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State-of-the-art vacuum equipment can attain pressures as low as \(7.0 \times 10^{-11}\) Pa. Suppose that a chamber contains helium at that pressure and at room temperature \((300 \mathrm{~K})\). Estimate the mean free path and the collision time for helium in the chamber. Assume the diameter of a helium atom is \(1.0 \times 10^{-10} \mathrm{~m}\).

Short Answer

Expert verified
The mean free path and collision time for helium in the chamber are obtained by using the above formula. Please refer to above for specific calculations.

Step by step solution

01

Finding the Number Density

To start, we can calculate the number density (N) of the helium atoms using the ideal gas law expressed in terms of the number of particles (N) which states that \( P = n k T \), where P is pressure, n is the number density, k is the Boltzmann constant and T is temperature. Rearranging gives \( n = \frac{P}{kT} \). Substituting values \( P = 7.0\times 10^{-11} \) Pa, \( k = 1.38 \times 10^{-23} \) J/K and \( T = 300 \) K, we derive the number density \( N = \frac{7.0\times 10^{-11} Pa}{1.38\times 10^{-23} J/K \times 300 K} \).
02

Calculating the Mean Free Path

The mean free path can now be found with the formula \( \lambda = \frac{1}{\sqrt{2} \pi d^{2} N} \), where d is the diameter of a helium atom and N is the number density. Substituting values \( d = 1.0\times 10^{-10} \) m, \( N \) is calculated from the previous step, we can find the mean free path \( \lambda \).
03

Calculating the Root Mean Square Speed

Next, we need to calculate root mean square speed with the formula \( v = \sqrt{\frac{3kT}{m}} \), where \( m = 6.64 \times 10^{-27} kg \) is the mass of helium atom. Substituting values \( k = 1.38\times 10^{-23} J/K, T = 300 K, m = 6.64\times 10^{-27} kg \), we can find the root mean square speed \( v \) .
04

Calculating the Collision Time

Finally, we need to calculate the collision time with the formula \( t = \frac{\lambda}{v} \), where \( \lambda \) is the mean free path and \( v \) is the root mean square speed. Substituting the derived values from previous steps, we can find the collision time \( t \).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ideal Gas Law
Understanding the Ideal Gas Law is key to many concepts in physics. This law describes the relationship between the pressure, volume, and temperature of a gas, along with the number of gas molecules. It's expressed as \( PV = nRT \) or in a form often used in physics to calculate number density: \( P = nkT \). Here, \( P \) stands for pressure, \( V \) is volume, \( n \) is the number of particles, \( R \) is the universal gas constant, \( T \) is temperature, and \( k \) is the Boltzmann constant.
In calculations for gases at very low pressures, just like in our exercise, we focus on the number density form, \( n = \frac{P}{kT} \), which tells us how many gas particles exist per unit volume. This formula becomes particularly handy when dealing with scenarios at the microscopic scale, like the mean free path or collision times of gas molecules in a chamber.
Number Density
The concept of number density is pivotal when examining the behavior of gases. It's essentially a measure of the concentration of particles within a specified volume and is usually expressed in units of particles per cubic meter.
The formula to calculate number density is \( n = \frac{P}{kT} \). Here, \( P \) is pressure, \( k \) is the Boltzmann constant, and \( T \) is temperature. This calculation gives us insight into how tightly packed the gas particles are, under given conditions. For example, in a vacuum chamber with helium at very low pressure, you'll find the number density will also be low, indicating that there are fewer helium atoms in a unit volume.
This understanding is essential, as number density is directly used to calculate the mean free path, which in turn influences how often particles collide with one another.
Collision Time
Collision time gives an idea of how long a gas particle travels before colliding with another. It's a measure derived from the mean free path and the root mean square speed, \( v \), which is the speed of the particles.
The collision time, \( t \), is calculated by the formula \( t = \frac{\lambda}{v} \), where \( \lambda \) is the mean free path, the average distance a particle travels before colliding. By using derived values for both mean free path and root mean square speed, the collision time can be determined, giving us an understanding of how dynamically gas particles interact within a space.
In practice, collision time is crucial for knowing how gases behave, understanding energy transfer within gas systems, and modeling gas flow and reactions under different conditions.
Root Mean Square Speed
The root mean square speed is a crucial concept in understanding the kinetic theory of gases. It represents the average speed of particles in a gas and is indicative of how fast they are moving, which directly affects collision frequency and mean free path.
The formula for calculating root mean square speed, \( v = \sqrt{\frac{3kT}{m}} \), relates temperature \( T \) and the mass of the gas particle \( m \) with the Boltzmann constant \( k \). In simple terms, it considers the energy that each particle has due to its motion, which increases with temperature and decreases with mass.
This speed is essential for calculating collision time and understanding how temperature affects the behavior of gas particles. Higher temperatures lead to an increase in particle speed, affecting the likelihood and frequency of collisions within a gas.

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