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Heat \(Q\) flows into a monatomic ideal gas, and the volume increases while the pressure is kept constant. What fraction of the heat energy is used to do the expansion work of the gas?

Short Answer

Expert verified
The fraction of the heat energy used for work is \(\frac{2}{5}\).

Step by step solution

01

Understand the Ideal Gas Law in Constant Pressure

For a monatomic ideal gas, the relation between pressure \(P\), volume \(V\), and temperature \(T\) is described by the ideal gas law: \(PV = nRT\), where \(n\) is the number of moles and \(R\) is the universal gas constant. In this problem, since the pressure is constant, any change in heat \(Q\) added to the gas leads to work done and a change in internal energy.
02

Use the First Law of Thermodynamics

The first law of thermodynamics states \(Q = \Delta U + W\), where \(\Delta U\) is the change in internal energy and \(W\) is the work done by the system. For a monatomic ideal gas, \(\Delta U = \frac{3}{2}nR(T_2-T_1)\). With constant pressure, \(W = P\Delta V = nR(T_2-T_1)\).
03

Calculate the Fraction Used as Work

From the previous equation, \(W = nR(T_2-T_1)\) and using the relation derived from the first law, \(Q = \Delta U + W = \frac{3}{2}nR(T_2-T_1) + nR(T_2-T_1)\). Solving this, we find \(Q = \frac{5}{2}nR(T_2-T_1)\). The fraction of heat used for work is \(\frac{W}{Q} = \frac{nR(T_2-T_1)}{\frac{5}{2}nR(T_2-T_1)} = \frac{2}{5}\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

First Law of Thermodynamics
The First Law of Thermodynamics is a fundamental principle that describes the conservation of energy. It states that the total energy of a closed system is constant. Mathematically, it can be expressed as \( Q = \Delta U + W \), where:
  • \( Q \) is the heat added to the system,
  • \( \Delta U \) is the change in internal energy,
  • \( W \) is the work done by the system.
In simple terms, this law explains how energy is transformed but not lost. When heat is added to a gas, it can either increase the gas's internal energy or be used to do work, such as expanding its volume. This transformation of energy aligns with the coal of energy conservation in physics, emphasizing that energy, although capable of changing form, cannot be created or destroyed.
Heat Transfer
Heat transfer, in the context of thermodynamics, refers to the transfer of thermal energy between a system and its surroundings. In our initial problem, heat \( Q \) flows into a monatomic ideal gas, a perfect illustration of heat transfer. There are three primary modes of heat transfer:
  • Conduction,
  • Convection,
  • Radiation.
Each method involves the movement of thermal energy due to temperature differences. For example, in gases, convection is the most common form, where heated gas molecules expand, rise, and transfer energy. The process is crucial as it contributes to changes in internal energy or results in mechanical work being done by or on the gas, such as expansion.
Monatomic Gas
In physics, a monatomic gas is composed of individual atoms, unlike diatomic or polyatomic gases, which are made up of molecules. Common examples include noble gases like helium and neon. These gases exhibit unique behaviors under heat due to their simple, non-interacting atomic structure. When considering the kinetic theory of gases, the internal energy \( \Delta U \) of a monatomic ideal gas is directly connected to its temperature. For a monatomic ideal gas, the change in internal energy is expressed as \( \Delta U = \frac{3}{2}nR(T_2 - T_1) \), where \( n \) is the number of moles, \( R \) is the gas constant, and \( T \) is the temperature. This relationship is vital in determining how a monatomic gas responds to heat addition, influencing both its internal energy and the work it performs.
Expansion Work
Expansion work is the work done by a gas as it expands against an external pressure. In thermodynamics, when a gas expands at constant pressure, the work done \( W \) can be calculated using \( W = P\Delta V \), where \( P \) is the pressure and \( \Delta V \) is the change in volume. In the context of the initial problem, this concept is crucial in calculating how much of the input heat is used for work during the process of gas expansion. The work done by the expansion, using the ideal gas law, can also be represented as \( W = nR(T_2 - T_1) \). Understanding expansion work helps explain how energy from heat can be converted into mechanical energy, showcasing the interaction between thermal energy and physical expansion of gases. This is a fundamental concept in thermodynamics, illustrating the practical use of energy in gases during thermodynamic processes.

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Most popular questions from this chapter

A player bounces a basketball on the floor, compressing it to 80.0% of its original volume. The air (assume it is essentially N\(_2\) gas) inside the ball is originally at 20.0\(^\circ\)C and 2.00 atm. The ball's inside diameter is 23.9 cm. (a) What temperature does the air in the ball reach at its maximum compression? Assume the compression is adiabatic and treat the gas as ideal. (b) By how much does the internal energy of the air change between the ball's original state and its maximum compression?

Five moles of an ideal monatomic gas with an initial temperature of 127\(^\circ\)C expand and, in the process, absorb 1500 J of heat and do 2100 J of work. What is the final temperature of the gas?

In a cylinder, 1.20 mol of an ideal monatomic gas, initially at 3.60 \(\times\) 10\(^5\) Pa and 300 K, expands until its volume triples. Compute the work done by the gas if the expansion is (a) isothermal; (b) adiabatic; (c) isobaric. (d) Show each process in a \(pV\)-diagram. In which case is the absolute value of the work done by the gas greatest? Least? (e) In which case is the absolute value of the heat transfer greatest? Least? (f) In which case is the absolute value of the change in internal energy of the gas greatest? Least?

A cylinder with a piston contains 0.250 mol of oxygen at 2.40 \(\times\) 10\(^5\) Pa and 355 K. The oxygen may be treated as an ideal gas. The gas first expands isobarically to twice its original volume. It is then compressed isothermally back to its original volume, and finally it is cooled isochorically to its original pressure. (a) Show the series of processes on a \(pV\)-diagram. Compute (b) the temperature during the isothermal compression; (c) the maximum pressure; (d) the total work done by the piston on the gas during the series of processes.

A gas in a cylinder expands from a volume of 0.110 m\(^3\) to 0.320 m\(^3\). Heat flows into the gas just rapidly enough to keep the pressure constant at 1.65 \(\times\) 10\(^5\) Pa during the expansion. The total heat added is 1.15 \(\times\) 10\(^5\) J. (a) Find the work done by the gas. (b) Find the change in internal energy of the gas. (c) Does it matter whether the gas is ideal? Why or why not?

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