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A sealed tank having a volume of \(25.0 \times 10^{-3} \mathrm{~m}^{3}\) contains \(0.56 \mathrm{~kg}\) of nitrogen \(\left(\mathrm{N}_{2}\right)\). How many kilomoles of gas are in the tank? [Hint: The atomic mass of the molecule is 28.]

Short Answer

Expert verified
There are 0.02 kilomoles of nitrogen gas in the tank.

Step by step solution

01

Calculate the Molar Mass of Nitrogen

The molecular formula for nitrogen gas is \(N_2\). Given the atomic mass of nitrogen is 28 g/mol for \(N_2\), we calculate the molar mass as \(28 \text{ g/mol}\). Since we need to convert grams to kilograms, the molar mass in kilograms is \(28 \times 10^{-3} \text{ kg/mol}\).
02

Determine the number of Moles

Use the formula: \[ ext{moles} = \frac{ ext{mass (kg)}}{ ext{molar mass (kg/mol)}} \] Substitute the given values: \[ ext{moles} = \frac{0.56 ext{ kg}}{28 \times 10^{-3} ext{ kg/mol}} = 20 ext{ mol} \] Thus, there are 20 moles of nitrogen gas in the tank.
03

Convert Moles to Kilomoles

1 kilomole is equal to 1000 moles. To find the number of kilomoles, divide the number of moles by 1000: \[ ext{kilomoles} = \frac{20 ext{ mol}}{1000} = 0.02 ext{ kilomoles} \] Therefore, there are 0.02 kilomoles of nitrogen gas in the tank.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Molar Mass Calculation
To solve many chemical and physical problems, it's essential to understand how to calculate molar mass. The molar mass of a substance is the mass of one mole of that substance, usually expressed in grams per mole (g/mol). For nitrogen gas, which is composed of two nitrogen atoms ( _2 ext{ ), the atomic mass of nitrogen is given as 14 per atom. Thus, the molecular formula _2 ext{ suggests that its molar mass is 28 g/mol.
  • The sum of atomic masses in a molecule gives the molar mass.
  • For _2, this is: 14 (atomic mass of N) x 2 = 28 g/mol.
When converting molar mass into another unit like kilograms per mole (kg/mol), which might be necessary for certain calculations, simply use the conversion 1 g = 0.001 kg. Therefore, 28 g/mol becomes 28 x 10^{-3} kg/mol. This conversion is crucial when working in different unit scales, as it maintains consistency across calculations.
Mole to Kilomole Conversion
After finding out how many moles of a substance you have, sometimes it may be useful or required to convert this measurement to kilomoles. 1 kilomole (kmol) is equivalent to 1000 moles (mol). To make this conversion:
  • Divide the number of moles by 1000.
  • This is particularly useful in calculations involving larger quantities of substances, where moles would become cumbersome.
For example, if you have a tank with 20 moles of nitrogen gas, converting this to kilomoles would involve dividing 20 by 1000, resulting in 0.02 kmol. This simplification is often used in industrial applications or large-scale chemical engineering where dealing with larger units becomes practical.
Chemical Formulas
Understanding chemical formulas is vital in determining the composition and properties of compounds. Chemical formulas represent molecules using atomic symbols and numeric subscripts to show the number of each type of atom present. For nitrogen gas, the chemical formula is _2. This tells us:
  • The molecule consists of two nitrogen atoms.
  • The bonding is between nitrogen atoms, not a compound with another element.
Using chemical formulas helps in calculating other properties like molar mass or predicting how the molecule will behave in a reaction. Being fluent in reading and interpreting these formulas is fundamental in chemistry, guiding not only stoichiometric calculations but also the theoretical understanding of molecular structure.
Gas Calculations
Gas calculations often involve understanding numerous properties such as volume, temperature, and pressure, along with the quantity of the gas, typically expressed in moles or kilomoles. In the case of our example with nitrogen in a sealed tank:
  • We calculated moles from a given mass and molar mass using the formula: \( \text{moles} = \frac{\text{mass (kg)}}{\text{molar mass (kg/mol)}} \).
  • Knowing the volume is crucial when further calculations are needed, like applying the Ideal Gas Law \( PV = nRT \), though this example did not require pressure or temperature.
Understanding these concepts allows accurate predictions about gas behavior under different conditions. With nitrogen gas, we focus on mole and mass calculations. But in other scenarios, knowledge of all variables ensures comprehensive analysis and application of gas properties.

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Most popular questions from this chapter

Compute the volume of \(8.0\) g of helium \((M=4.0 \mathrm{~kg} / \mathrm{kmol})\) at 15 \({ }^{\circ} \mathrm{C}\) and \(480 \mathrm{mmHg}\). Use \(P V=(m / M) R T\) to obtain $$ V=\frac{m R T}{M P}=\frac{(0.0080 \mathrm{~kg})(8314 \mathrm{~J} / \mathrm{kmol} \cdot \mathrm{K})(288 \mathrm{~K})}{(4.0 \mathrm{~kg} / \mathrm{kmol})\left[(480 / 760)\left(1.01 \times 10^{5} \mathrm{~N} / \mathrm{m}^{2}\right)\right]}=0.075 \mathrm{~m}^{3}=75 \text { liters } $$

A \(6.00-\mathrm{m}^{3}\) cylinder filled with oxygen at an absolute pressure of \(2.00\) atm is sealed with a movable piston. The chamber is then compressed down to \(3.0\) liters. If the temperature is kept constant, what will be the new absolute pressure? [Hint: Use Boyle's Law.]

One kilomole of ideal gas occupies \(22.4 \mathrm{~m}^{3}\) at \(0{ }^{\circ} \mathrm{C}\) and 1 atm. \((a)\) What pressure is required to compress \(1.00 \mathrm{kmol}\) into a \(5.00 \mathrm{~m}^{3}\) container at \(100^{\circ} \mathrm{C} ?(b)\) If \(1.00 \mathrm{kmol}\) was to be sealed in a \(5.00 \mathrm{~m}^{3}\) tank that could withstand a gauge pressure of only \(3.00\) atm, what would be the maximum temperature of the gas if the tank was not to burst?

A mass of ideal gas occupies \(38 \mathrm{~mL}\) at \(20^{\circ} \mathrm{C}\). If its pressure is held constant, what volume does it occupy at a temperature of \(45^{\circ} \mathrm{C}\) ?

On a day when the barometer reads \(75.23 \mathrm{~cm}\), a reaction vessel holds \(250 \mathrm{~mL}\) of ideal gas at \(20.0^{\circ} \mathrm{C}\). An oil manometer \((\rho=810\) \(\mathrm{kg} / \mathrm{m}^{3}\) ) reads the pressure in the vessel to be \(41.0 \mathrm{~cm}\) of oil and below atmospheric pressure. What volume will the gas occupy under S.T.P.?

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