 16.00 g/mol, the molar mass of CO2 comes out to 44.01 g/mol (or 0.04401 kg/mol, since we often use kilograms in physics equations). Knowing this value allows us to use equations like the ideal gas law and the formula for rms speed accurately. This is essential for understanding the physical characteristics of the Martian atmosphere when CO2 is the main component.

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Most popular questions from this chapter

A cylindrical diving bell has a radius of \(750 \mathrm{~cm}\) and a height of \(2.50 \mathrm{~m}\). The bell includes a top compartment that holds an undersea adventurer. A bottom compartment separated from the top by a sturdy grating holds a tank of compressed air with a valve to release air into the bell, a second valve that can release air from the bell into the sea, a third valve that regulates the entry of seawater for ballast, a pump that removes the ballast to increase buoyancy, and an electric heater that maintains a constant temperature of \(20.0^{\circ} \mathrm{C}\). The total mass of the bell and all of its apparatuses is \(4350 \mathrm{~kg}\). The density of seawater is \(1025 \mathrm{~kg} / \mathrm{m}^{3}\). (a) An \(80.0 \mathrm{~kg}\) adventurer enters the bell. How many liters of seawater should be moved into the bell so that it is neutrally buoyant? (b) By carefully regulating ballast, the bell is made to descend into the sea at a rate of \(1.0 \mathrm{~m} / \mathrm{s}\). Compressed air is released from the tank to raise the pressure in the bell to match the pressure of the seawater outside the bell. As the bell descends, at what rate should air be released through the first valve? (Hint: Derive an expression for the number of moles of air in the bell \(n\) as a function of depth \(y ;\) then differentiate this to obtain \(d n / d t\) as a function of \(d y / d t .)\) (c) If the compressed air tank is a fully loaded, specially designed, \(600 \mathrm{ft}^{3}\) tank, which means it contains that volume of air at standard temperature and pressure ( \(0^{\circ} \mathrm{C}\) and \(1 \mathrm{~atm}\) ), how deep can the bell descend?

Oxygen \(\left(\mathrm{O}_{2}\right)\) has a molar mass of \(32.0 \mathrm{~g} / \mathrm{mol} .\) What is (a) the average translational kinetic energy of an oxygen molecule at a temperature of \(300 \mathrm{~K} ;\) (b) the average value of the square of its speed; (c) the rootmean-square speed; (d) the momentum of an oxygen molecule traveling at this speed? (e) Suppose an oxygen molecule traveling at this speed bounces back and forth between opposite sides of a cubical vessel \(0.10 \mathrm{~m}\) on a side. What is the average force the molecule exerts on one of the walls of the container? (Assume that the molecule's velocity is perpendicular to the two sides that it strikes.) (f) What is the average force per unit area? (g) How many oxygen molecules traveling at this speed are necessary to produce an average pressure of 1 atm? (h) Compute the number of oxygen molecules that are contained in a vessel of this size at \(300 \mathrm{~K}\) and atmospheric pressure. (i) Your answer for part (h) should be three times as large as the answer for part \((\mathrm{g})\). Where does this discrepancy arise?

A Jaguar XK8 convertible has an eight-cylinder engine. At the beginning of its compression stroke, one of the cylinders contains \(499 \mathrm{~cm}^{3}\) of air at atmospheric pressure \(\left(1.01 \times 10^{5} \mathrm{~Pa}\right)\) and a temperature of \(27.0^{\circ} \mathrm{C}\). At the end of the stroke, the air has been compressed to a volume of \(46.2 \mathrm{~cm}^{3}\) and the gauge pressure has increased to \(2.72 \times 10^{6} \mathrm{~Pa}\). Compute the final temperature.

Modern vacuum pumps make it easy to attain pressures of the order of \(10^{-13}\) atm in the laboratory. Consider a volume of air and treat the air as an ideal gas. (a) At a pressure of \(9.00 \times 10^{-14}\) atm and an ordinary temperature of \(300.0 \mathrm{~K}\), how many molecules are present in a volume of \(1.00 \mathrm{~cm}^{3} ?\) (b) How many molecules would be present at the same temperature but at 1.00 atm instead?

How many moles of an ideal gas exert a gauge pressure of 0.876 atm in a volume of \(5.43 \mathrm{~L}\) at a temperature of \(22.2^{\circ} \mathrm{C} ?\)

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