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A 30-mL tube contains \(0.25 \mathrm{~g}\) of water vapor \((M=18 \mathrm{~kg} / \mathrm{kmol})\) at a temperature of \(340^{\circ} \mathrm{C}\). Assuming the gas to be ideal, what is its pressure?

Short Answer

Expert verified
The pressure of the gas is approximately 2365 Pa.

Step by step solution

01

Identify Given Quantities

We know that the volume of the gas is given as \( V = 30 \text{ mL} = 30 \times 10^{-3} \text{ L} \). The mass of the gas is \( m = 0.25 \text{ g} = 0.25 \times 10^{-3} \text{ kg} \), the molar mass \( M = 18 \text{ kg/mol} \), and the temperature \( T = 340^{\circ} \text{C} = 340 + 273 = 613 \text{ K} \).
02

Calculate Number of Moles

Using the formula \( n = \frac{m}{M} \), where \( n \) is the number of moles, calculate the number of moles of the water vapor. Substituting the given values:\[n = \frac{0.25 \times 10^{-3}}{18} \text{ mol} = 0.01389 \text{ mol}.\]
03

Use Ideal Gas Law

The pressure \( P \) of an ideal gas can be found using \( PV = nRT \), where \( R = 8.314 \text{ J/mol K} \) is the universal gas constant. Rearranging for \( P \), we get:\[P = \frac{nRT}{V}.\]
04

Substitute Values to Find Pressure

Substitute the values calculated and given into the rearranged ideal gas law:\[P = \frac{(0.01389)(8.314)(613)}{30 \times 10^{-3}}\]Calculate to find:\[P \approx 2365 \text{ Pa}.\]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Moles Calculation
In order to find properties of gases, calculating the number of moles is essential. When dealing with the ideal gas law, it requires understanding the formula for moles. Moles ( ext{mol}) can be calculated using the equation \( n = \frac{m}{M} \), where \( m \) is the mass of the substance in kilograms and \( M \) is the molar mass in kilograms per mole.

In the example, we have a water vapor mass of \( 0.25 \, \text{g} \) which we convert to kilograms as \( 0.25 \times 10^{-3} \, \text{kg} \). The molar mass \( M \) of water is given as \( 18 \, \text{kg/mol} \). Plug these into the equation:

\[ n = \frac{0.25 \times 10^{-3}}{18} = 0.01389 \, \text{mol} \]

This calculated mole value is fundamental for the subsequent calculations of pressure in the ideal gas scenario.
Pressure Calculation
Calculating pressure for an ideal gas uses the ideal gas law formula \( PV = nRT \), where
  • \( P \) is pressure,
  • \( V \) is volume,
  • \( n \) is number of moles,
  • \( R \) is the universal gas constant,
  • \( T \) is temperature in Kelvin.
To isolate pressure \( P \), rearrange to \( P = \frac{nRT}{V} \).

For our case, we substitute the values:
  • \( n = 0.01389 \) \, \text{mol}
  • \( R = 8.314 \, \text{J/mol K} \)
  • \( T = 613 \, \text{K} \)
  • \( V = 30 \times 10^{-3} \, \text{L} \)
Now replace these into the formula:
\[ P = \frac{(0.01389)(8.314)(613)}{30 \times 10^{-3}} \approx 2365 \, \text{Pa} \]

Understanding how to break down these calculations allows you to find the pressure of gases in any ideal scenario.
Universal Gas Constant
The Universal Gas Constant \( R \) plays a crucial role in the ideal gas law. It links the physical properties of gases to temperature and pressure, enabling us to solve for unknowns in the ideal gas equation \( PV = nRT \).

The value of \( R \) used in most calculations is \( 8.314 \, \text{J/mol K} \), a standard unit necessary to keep consistent measurements across moles, pressure, volume, and temperature.

Understanding the significance of \( R \) ensures accurate calculations when working with different gases under varying conditions, making it an indispensable part of gas law equations. It is important to ensure that all units used are consistent with the units of \( R \), to maintain clarity and prevent errors in calculations.
Temperature Conversion
When dealing with gases, temperature must always be measured in Kelvin for it to be coherent with the ideal gas law.

