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Liquid nitrogen, which is used in many physics research labs, can present a safety hazard if a large quantity evaporates in a confined space. The resulting nitrogen gas reduces the oxygen concentration, creating the risk of asphyxiation. Suppose \(1.00 \mathrm{~L}\) of liquid nitrogen \(\left(\rho=808 \mathrm{~kg} / \mathrm{m}^{3}\right)\) evaporates and comes into equilibrium with the air at \(21.0^{\circ} \mathrm{C}\) and \(101 \mathrm{kPa}\). How much volume will it occupy?

Short Answer

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#tag_title#Calculations#tag_content# Step 1: Determine the mass of liquid nitrogen $$ m = \rho \times V_{liq} = 808 \mathrm{~kg/m^3} \times 1.00 \times 10^{-3} \mathrm{~m^3} = 0.808 \mathrm{~kg} $$ Step 2: Convert the temperature to Kelvin $$ T_K = T_C + 273.15 = 21.0^{\circ} \mathrm{C} + 273.15 = 294.15 \mathrm{K} $$ Step 3: Use the Ideal Gas Law to find the volume of nitrogen gas Find the number of moles: $$ n = \frac{m}{M_N} = \frac{0.808 \mathrm{~kg}}{28.02 \mathrm{~g/mol} \times 10^{-3} \mathrm{~kg/g}} = 28.84 \mathrm{mol} $$ Calculate the volume of gas: $$ V_{gas} = \frac{nRT}{P} = \frac{28.84 \mathrm{mol} \times 8.314 \mathrm{kPa \cdot L/(mol \cdot K)} \times 294.15 \mathrm{K}}{101 \mathrm{kPa}} = 722.9 \mathrm{L} $$ The volume occupied by 1.00 L of liquid nitrogen when it evaporates and comes into equilibrium with the air at 21.0°C and 101 kPa is approximately 722.9 L.

Step by step solution

01

Determine the mass of liquid nitrogen

First, we need to find the mass of the liquid nitrogen. We are given its density, \(\rho = 808 \mathrm{~kg} / \mathrm{m}^{3}\), and volume, \(V_{liq} = 1.00 \mathrm{~L} = 1.00 \times 10^{-3} \mathrm{~m}^{3}\). We can find the mass using the formula: $$ m = \rho \times V_{liq} $$
02

Convert the temperature to Kelvin

We need to have the temperature in Kelvin to use the Ideal Gas Law. We are given the temperature in Celsius, \(T_C = 21.0^{\circ} \mathrm{C}\), and can convert it to Kelvin using the formula: $$ T_K = T_C + 273.15 $$
03

Use the Ideal Gas Law to find the volume of nitrogen gas

Now we can use the Ideal Gas Law, expressed as \(PV = nRT\), to find the volume occupied by the nitrogen gas. We are given the pressure, \(P = 101 \mathrm{kPa}\), and can find the number of moles, \(n\), from the mass, \(m\), using the molar mass of nitrogen, \(M_N = 28.02 \mathrm{~g/mol}\): $$ n = \frac{m}{M_N} $$ We will use the universal gas constant, \(R = 8.314 \mathrm{J/(mol \cdot K)} = 8.314 \mathrm{kPa \cdot L/(mol \cdot K)}\). Finally, we can solve for the volume of gas, \(V_{gas}\): $$ V_{gas} = \frac{nRT}{P} $$ Now let's perform the calculations.

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