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An electron in a hydrogen atom is in an slevel, and the atom is in a magnetic field BS _ Bkn Explain why the 鈥渟pin up鈥 statems=+12 has higher energy than the 鈥渟pin down鈥 state ms=12.

Short Answer

Expert verified

We get the interaction energy U=(2.00232)BBms, So, for ms=-12, the interaction energy is negative, decreasing the energy of the electron, and for ms=+12, the interaction energy is positive, increasing the energy of the electron.

Step by step solution

01

Step 1:

From the below equation, the z-component of the spin angular momentum of the electrons is given by:

Sz=ms

鈥. (1)

From the below equation, the z-component of the spin magnetic moment uzis related tosz by:

z=-(2.00232)e2mSz

Substituting equation (1), we get:

z=-(2.00232)e2m(ms)=-2.00232e2mms=-2.00232Bms

WhereB is the Bohr magnetron.

02

Step 2:

From the equation given below, the potential energy U associated with the interaction between a magnetic moment and an external magnetic fieldB is given by:

U=-.B

But, we haveB=Bk(the magnetic field is in the z-direction only), thus, the interaction is:

U=-zB

Substituting form equation (2), we get

U=(2.00232)BBms

So, forms=+12, the interaction energy is:

U1/2=(1.00116)BB

Thus, the energy of this electron increases by this amount

Forms=-12, the interaction energy is:

U-1/2=-(1.00116)BB

Thus, the energy of this electron decreases by this amount

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