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Propane gas \(\left(\mathrm{C}_{3} \mathrm{H}_{8}\right)\) behaves like an ideal gas with \(\gamma=1.127\) . Determine the molar heat capacity at constant volume and the molar heat capacity at constant pressure.

Short Answer

Expert verified
\(C_v \approx 65.43 \text{ J/mol·K}; C_p \approx 73.744 \text{ J/mol·K}\)

Step by step solution

01

Understand the Relationship Between Heat Capacities

For an ideal gas, the ratio of specific heats (adiabatic index) is defined as \( \gamma = \frac{C_p}{C_v} \), where \( C_p \) is the molar heat capacity at constant pressure, and \( C_v \) is the molar heat capacity at constant volume. We have \( \gamma = 1.127 \) for propane.
02

Use the Relationship Between Heat Capacities and Gas Constants

For ideal gases, there is a relation given by \( C_p - C_v = R \), where \( R \) is the universal gas constant, approximately \( 8.314 \text{ J/mol·K} \).
03

Set Up Equations Using Known Values

From the relationship \( \gamma = \frac{C_p}{C_v} \), we can express \( C_p = \gamma C_v \). Along with \( C_p = C_v + R \), we now have two equations:1. \( C_p = \gamma C_v \)2. \( C_p = C_v + R \)We will use these to solve for \( C_v \) and \( C_p \).
04

Solve for Molar Heat Capacity at Constant Volume \( C_v \)

Substituting \( C_p = \gamma C_v \) into the second equation, we get:\[ \gamma C_v = C_v + R \]Rearranging terms gives:\[ C_v (\gamma - 1) = R \]Solving for \( C_v \):\[ C_v = \frac{R}{\gamma - 1} = \frac{8.314}{1.127 - 1} = \frac{8.314}{0.127} \approx 65.43 \text{ J/mol·K} \]
05

Solve for Molar Heat Capacity at Constant Pressure \( C_p \)

Now that we have \( C_v \), we can find \( C_p \) using:\[ C_p = C_v + R \]Substituting the calculated value of \( C_v \):\[ C_p = 65.43 + 8.314 \approx 73.744 \text{ J/mol·K} \]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ideal Gas Law
The Ideal Gas Law is a fundamental principle that describes the behavior of ideal gases. It is expressed by the equation \( PV = nRT \), where:
  • \( P \) stands for pressure, measured in pascals (Pa)
  • \( V \) is the volume in cubic meters (m³)
  • \( n \) is the amount of gas in moles
  • \( R \) is the universal gas constant, approximately \( 8.314 \, \text{J/mol·K}\)
  • \( T \) represents the temperature in Kelvin (K)
This law assumes that the gas particles do not interact, except through perfectly elastic collisions, and that the particles themselves take up no space. It serves as a great approximation for gases under many circumstances, especially when temperatures are high and pressures are low. By using the Ideal Gas Law, we can relate the physical properties of gases and solve for unknown variables when others are known.
Molar Heat Capacity
Molar Heat Capacity refers to the amount of heat required to raise the temperature of one mole of a substance by one degree Kelvin. There are two types of molar heat capacities for gases:
  • Molar Heat Capacity at Constant Volume \( (C_v) \)
  • Molar Heat Capacity at Constant Pressure \( (C_p) \)
For an ideal gas, the relationship between these two is given by the formula \( C_p - C_v = R \), where \( R \) is the gas constant. The difference accounts for the energy required not only to raise the temperature but also to do work as the gas expands. This energy manifests either as increased internal energy or as work done by the gas against the surroundings. Understanding this helps in calculating energy changes and efficiency for engines and other thermodynamic systems.
Adiabatic Index
The Adiabatic Index, denoted as \( \gamma \), is the ratio of the molar heat capacity at constant pressure \( (C_p) \) to the molar heat capacity at constant volume \( (C_v) \). It is expressed as \( \gamma = \frac{C_p}{C_v} \). The value of \( \gamma \) provides insight into how a gas behaves when compressed or expanded without heat exchange.
This index is crucial for processes like adiabatic compression and expansion, which occur in thermodynamic cycles like those in heat engines and refrigerators. For propane, like in our example, \( \gamma = 1.127 \), indicating specific thermodynamic properties, which help us derive the heat capacities using the noted relationships. It affects the speed of sound in a gas, as well as the pressure and volume changes in adiabatic processes.
Gas Constant
The Gas Constant \( (R) \) is a fundamental constant in physics and chemistry, appearing in the ideal gas equation \( PV = nRT \). It is a measure of the energy per temperature increment per mole. Its value is approximately \( 8.314 \, \text{J/mol·K} \). The constant plays a pivotal role in transitioning among various formulations of gas properties and applying the ideal gas law efficiently.
It not only connects pressure, volume, and temperature in a universal way but also helps calculate changes in the internal energy and enthalpy of gases. In the study of thermodynamics, \( R \) forms the cornerstone of equations relating different thermodynamic variables, allowing us to solve real-world problems involving gases with greater ease.

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Most popular questions from this chapter

One mole of ideal gas is slowly compressed to one-third of its original volume. In this compression, the work done on the gas has magnitude 600 \(\mathrm{J}\) . For the gas, \(C_{p}=7 R / 2\) . (a) If the process is isothermal, what is the heat flow \(Q\) for the gas? Does heat flow into or out of the gas? (b) If the process is isobaric, what is the change in internal energy of the gas? Does the internal energy increase or decrease?

CALC During the time 0.305 mol of an ideal gas under- goes an isothermal compression at \(22.0^{\circ} \mathrm{C}, 468 \mathrm{J}\) of work is done on it by the surroundings. (a) If the final pressure is 1.76 atm, what was the initial pressure? (b) Sketch a pV-diagram for the process.

In a certain process, \(2.15 \times 10^{5} \mathrm{J}\) of heat is liberated by a system, and at the same time the system contracts under a constant external pressure of \(9.50 \times 10^{5} \mathrm{Pa}\) . The internal energy of the system is the same at the beginning and end of the process. Find the change in volume of the system. (The system is not an ideal gas.)

Nitrogen gas in an expandable container is cooled from \(50.0^{\circ} \mathrm{C}\) to \(10.0^{\circ} \mathrm{C}\) with the pressure held constant at \(3.00 \times 10^{3}\) Pa. The total heat liberated by the gas is \(2.50 \times 10^{4}\) . Assume that the gas may be treated as ideal. (a) Find the number of moles of gas. (b) Find the change in internal energy of the gas. (c) Find the work done by the gas. (d) How much heat would be liberated by the gas for the same temperature change if the volume were constant?

A player bounces a basketball on the floor, compressing it to 80.0\(\%\) of its original volume. The air (assume it is essentially \(\mathrm{N}_{2}\) gas) inside the ball is originally at a temperature of \(20.0^{\circ} \mathrm{C}\) and a pressure of 2.00 atm. The ball's inside diameter is 23.9 \(\mathrm{cm}\) . (a) What temperature does the air in the ball reach at its maximum compression? Assume the compression is adiabatic and treat the gas as ideal. (b) By how much does the internal energy of the air change between the ball's original state and its maximum compression?

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