/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 35 Compute the molecular mass \(M\)... [FREE SOLUTION] | 91Ó°ÊÓ

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Compute the molecular mass \(M\) of a gas for which \(y=1.40\) and in which the speed of sound is \(1260 \mathrm{~m} / \mathrm{s}\) at precisely \(0{ }^{\circ} \mathrm{C}\).

Short Answer

Expert verified
The molecular mass of the gas is 1.995 g/mol.

Step by step solution

01

Understand the Problem

We need to calculate the molecular mass \(M\) of a gas given that its adiabatic index \(y = 1.40\) and the speed of sound in the gas is \(1260 \mathrm{~m/s}\) at \(0^{\circ}\mathrm{C}\).
02

Use the Formula for Speed of Sound

The formula that relates the speed of sound \(v\) in a gas to its molecular mass \(M\) is given by: \[ v = \sqrt{\frac{y R T}{M}} \]where \(v\) is the speed of sound, \(y\) is the adiabatic index, \(R\) is the gas constant \((8.314 \mathrm{~J} \mathrm{~mol}^{-1} \mathrm{~K}^{-1})\), \(T\) is the temperature in Kelvin, and \(M\) is the molar mass of the gas.
03

Convert Temperature to Kelvin

Since the temperature is given as \(0^{\circ}\mathrm{C}\), convert it to Kelvin: \[ T = 0 + 273.15 = 273.15 \mathrm{~K}\]
04

Solve for Molar Mass M

Re-arrange the speed of sound formula to solve for \(M\): \[ M = \frac{y R T}{v^2} \]Substitute the given values into the equation: \[ M = \frac{1.40 \times 8.314 \mathrm{~J} \mathrm{~mol}^{-1} \mathrm{~K}^{-1} \times 273.15 \mathrm{~K}}{(1260 \mathrm{~m/s})^2} \]
05

Calculate the Molecular Mass

Perform the calculation:1. Calculate the numerator: \(1.40 \times 8.314 \times 273.15 = 3165.6715\) 2. Calculate the square of the speed of sound: \(1260^2 = 1587600\)3. Divide the numerator by the denominator to find \(M\): \[ M = \frac{3165.6715}{1587600} = 0.001995 \mathrm{~kg/mol} \]
06

Convert to Grams

Since molar mass is usually expressed in grams per mole, convert \(M\) from \(\mathrm{kg/mol}\) to \(\mathrm{g/mol}\): \[ 0.001995 \mathrm{~kg/mol} = 1.995 \mathrm{~g/mol} \]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Speed of Sound in Gases
Sound travels through different mediums by creating waves, and how fast these waves move depends on the medium they travel in. When considering gases, the speed of sound is not constant but varies with factors like temperature and the type of gas. The speed of sound in air, for example, is different from the speed of sound in helium because of the properties of the gases. For gases, the speed of sound can be determined by the formula:
  • \( v = \sqrt{\frac{y R T}{M}} \)
where:
  • \( v \) is the speed of sound,
  • \( y \) is the adiabatic index, which we'll discuss shortly,
  • \( R \) is the universal gas constant,
  • \( T \) is the temperature in Kelvin,
  • \( M \) is the molar mass of the gas.

Understanding and using this formula allows us to calculate important properties of gases from the speed of sound. It's crucial to note this formula because sound speed varies significantly depending on these parameters.
Adiabatic Index
The adiabatic index, represented by \( y \), is a measure of how a gas expands and compresses without losing heat. It is also known as the heat capacity ratio.
Its value varies depending on the specific gas and is defined as the ratio of specific heats:
  • \( y = \frac{C_p}{C_v} \)
where:
  • \( C_p \) is the heat capacity at constant pressure,
  • \( C_v \) is the heat capacity at constant volume.

Gases with higher adiabatic indexes tend to have more rigid molecular structures, which affects their thermodynamic properties like sound speed. In the problem we solved, the gas has an adiabatic index of 1.40, a common value for diatomic gases like nitrogen and oxygen, which are the primary components of air. This helps predict how the gas responds to pressure changes.
Temperature Conversion to Kelvin
Temperature plays a crucial role in gas behavior and calculations involving gases, such as determining the speed of sound. However, temperatures in scientific formulas are often expressed in Kelvin, the SI unit, rather than degrees Celsius. The conversion from Celsius to Kelvin is straightforward:
  • \( T (\text{Kelvin}) = T (\degree C) + 273.15 \)

This conversion is essential because the Kelvin scale begins at absolute zero, the point where all molecular motion ceases, unlike the Celsius scale, which begins from the freezing point of water. In the problem given, at \( 0^{\circ}C \), the temperature in Kelvin is \( 273.15 \).
By using Kelvin, we achieve more consistent and accurate calculations, especially in thermodynamics and physics, where absolute temperatures are required.

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Most popular questions from this chapter

A person riding a power mower may be subjected to a sound of intensity \(2.00 \times 10^{-2} \mathrm{~W} / \mathrm{m}^{2}\). What is the intensity level to which the person is subjected?

When two tuning forks are sounded simultaneously, they produce one beat every \(0.30\) s. (a) By how much do their frequencies differ? (b) A tiny piece of chewing gum is placed on a prong of one fork. Now there is one beat every \(0.40 \mathrm{~s}\). Was this tuning fork the lower-or the higher-frequency fork? The number of beats per second equals the frequency difference. (a) Frequency difference \(=\frac{1}{0.30 \mathrm{~s}}=3.3 \mathrm{~Hz}\) (b) Frequency difference \(=\frac{1}{0.40 \mathrm{~s}}=2.5 \mathrm{~Hz}\) Adding gum to the prong increases its mass and thereby decreases its vibrational frequency. This lowering of frequency caused it to come closer to the frequency of the other fork. Hence, the fork in question had the higher frequency.

At S.T.P., the speed of sound in air is \(331 \mathrm{~m} / \mathrm{s}\). Determine the speed of sound in hydrogen at S.T.P. if the specific gravity of hydrogen relative to air is \(0.0690\) and if \(y=1.40\) for both gases.

A car moving at \(20 \mathrm{~m} / \mathrm{s}\) with its horn blowing \((f=1200 \mathrm{~Hz})\) is chasing another car going at \(15 \mathrm{~m} / \mathrm{s}\) in the same direction. What is the apparent frequency of the horn as heard by the driver being chased? Take the speed of sound to be \(340 \mathrm{~m} / \mathrm{s}\). This is a Doppler problem. Draw the observer-to-source arrow; that's the positive direction. Both the source and the observer are moving in the negative direction. Hence, we use \(-\mathrm{u}_{o}\) and \(-\mathrm{v}_{\mathrm{s}}\) $$ f_{o}=f_{s} \frac{v \pm v_{o}}{v \mp v_{s}}=(1200 \mathrm{~Hz}) \frac{340-15}{340-20}=1.22 \mathrm{kHz} $$ Because the source is approaching the observer, the latter will measure an increase in frequency.

$$ \begin{array}{l} \text { What sound intensity is } 3.0 \mathrm{~dB} \text { louder than a sound of intensity of }\\\ 10 \mu \mathrm{W} / \mathrm{cm}^{2} ? \end{array} $$

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