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43.55. The atomic mass of \(\frac{25}{12} \mathrm{Mg}\) is 24.985837 \(\mathrm{u}\) , and the atomic mass of 13 \(\mathrm{Al}\) is 24.990429 \(\mathrm{u}\) . (a) Which of these nuclei will decay into the other? (b) What type of decay will occur? Explain how you determined this. (c) How much energy (in MeV) is released in the decay?

Short Answer

Expert verified
(a) 13Al decays to 25Mg. (b) Beta-plus decay due to decrease in atomic number. (c) 4.276 MeV energy is released.

Step by step solution

01

Understanding the decay

Nuclei tend to decay when they are less stable, and this is generally determined by comparing their atomic mass and energy content. A nucleus will decay to another nucleus if it results in a lower atomic mass and energy state.
02

Comparing Atomic Masses

Here, we need to compare the atomic masses of the two nuclei. The atomic mass of 25Mg is 24.985837 u, and for 13Al it is 24.990429 u. Since the mass of magnesium (24.985837 u) is less than that of aluminum (24.990429 u), 13Al will decay to the more stable 25Mg.
03

Identifying the Type of Decay

Since 13Al is decaying into 25Mg, and there is a change in the atomic number which increases by 1 (going from aluminum with the atomic number of 13 to magnesium with the atomic number of 12), this indicates a beta-plus decay (positron emission) where a proton is converted into a neutron.
04

Calculating the Energy Released

The energy released in a decay process can be calculated using the mass defect and converting it into energy. First, find the difference in atomic mass:\[\Delta m = 24.990429 \, \text{u} - 24.985837 \, \text{u} = 0.004592 \, \text{u}\]Convert this mass difference to energy:\[E = \Delta m \times 931.5 \, \text{MeV/u} = 0.004592 \, \text{u} \times 931.5 \, \text{MeV/u} = 4.276 \, \text{MeV}\]Thus, 4.276 MeV of energy is released in the decay.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Atomic Mass Comparison
Understanding atomic mass comparison is crucial in determining which nucleus will decay.
When looking at nuclear decay, the atomic mass gives hints about the stability of nuclei.
In general, a nucleus will decay to a more stable state, usually signified by a lower atomic mass. Let's consider the example given in the exercise with magnesium-25 (\(^{25}_{12} \text{Mg}\)) and aluminum-13 (\(^{13}_{12} \text{Al}\)). Here are the key points:
  • Magnesium-25 has an atomic mass of 24.985837 u.
  • Aluminum-13 has an atomic mass of 24.990429 u.
The lower atomic mass for magnesium means it is in a more stable state compared to aluminum.
In situations where mass is the determining factor, the nucleus with the higher atomic mass (aluminum in this case) will undergo decay to achieve a more stable configuration.
Thus, aluminum-13 will naturally decay into magnesium-25.
Beta-Plus Decay
Beta-plus decay, often referred to as positron emission, is a type of radioactive decay.
In beta-plus decay, a proton within the nucleus is transformed into a neutron, resulting in the emission of a positron and a neutrino. In the given exercise, we observe the transformation of\(^{13}_{12} \text{Al}\) to\(^{25}_{12} \text{Mg}\):
  • Aluminum has an atomic number of 13, meaning it contains 13 protons.
  • Magnesium has an atomic number of 12, consisting of 12 protons.
This change indicates that one proton is lost, confirming the occurrence of beta-plus decay.

What Happens in the Nucleus?

During the decay:
  • One proton in the aluminum nucleus is converted to a neutron.
  • This conversion results in the emission of a positron (\(e^+\)).
The atomic number decreases by one while the mass number remains unchanged, consistent with the properties of beta-plus decay. This process is utilized in various applications including medicine.
Energy Release Calculation
Calculating the energy released during nuclear decay can be determined by evaluating the mass defect.
The mass defect refers to the difference in atomic masses before and after the decay event. In the case of the decay from\(^{13}_{12} \text{Al}\) to\(^{25}_{12} \text{Mg}\), we observe the following steps:
  • Determine the difference in atomic masses (mass defect):\[\Delta m = 24.990429 \, \text{u} - 24.985837 \, \text{u} = 0.004592 \, \text{u}\]
  • The energy released is calculated using the formula:\[E = \Delta m \times 931.5 \, \text{MeV/u}\]
  • Substituting the values gives us:\[E = 0.004592 \, \text{u} \times 931.5 \, \text{MeV/u} \approx 4.276 \, \text{MeV}\]

Understanding the Energy Conversion

This conversion of mass defect into energy release reflects Einstein’s mass-energy equivalence principle given by:\[E = mc^2\]where energy \(E\) is directly proportional to the mass defect \(m\). Thus, the 4.276 MeV energy released highlights how even small amounts of mass can convert into significant energy. This principle is foundational in nuclear chemistry.

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Most popular questions from this chapter

43.80. Industrial Radioactivity. Radioisotopes are used in a variety of manufacturing and testing techniques. Wear measurements can be made using the following method. An automobile engine is produced using piston rings with a total mass of 100 \(\mathrm{g}\) , which includes 9.4\(\mu \mathrm{Ci}\) of \(^{59} \mathrm{Fe}\) whose half-life is 45 days. The engine is test-run for 1000 hours, after which the oil is drained and its activity is measured. If the activity of the engine oil is 84 decays/s, how much mass was worn from the piston rings per hour of operation?

43.70. The nucleus \(\frac{15}{8} \mathrm{O}\) has a half-life of \(122.2 \mathrm{s} ; \mathrm{g} \mathrm{O}\) has a half-life of 26.9 s. If at some time a sample contains eqnal amounts of \(\frac{15}{8} \mathrm{O}\) and \(_{8}^{19} \mathrm{O}\) what is the ratio of \(_{8}^{15} 0\) to \(_{8}^{19} \mathrm{O}\) (b) after 15.0 minutes?

43.49. Use conservation of mass-energy to show that the energy released in alpha decay is positive whenever the mass of the original neutral atom is greater than the sum of the masses of the final neutral atom and the neutral "He atom. (Hint: Let the parent nucleus have atomic number \(Z\) and nucleon number \(A\) . First write the reaction in terms of the nuclei and particles involved, and then \(n\) then \(n\) add \(Z\) electron masses to both sides of the reaction and allot them as needed to arrive at neutral atoms.)

43.15. The \(\alpha\) decay of \(^{238} \mathrm{U}\) is accompanied by a \(\gamma\) ray of measured wavelength 0.0248 \(\mathrm{nm}\) . This decay is due to a transition of the nucleus between two energy levels. What is the difference in energy (in MeV) between these two levels?

43.74. In the 1986 disaster at the Chernobyl reactor in the Soviet Union (now Ukraine), about \(\frac{1}{8}\) of the \(^{13} \mathrm{Cs}\) present in the reactor was released. The isotope \(^{137} \mathrm{Cs}\) has a half-life for \(\beta\) decay of 30.07 \(\mathrm{y}\) and decays with the emission of a total of 1.17 \(\mathrm{MeV}\) of energy per decay. Of this, 0.51 \(\mathrm{MeV}\) goes to the emitted electron and the remaining 0.66 MeV to a \(\gamma\) ray. The radioactive 137 \(\mathrm{Cs}\) is absorbed by plants, which are eaten by livestock and humans. How many \(^{137} \mathrm{Cs}\) atoms would need to be present in each kilogram of body tissue if an equivalent dose for one week is 3.5 \(\mathrm{Sv}\) ? Assume that all of the energy from the decay is deposited in that 1.0 \(\mathrm{kg}\) of tissue and that the RBE of the electrons is 1.5 .

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