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A hypothetical diatomic molecule of oxygen(mass=2.65610-26kg) and hydrogen(mass=1.6710-27kg) emits a photon of wavelength 2.39 mm when it makes a transition from one vibrational state to the next lower state. If we model this molecule as two point masses at opposite ends of a massless spring, how many vibrations per second is the molecule making?

Short Answer

Expert verified

The molecule of two masses is making1.261014 cycles per second

Step by step solution

01

The energy between any two adjacent vibrational levels

The energy between any two adjacent vibrational levels is given by

E=h2

Where, is oscillating angular frequency and is spring constant .

Planck鈥檚 quantum theory

1.Diffrent atoms and molecules can emit or absorb energy in discrete quantities known as quantum.

2. The energy of the radiation absorbed or emitted is directly proportional to the frequency of radiation.

Mathematically energy of radiation is given by

E=hvE=hc

Where, E is the energy of the radiation, h is the Planck鈥檚 constant , is the wavelength of emitted light and c is the speed of light.

02

Calculation of oscillating angular frequency

Using

E=hcE=6.631034J.s3.0108m/s2.39106mE=8.321020J

Here, the energy emitted by photon equals the energy difference between two adjacent vibrational states

So,

E=EE=8.3210-20J

Using

E=h2=2Eh

Put the values of constants in above equation

=2Eh=28.321020J6.631034J.s=21.261014rad/s

03

The calculation of vibration per second making by molecule

Using

f=2

Now put the values of constants in above relation

f=21.2610142f=1.261014Hz

Thus, the molecule of two masses of oxygen and hydrogen is making 1.261014cycles per second

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