The Kelvin scale starts at absolute zero, which means its values are always positive, a vital attribute for calculations using the Ideal Gas Law.

To convert from Celsius to Kelvin, simply add 273.15 to the Celsius temperature. In our example, we have:
\[ T_{\text{Kelvin}} = 340^{\circ} C + 273.15 = 613.15 \, \text{K} \]

By using Kelvin, you ensure that the calculated pressures and volumes remain physically feasible and consistent with scientific standards. Always check your temperature units to avoid any mishaps in your computations.

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Most popular questions from this chapter

A given mass of an ideal gas occupies a volume of \(4.00 \mathrm{~m}^{3}\) at 758 \(\mathrm{mmHg}\). Compute its volume at \(635 \mathrm{mmHg}\) if the temperature remains unchanged.

The gauge pressure in a car tire is \(305 \mathrm{kPa}\) when its temperature is \(15^{\circ} \mathrm{C}\). After running at high speed, the tire has heated up and its gauge pressure is \(360 \mathrm{kPa}\). What is then the temperature of the gas in the tire? Assume atmospheric pressure to be \(101 \mathrm{kPa}\). Being careful to use only absolute temperature and absolute pressures: $$ \frac{P_{1} V_{1}}{T_{1}}=\frac{P_{2} V_{2}}{T_{2}} \quad \text { or } \quad T_{2}=T_{1}\left(\frac{P_{2}}{P_{1}}\right)\left(\frac{V_{2}}{V_{1}}\right) $$ $$ \text { with } \quad P_{1}=305 \mathrm{kPa}+101 \mathrm{kPa}=406 \mathrm{kPa} \quad \text { and } \quad P_{2}=360 \mathrm{kPa}+101 \mathrm{kPa}=461 \mathrm{kPa} $$ $$ \begin{array}{l} \text { Then }\\\ T_{2}=(273+15)\left(\frac{461}{406}\right)(1.00)=327 \mathrm{~K} \end{array} $$ The final temperature of the tire is \(327-273=54{ }^{\circ} \mathrm{C}\).

A \(5000-\mathrm{cm}^{3}\) tank contains an ideal gas \((M=40 \mathrm{~kg} / \mathrm{kmol})\) at a gauge pressure of \(530 \mathrm{kPa}\) and a temperature of \(25^{\circ} \mathrm{C}\). Assuming atmospheric pressure to be \(100 \mathrm{kPa}\), what mass of gas is in the tank?

Compute the density of \(\mathrm{H}_{2} \mathrm{~S}\) gas \((M=34.1 \mathrm{~kg} / \mathrm{kmol})\) at \(27^{\circ} \mathrm{C}\) and \(2.00\) atm, assuming it to be ideal.

On a day when atmospheric pressure is \(76 \mathrm{cmHg}\), the pressure gauge on a tank reads the pressure inside to be \(400 \mathrm{cmHg}\). The gas in the tank has a temperature of \(9^{\circ} \mathrm{C}\). If the tank is heated to \(31^{\circ} \mathrm{C}\) by the Sun, and if no gas exits from it, what will the pressure gauge read? $$ \frac{P_{1} V_{1}}{T_{1}}=\frac{P_{2} V_{2}}{T_{2}} \quad \text { and } \quad P_{2}=P_{1}\left(\frac{T_{2}}{T_{1}}\right)\left(\frac{V_{1}}{V_{2}}\right) $$ But gauges on tanks usually read the difference in pressure between inside and outside; this is called the gauge pressure. Therefore, $$ P_{1}=76 \mathrm{cmHg}+400 \mathrm{cmHg}=476 \mathrm{cmHg} $$ Also, \(V_{1}=V_{2}\). We then have $$ P_{2}=(476 \mathrm{~cm} \mathrm{Hg})\left(\frac{273+31}{273+9}\right)(1.00)=513 \mathrm{cmHg} $$ The gauge will read \(513 \mathrm{cmHg}-76 \mathrm{cmHg}=437 \mathrm{cmHg}\).

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