Chapter 15: Problem 3
Why does the temperature of a gas increase when it is quickly compressed?
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These are the key concepts you need to understand to accurately answer the question.
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Chapter 15: Problem 3
Why does the temperature of a gas increase when it is quickly compressed?
These are the key concepts you need to understand to accurately answer the question.
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A gas contained in a cylinder that has a piston is kept at a constant pressure of \(2.8 \times 10^{5} \mathrm{~Pa}\). The gas expands from \(0.5 \mathrm{~m}^{3}\) to \(1.5 \mathrm{~m}^{3}\) when \(300 \mathrm{~kJ}\) of heat is added to the cylinder. What is the change in internal energy of the gas?
A cylinder that has a piston contains \(2.00 \mathrm{~mol}\) of an idea gas and undergoes a reversible isothermal expansion at \(400 \mathrm{~K}\) from an initial pressure of 12 atm down to 3 atm. Determine the amount of work done by the gas.
A pot full of hot water is placed in a cold room, and the pot gradually cools. How does the entropy of the water change?
The energy efficiency ratio (or rating) - the EER-for air conditioners, refrigerators and freezers is defined as the ratio of the input rate of heat \(\left(Q_{\mathrm{C}} / t\right.\), in \(\mathrm{BTU} / \mathrm{h})\) to the output rate of work \((\mathrm{W} / t\), in W): \(\mathrm{EER}=\frac{Q_{\mathrm{C}} / t(\mathrm{BTU} / \mathrm{hr})}{W / t(\mathrm{~W})}\). (a) Show that the EER can be expressed as EER \(=\frac{Q_{C}(\mathrm{BTU})}{W(\mathrm{~W} \cdot \mathrm{h})}\) and is therefore nothing more than the coefficient of performance CP expressed in mixed units. (b) Show that the EER is related to the coefficient of performance \(\mathrm{CP}\) by the equation \(\mathrm{CP}=\mathrm{EER} / 3.412\). (c) Typical home freezers have EER ratings of about \(5.1\) and operate between an interior freezer temperature of \(0^{\circ} \mathrm{F}\) and an outside kitchen temperature of about \(70^{\circ} \mathrm{F}\). What is the coefficient of performance for such a freezer, and how does it compare to the coefficient of performance of the best possible freezer operating between those temperatures? (d) What is the EER of the best possible freezer in part (c)?
Starting with the differential form of the first law of thermodynamics, \(d U=d Q+P d V\), derive the condition for the adiabatic expansion of an ideal gas, \(P V^{\gamma}=\) constant. Note that \(\gamma=C_{P} / C_{V}\).
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