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43.45. At the beginning of Section 43.7 the equation of a fission process is given in which \(^{25} \mathrm{U}\) is struck by a neutron and undergoes fission to produce \(^{144} \mathrm{Ba},^{89} \mathrm{Kr}\) , and three neutrons. The measured masses of these isotopes are \(235.043930 \mathrm{u}(235 \mathrm{U}), 143.922953 \mathrm{u}\) \(\left(^{144} \mathrm{Ba}\right), 88.917630 \mathrm{u}\left(^{89} \mathrm{Kr}\right),\) and 1.0086649 \(\mathrm{u}\) (neutron). (a) Calculate the energy (in MeV) released by each fission reaction. (b) Calculate the energy released per gram of \(^{235} \mathrm{U},\) in MeV/g.

Short Answer

Expert verified
(a) 45.44 MeV per fission reaction. (b) 1.16 \times 10^{22} MeV/g.

Step by step solution

01

Determine the Initial and Final Masses

Start by writing the equation for the fission process:\[ ^{235} \mathrm{U} + ^{1}n \rightarrow ^{144} \mathrm{Ba} + ^{89} \mathrm{Kr} + 3\ ^{1}n \]Calculate the total mass of the reactants:\[ \text{Initial mass} = 235.043930\ \mathrm{u}\ (^{235} \mathrm{U}) + 1.0086649\ \mathrm{u}\ (\text{neutron}) = 236.0525949\ \mathrm{u} \]Calculate the total mass of the products:\[ \text{Final mass} = 143.922953\ \mathrm{u}\ (^{144} \mathrm{Ba}) + 88.917630\ \mathrm{u}\ (^{89} \mathrm{Kr}) + 3 \times 1.0086649\ \mathrm{u}\ (\text{neutrons}) = 236.0038137\ \mathrm{u} \]
02

Calculate Mass Defect

Find the mass defect by subtracting the total mass of the products from the mass of the reactants:\[ \Delta m = 236.0525949\ \mathrm{u} - 236.0038137\ \mathrm{u} = 0.0487812\ \mathrm{u} \]
03

Convert Mass Defect to Energy

Use Einstein's equation \( E = mc^2 \) to convert the mass defect to energy. First, convert the mass from atomic mass units to energy using the conversion factor \( 1\ \mathrm{u} = 931.5\ \mathrm{MeV/c^2} \):\[ E = \Delta m \times 931.5\ \mathrm{MeV/u} = 0.0487812\ \mathrm{u} \times 931.5\ \mathrm{MeV/u} = 45.44\ \mathrm{MeV} \]
04

Calculate Energy Released per Gram of Uranium-235

Find the number of moles in one gram of \( ^{235}\mathrm{U} \). The molar mass of \( ^{235}\mathrm{U} \) is approximately 235 g/mol:\[ \text{Number of moles in 1g} = \frac{1\ \mathrm{g}}{235\ \mathrm{g/mol}} = 0.00425532\ \mathrm{mol} \]Calculate the number of nuclei per gram using Avogadro's number \( 6.022 \times 10^{23}\ \mathrm{mol}^{-1} \):\[ \text{Number of nuclei} = 0.00425532\ \mathrm{mol} \times 6.022 \times 10^{23}\ \mathrm{mol}^{-1} = 2.56 \times 10^{21}\ \text{nuclei} \]Multiply the energy per fission event by the number of nuclei per gram:\[ \text{Energy per gram} = 45.44\ \mathrm{MeV/nucleus} \times 2.56 \times 10^{21}\ \text{nuclei} = 1.16 \times 10^{22}\ \mathrm{MeV/g} \]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Mass Defect
In nuclear reactions, particularly in fission, the concept of mass defect plays a crucial role. During nuclear fission, an atomic nucleus split into smaller parts, and this process demonstrates that the total mass of the resulting products is slightly less than the original mass. This difference in mass is what we refer to as the mass defect.

The mass defect can be observed in the fission of Uranium-235. Initially, the combined mass of the Uranium-235 nucleus and its colliding neutron is slightly more than the sum of the masses of the fission products, which include smaller isotopes and additional neutrons. This minuscule difference, while seemingly negligible, is what holds the key to the enormous energy released.

Understanding the mass defect is pivotal because it underscores how mass and energy are interrelated, in line with Einstein's theory of relativity, which is expressed as the equation, \( E = mc^2 \). This equation implies that any loss of mass during a reaction is directly convertible into energy.
Energy Conversion
The essence of energy conversion in nuclear fission arises from the mass defect. According to Einstein's famous equation, \( E = mc^2 \), the lost mass (mass defect) during a nuclear reaction is transformed into energy. This is because mass and energy are interchangeable—two sides of the same coin, as per the principles of the theory of relativity.

In the fission of Uranium-235, the initial and final masses differ by a small amount, labeled as the mass defect. Using the conversion factor, 1 atomic mass unit (u) equals 931.5 MeV of energy, we can translate this defect into an energy quantity.

