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Suppose that the uncertainty of position of an electron is equal to the radius of the \(n=1\) Bohr orbit for hydrogen. Calculate the simultaneous minimum uncertainty of the corresponding momentum component, and compare this with the magnitude of the momentum of the electron in the \(n=1\) Bohr orbit. Discuss your results.

Short Answer

Expert verified
The minimum uncertainty in momentum is \(9.94 \times 10^{-25} \text{ kg m/s}\), less than the electron's actual momentum \(1.99 \times 10^{-24} \text{ kg m/s}\). This aligns with quantum mechanics principles.

Step by step solution

01

Understanding the Problem

We need to find the minimum uncertainty in the momentum of an electron when its position uncertainty is equal to the radius of the Bohr orbit for \(n=1\) in a hydrogen atom. We'll then compare this minimum uncertainty in momentum to the actual momentum of the electron in the \(n=1\) orbit.
02

Applying Heisenberg's Uncertainty Principle

According to Heisenberg's Uncertainty Principle, the product of the uncertainty in position \( \Delta x \) and the uncertainty in momentum \( \Delta p \) cannot be less than \( \frac{\hbar}{2} \), where \( \hbar \) is the reduced Planck's constant: \[ \Delta x \Delta p \geq \frac{\hbar}{2} \] Given that \( \Delta x \) is equal to the radius of the \( n = 1 \) Bohr orbit, \( a_0 = 0.529 \times 10^{-10} \) m, we can substitute this into the equation to find \( \Delta p \).
03

Calculating Minimum Uncertainty in Momentum

Using the formula from Heisenberg's Principle, we obtain:\[ \Delta p = \frac{\hbar}{2 \Delta x} = \frac{1.0545718 \times 10^{-34} \text{ Js}}{2 \times 0.529 \times 10^{-10} \text{ m}} = 9.94 \times 10^{-25} \text{ kg m/s} \].
04

Calculating Electron Momentum in the Bohr Orbit

The momentum of an electron in the \( n=1 \) Bohr orbit is given by \[ p = \frac{\hbar}{a_0} = \frac{1.0545718 \times 10^{-34} \text{ Js}}{0.529 \times 10^{-10} \text{ m}} = 1.99 \times 10^{-24} \text{ kg m/s} \]
05

Comparing Minimum Uncertainty and Actual Momentum

The calculated minimum uncertainty in momentum, \( \Delta p = 9.94 \times 10^{-25} \text{ kg m/s} \), is less than the actual momentum \( p = 1.99 \times 10^{-24} \text{ kg m/s} \) of the electron in the \( n=1 \) Bohr orbit. This demonstrates that the actual momentum is above the uncertainty limit, consistent with quantum principles.
06

Discussing the Results

The comparison shows that while the momentum uncertainty is significant, the electron's momentum exceeds this minimum uncertainty. This highlights the nature of quantum mechanics, where even the fundamental parameters have intrinsic uncertainties but observable quantities like actual momentum lie well-resolved beyond these minima.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Bohr Model of the Atom
The Bohr Model of the Atom, developed by Niels Bohr in 1913, is a foundational concept in atomic theory. It introduces a planetary model where electrons orbit the nucleus much like planets around the sun. The model was specifically formulated to explain the energy levels of hydrogen atoms.

One of its key features is the quantization of electron orbits. Instead of existing at any arbitrary distance from the nucleus, electrons are confined to specific orbits or shells. The energy associated with each orbit is quantized, meaning it can only take on certain discrete values.

  • Each orbit corresponds to a specific energy level for the electron, designated by the principal quantum number, \( n \).
  • In the hydrogen atom, the lowest energy level (\( n = 1 \)) is known as the ground state.
  • Electrons can move between these levels by absorbing or emitting a photon, leading to spectral lines that match observations of hydrogen's emission spectrum.

The Bohr Model successfully explained the Rydberg formula for the spectral emission lines of hydrogen, but it falls short for multielectron atoms. The broader insights for these atoms eventually required more complex quantum mechanical approaches.
Quantum Mechanics
Quantum Mechanics is the branch of physics that deals with the behavior of matter and light on the atomic and subatomic scale. It provides a powerful framework for understanding the unique characteristics of particles like electrons in atoms, which cannot be accurately described by classical physics.

