/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 51 Compute the Fermi energy of pota... [FREE SOLUTION] | 91Ó°ÊÓ

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Compute the Fermi energy of potassium by making the simple approximation that each atom contributes one free electron. The density of potassium is \(851 \mathrm{kg} / \mathrm{m}^{3},\) and the mass of a single potassium atom is \(6.49 \times 10^{-26} \mathrm{kg}\) .

Short Answer

Expert verified
The Fermi energy of potassium is approximately 5.59 eV.

Step by step solution

01

Calculate the number of atoms per cubic meter

First, find the number of potassium atoms in one cubic meter by dividing the density of potassium by the mass of a single potassium atom. The density \(\rho\) is 851 kg/m³, and the mass of one atom \(m_a\) is \(6.49 \times 10^{-26}\) kg. The number of atoms per cubic meter \(N\) is\[ N = \frac{\rho}{m_a} = \frac{851}{6.49 \times 10^{-26}} \approx 1.31 \times 10^{28} \text{ atoms/m}^3. \]
02

Determine the number density of electrons

Assuming each atom contributes one free electron, the number density of electrons \(n\) is equal to the number of atoms per cubic meter, which we calculated previously as\[ n = 1.31 \times 10^{28} \text{ electrons/m}^3. \]
03

Use the formula for Fermi energy

The Fermi energy \(E_F\) of a free electron gas can be calculated using the formula:\[ E_F = \frac{\hbar^2}{2m_e}(3\pi^2 n)^{2/3}, \]where \( \hbar \approx 1.0545718 \times 10^{-34} \text{ J} \cdot \text{s}\) is the reduced Planck's constant and \(m_e \approx 9.10938356 \times 10^{-31} \text{ kg}\) is the mass of an electron.
04

Compute the Fermi energy

Substitute the values for \(\hbar\), \(m_e\), and \(n\) into the Fermi energy formula:\[E_F = \frac{(1.0545718 \times 10^{-34})^2}{2 \cdot 9.10938356 \times 10^{-31}}(3\pi^2 \cdot 1.31 \times 10^{28})^{2/3}. \]Perform the necessary calculations:\[E_F \approx 8.95 \times 10^{-19} \text{ J}. \]Convert Joules to electronvolts, knowing that 1 eV = \(1.60218 \times 10^{-19}\) J:\[E_F \approx \frac{8.95 \times 10^{-19}}{1.60218 \times 10^{-19}} \approx 5.59 \text{ eV}.\]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Density of Potassium
When discussing the density of a substance, we are referring to the amount of mass packed into a given volume. For potassium, the density is measured at 851 kg/m³. This indicates how tightly the potassium atoms are packed in a cubic meter of space.
Density is calculated by the formula: \( \text{Density} = \frac{\text{Mass}}{\text{Volume}} \). This value is crucial in calculations like determining how many atoms exist in a cubic meter.
By knowing the density and the mass of individual atoms, we can compute the number of atoms in a given volume, which becomes handy in advanced physics applications, such as calculating Fermi energy.
Free Electron Model
The Free Electron Model is an essential concept in understanding the behavior of metals. In this model, electrons within a metal are treated as free particles not bound to any atom. This means they can move freely within the entire volume of the metal, contributing to conductivity.
Potassium, like other alkali metals, is often assumed to contribute one free electron per atom. This assumption simplifies calculations, allowing physicists to model metals as a sea of electrons moving in a potential field without the complexities of atomic bonds.
Using this model helps us understand electrical properties and calculate the Fermi energy, a type of energy level crucial in quantum mechanics.
Quantum Mechanics
Quantum Mechanics is the branch of physics that describes the behavior of matter and energy on very small scales, such as atoms and subatomic particles. It introduces concepts that defy classical physics, such as wave-particle duality and uncertainty principles.
It also provides the framework to understand electron behaviors in materials, as it accounts for their wave-like characteristics and probabilistic nature.
In the context of the Fermi energy calculation, quantum mechanics allows us to understand how electrons fill energy levels within a material and how these electrons behave at absolute zero temperature, forming what's known as the 'Fermi sea.'
Planck's Constant
Planck's Constant is a fundamental quantity in quantum mechanics that relates the energy of a photon to its frequency. Its value is approximately \(6.62607015 \times 10^{-34} \text{ J} \cdot \text{s} \). In Fermi energy calculations, we use the reduced Planck's Constant, \( \hbar \approx 1.0545718 \times 10^{-34} \text{ J} \cdot \text{s} \), which accounts for a factor of \(2\pi\) in angular frequency.
This constant is pivotal in determining quantum scales and is integral to equations that describe how subatomic particles behave.
In our Fermi energy computation for potassium, Planck's Constant is used to relate the number density of electrons to their energy levels, providing insight into the electronic properties of the material.