For this specific reaction, a mass defect of 0.0487812 u is associated with an energy release of 45.44 MeV per fission event. This converted energy manifests as kinetic energy among the reaction products, eventually leading to heat, which can be harnessed for power generation in nuclear reactors.
Uranium-235 Fission
Uranium-235 is a commonly used fissile isotope in nuclear reactors and weapons. Its ability to undergo fission means it can split into smaller nuclei when struck by a neutron.
  • In the fission of Uranium-235, a neutron initiates the process.
  • The Uranium-235 nucleus absorbs this neutron and becomes unstable.
  • It then splits into two smaller nuclei, for example, Barium-144 and Krypton-89, along with additional neutrons and energy release.
The process not only releases a large amount of energy but also produces more neutrons, which can propagate further fission reactions. This characteristic is pivotal in maintaining a sustained chain reaction in a nuclear reactor, permitting energy production over an extended period.

The byproducts of fission are radioactive and require careful handling and disposal due to their potential long-term environmental and health impacts.
MeV per Gram Calculations
Calculating the energy output of Uranium-235 by relating it to a macroscopic measure such as MeV per gram is crucial for assessing its efficiency and utility.

To determine this, we start by calculating how many moles of Uranium-235 there are in one gram. Knowing Uranium-235's molar mass is approximately 235 g/mol, we find approximately 0.00425532 moles in one gram. Using Avogadro's number, \( 6.022 \times 10^{23} \), we calculate the number of Uranium-235 nuclei in this amount.

This provides a count of 2.56 x 10^{21} nuclei per gram.

Multiplying the energy release per fission event (45.44 MeV) by the number of nuclei per gram gives us an enormous energy value of 1.16 x 10^{22} MeV per gram. This highlights the incredible energy potential stored in nuclear materials, which is vastly superior to conventional fuels when measured by energy output per unit mass.

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Most popular questions from this chapter

43.74. In the 1986 disaster at the Chernobyl reactor in the Soviet Union (now Ukraine), about \(\frac{1}{8}\) of the \(^{13} \mathrm{Cs}\) present in the reactor was released. The isotope \(^{137} \mathrm{Cs}\) has a half-life for \(\beta\) decay of 30.07 \(\mathrm{y}\) and decays with the emission of a total of 1.17 \(\mathrm{MeV}\) of energy per decay. Of this, 0.51 \(\mathrm{MeV}\) goes to the emitted electron and the remaining 0.66 MeV to a \(\gamma\) ray. The radioactive 137 \(\mathrm{Cs}\) is absorbed by plants, which are eaten by livestock and humans. How many \(^{137} \mathrm{Cs}\) atoms would need to be present in each kilogram of body tissue if an equivalent dose for one week is 3.5 \(\mathrm{Sv}\) ? Assume that all of the energy from the decay is deposited in that 1.0 \(\mathrm{kg}\) of tissue and that the RBE of the electrons is 1.5 .

43.49. Use conservation of mass-energy to show that the energy released in alpha decay is positive whenever the mass of the original neutral atom is greater than the sum of the masses of the final neutral atom and the neutral "He atom. (Hint: Let the parent nucleus have atomic number \(Z\) and nucleon number \(A\) . First write the reaction in terms of the nuclei and particles involved, and then \(n\) then \(n\) add \(Z\) electron masses to both sides of the reaction and allot them as needed to arrive at neutral atoms.)

43.24. Radioactive Tracers. Radioactive isotopes are often introduced into the body through the bloodstream. Their spread through the body can then be monitored by detecting the appearance of radiation in different organs. 131 \(\mathrm{I}\) , a \(B^{-}\) emitter with a half-life of 8.0 \(\mathrm{d}\) is one such tracer. Suppose a scientist introduces a sample with an activity of 375 \(\mathrm{Bq}\) and watches it spread to the organs. (a) Assuming that the sample all went to the thyroid gland, what will be the decay rate in that gland 24 \(\mathrm{d}\) (about 2\(\frac{1}{2}\) weeks) later? (b) If the decay rate in the thyroid 24 d later is actually measured to be 17.0 \(\mathrm{Bq}\) , what percentage of the tracer went to that gland? (c) What isotope remains after the \(\mathrm{I}-131\) decays?

43.72. An Oceanographic Tracer. Nuclear weapons tests in the 1950 s and 1960 s released significant amounts of radioactive tritium \((3 \mathrm{H}, \text { half-life } 12.3 \text { years) into the atmosphere. The tritium }\) atoms were quickly bound into water molecules and rained out of the air, most of them ending up in the ocean. For any of this tritium-tagged water that sinks below the surface, the amount of time during which it has been isolated from the surface can be calculated by measuring the ratio of the decay product, \(\frac{3}{2} \mathrm{He},\) to the remaining tritium in the water. For example, if the ratio of \(\frac{3}{1}\) He to \(\frac{3}{1} \mathrm{H}\) in a sample of water is \(1 : 1,\) the water has been below the surface for one half-life, or approximately 12 years. This method has provided oceanographers with a convenient way to trace the movements of subsurface currents in parts of the ocean. Suppose that in a particular sample of water, the ratio of \(\frac{3}{2} \mathrm{He}\) to \(\frac{3}{1} \mathrm{H}\) is 4.3 to 1.0 . How many years ago did this water sink below the surface?

43.70. The nucleus \(\frac{15}{8} \mathrm{O}\) has a half-life of \(122.2 \mathrm{s} ; \mathrm{g} \mathrm{O}\) has a half-life of 26.9 s. If at some time a sample contains eqnal amounts of \(\frac{15}{8} \mathrm{O}\) and \(_{8}^{19} \mathrm{O}\) what is the ratio of \(_{8}^{15} 0\) to \(_{8}^{19} \mathrm{O}\) (b) after 15.0 minutes?

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