The principles of quantum mechanics challenge our traditional views by introducing two critical ideas:
  • Wave-Particle Duality: Particles, such as electrons, exhibit both particle-like and wave-like properties. This duality is fundamental to quantum theory.
  • Uncertainty Principle: Formulated by Werner Heisenberg, it states that the position and momentum of a particle cannot both be precisely determined simultaneously. This limits the precision of our measurements and fundamentally alters our understanding of determinism in physics.

Electrons in atoms do not have well-defined paths as in the classical planetary model, but are described by probability distributions indicating where they are likely to be found.

The development of quantum mechanics has led to ground-breaking technologies and philosophical debates about the nature of reality. Despite its abstractness, it has become a cornerstone of modern physics and chemistry.
Electron Momentum
Electron Momentum in quantum mechanics refers to the momentum of an electron that is not merely a product of its mass and velocity, unlike in classical physics. In the microscopic world, momentum is intricately linked with the wave nature of particles.

In the Bohr Model and quantum mechanics, the momentum of an electron can be understood through:
  • Quantized Orbits: In the Bohr Model, the momentum of an electron in its orbit is quantized, meaning it can only take specific values based on its orbit's radius.
  • Uncertainty Principle: Electron momentum is subject to Heisenberg's Uncertainty Principle. The principle posits that the more precisely an electron's position is known, the less precisely its momentum can be known, and vice versa. This principle becomes particularly relevant when calculating uncertainties, as seen in the exercise example.

The calculated minimum uncertainty of an electron's momentum compared to its actual momentum in the Bohr Model highlights the nuanced understanding that quantum mechanics provides. These insights are instrumental in explaining phenomena like spectral lines and the stability of atomic structures.

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Most popular questions from this chapter

A beam of \(40-\mathrm{eV}\) electrons traveling in the \(+x-\) direction passes through a slit that is parallel to the \(y\) -axis and 5.0\(\mu \mathrm{m}\) wide. The diffraction pattern is recorded on a screen 2.5 \(\mathrm{m}\) from the slit. (a) What is the de Broglie wavelength of the electrons? (b) How much time does it take the electrons to travel from the slit to the screen? (c) Use the width of the central diffraction pattern to calculate the uncertainty in the \(y\) -component of momentum of an electron just after it has passed through the slit. (d) Use the result of part (c) and the Heisenberg uncertainty principle (Eq. 39.29 for \(y\) ) to estimate the minimum uncertainty in the \(y\) -coordinate of an electron just after it has passed through the slit. Compare your result to the width of the slit.

A CD-ROM is used instead of a crystal in an electron- diffraction experiment. The surface of the CD-ROM has tracks of tiny pits with a uniform spacing of 1.60\(\mu \mathrm{m} .\) (a) If the speed of the electrons is \(1.26 \times 10^{4} \mathrm{m} / \mathrm{s},\) at which values of \(\theta\) will the \(m=1\) and \(m=2\) intensity maxima appear? (b) The scattered electrons in these maxima strike at normal incidence a piece of photographic film that is 50.0 \(\mathrm{cm}\) from the CD-ROM. What is the spacing on the film between these maxima?

In a TV picture tube the accelerating voltage is 15.0 \(\mathrm{kV}\) , and the electron beam passes through an aperture 0.50 \(\mathrm{mm}\) in diameter to a screen 0.300 \(\mathrm{m}\) away. (a) Calculate the uncertainty in the component of the electron's velocity perpendicular to the line between aperture and screen. (b) What is the uncertainty in position of the point where the electrons strike the screen? (c) Does this uncertainty affect the clarity of the picture significantly? (Use nonrelativistic expressions for the motion of the electrons. This is fairly accurate and is certainly adequate for obtaining an estimate of uncertainty effects.)

(a) Using the Bohr model, calculate the speed of the electron in a hydrogen atom in the \(n=1,2,\) and 3 levels. (b) Calculate the orbital period in each of these levels. (c) The average lifetime of the first excited level of a hydrogen atom is \(1.0 \times 10^{-8}\) s. In the Bohr model, how many orbits does an electron in the \(n=2\) level complete before returning to the ground level?

Doorway Diffraction. If your wavelength were 1.0 \(\mathrm{m}\) , you would undergo considerable diffraction in moving through a doorway. (a) What must your speed be for you to have this wave length? (Assume that your mass is 60.0 \(\mathrm{kg.}\) ) (b) At the speed calculated in part (a), how many years would it take you to move 0.80 \(\mathrm{m}\) (one step)? Will you notice diffraction effects as you walk through doorways?

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