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Most popular questions from this chapter

Hydrogen is found in two naturally occurring isotopes; normal hydrogen (containing a single proton in its nucleus) and deuterium (having a proton and a neurron). Assuming that both molecules are the same size and that the proton and neutron have the same mass (which is almost the case), find the ratio of (a) the energy of any given rotational state in a diatomic hydrogen molecule to the energy of the same state in a diatomic deuterium molecule and (b) the energy of any given vibrational state in hydrogen to the same state in deuterium (assuming that the force constant is the same for both molecules) Why is it physically reasonable that the force constant would be the same for hydrogen and deuterium molecules?

CP (a) The equilibrium separation of the two nuclei in an NaCl molecule is 0.24 \(\mathrm{nm}\) . If the molecule is modeled as charges \(+e\) and \(-e\) separated by 0.24 \(\mathrm{nm}\) , what is the electric dipole moment of the molecule (see Section 21.7\() ?\) (b) The measured electric dipole moment arises from point charges \(+q\) and \(-q\) separated by 0.24 \(\mathrm{nm}\) , what is \(q ?\) (c) A definition of the fractional ionic character of the bond is \(q / e\) . If the sodium atom has charge \(+e\) and the chlorine atom has charge \(-e\) the fractional ionic character would be equal to 1. What is the actual fractional ionic character for the bond in NaCl? (d) The equilibrium distance between nuclei in the hydrogen iodide (HI) molecule is \(0.16 \mathrm{nm},\) and the measured electric dipole moment of the molecule is \(1.5 \times 10^{-30} \mathrm{C} \cdot \mathrm{m}\) . What is the fractional ionic character for the bond in \(\mathrm{HI}\) ? How does your answer compare to that for NaCl calculated in part (c)? Discuss reasons for the difference in these results.

If the energy of the \(\mathrm{H}_{2}\) covalent bond is \(-4.48 \mathrm{eV},\) what wavelength of light is needed to break that molecule apart? In what part of the electromagnetic spectrum does this light lie?

cp calt (a) Consider the hydrogen molecule $$\left(\mathrm{H}_{2}\right)$$ to be a simple harmonic oscillator with an equilibrium spacing of \(0.074 \mathrm{nm},\) and estimate the vibrational energy-level spacing for H. The mass of a hydrogen atom is \(1.67 \times 10^{-27} \mathrm{kg}\) . Hint: Estimate the force constant by equating the change in Coulomb repulsion of the protons, when the atoms move slightly closer together than \(r_{0}\) to the "spring" force. That is, assume that the chemical binding force remaing" approximately constant as \(r\) is decreased slightly from \(r_{0}\) ) ( b) Use the results of part (a) to calculate the vibrational energy-level spacing for the deuterium molecule, \(\mathrm{D}_{2}\) . Assume that the spring constant is the same for \(D_{2}\) as for \(\mathrm{H}_{2}\) . The mass of a deuterium atom is \(3.34 \times 10^{-27} \mathrm{kg}\)

When a diatomic molecule undergoes a transition from the \(l=2\) to the \(I=1\) rotational state, a photon with wavelength 63.8\(\mu \mathrm{m}\) is emitted. What is the moment of inertia of the molecule for an axis through its center of mass and perpendicular to the line connecting the nuclei?

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